Article(id=1319237207383195954, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220725, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1662048000000, receivedDateStr=2022-09-02, revisedDate=1664208000000, revisedDateStr=2022-09-27, acceptedDate=null, acceptedDateStr=null, onlineDate=1792460260482, onlineDateStr=2026-10-20, pubDate=1671465600000, pubDateStr=2022-12-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792460260482, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792460260482, creator=13701087609, updateTime=1792460260482, updator=13701087609, issue=Issue{id=1319237171312177253, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='12', pageStart='3091', pageEnd='3336', issueExtLink='null', onlineDate='null', pubDate='1671465600000', pubDateStr='2022-12-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792460251882, creator='13701087609', updateTime=1792460721974, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319239143067071226, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319239143067071227, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=3165, endPage=3184, ext={EN=ArticleExt(id=1319237207584522547, articleId=1319237207383195954, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Development on Fluorescence Sensing Properties of Lanthanide Metal-Organic Frameworks, columnId=1321891438401532897, journalTitle=Journal of the Chinese Ceramic Society, columnName=Advanced Rare Earth Luminescence Materials for Sensing and Detection—Review, runingTitle=null, highlight=null, articleAbstract=

Lanthanide metal-organic framework (Ln-MOF) is a novel inorganic-organic porous material, which is composed of organic ligands and lanthanide metal ions or metal clusters. Ln-MOFs have abundant molecular building blocks and a high fluorescence quantum efficiency due to the high coordination number and unique optical properties of lanthanide metal ions. This review summarized recent work on Ln-MOFs, mainly focusing on the application of Ln-MOFs in photonics such as temperature detection, small molecule detection, gas detection, etc. The design and controllable preparation methods of Ln-MOFs as well as the assembly of organic dyes, perovskite quantum dots, etc. in the Ln-MOFs channel and the assembly of Ln3+ in the MOFs channel were introduced. In addition, the future development and application prospects of the Ln-MOFs were also proposed.

, authors=Heqi ZHENG, Yuanjing CUI, Guodong QIAN, authorsList=Heqi ZHENG, Yuanjing CUI, Guodong QIAN, authorCompany=null, correspAuthors=Yuanjing CUI, Guodong QIAN, authorNote=

ZHENG He-Qi (1993-), male, Doctoral candidate. E-mail:

, correspAuthorsNote=
CUI Yuanjing (1975-), male, Ph.D., Professor; E-mail:
QIAN Guodong (1966-), male, Ph.D., Professor.
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稀土金属-有机框架是一种由稀土金属离子或稀土金属簇与有机桥联配体通过配位作用组装形成的新型无机-有机多孔材料。由于其高配位数和独特的稀土金属离子(Ln3+)的光学特性赋予稀土金属-有机框架以丰富的分子构筑单元以及高的荧光量子效率。总结了稀土金属-有机框架的最新研究成果,介绍了稀土金属-有机框架在温度传感、小分子传感、气体传感等光子学领域的应用。另外,还介绍了包括稀土金属-有机框架的设计思路和可控制备方法,以及有机染料等在稀土金属-有机框架孔道中的组装和稀土金属离子在金属-有机框架材料孔道中的组装,并对今后的发展方向和应用前景进行了展望。

, authors=郑和奇, 崔元靖, 钱国栋, authorsList=郑和奇, 崔元靖, 钱国栋, authorCompany=null, correspAuthors=崔元靖, 钱国栋, authorNote=

郑和奇(1993—),男,博士研究生。

, correspAuthorsNote=
崔元靖(1975—),男,博士,教授;
钱国栋(1966—),男,博士,教授。
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稀土金属-有机框架材料的荧光传感应用研究进展
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郑和奇 , 崔元靖 , 钱国栋
硅酸盐学报 | 稀土发光传感与探测新材料专题—综合评述 2022,50(12): 3165-3184
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硅酸盐学报 |稀土发光传感与探测新材料专题—综合评述 2022 , 50 (12) : 3165 -3184
稀土金属-有机框架材料的荧光传感应用研究进展
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郑和奇 , 崔元靖 , 钱国栋
作者信息
  • 硅材料国家重点实验室,浙江大学材料科学与工程学院,杭州 310027
通讯作者:
崔元靖(1975—),男,博士,教授;
钱国栋(1966—),男,博士,教授。
作者简介:

郑和奇(1993—),男,博士研究生。

Development on Fluorescence Sensing Properties of Lanthanide Metal-Organic Frameworks
Heqi ZHENG , Yuanjing CUI , Guodong QIAN
Affiliations
  • State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China
  • Corresponding Author:
    CUI Yuanjing (1975-), male, Ph.D., Professor; E-mail:
    QIAN Guodong (1966-), male, Ph.D., Professor.

    ZHENG He-Qi (1993-), male, Doctoral candidate. E-mail:

出版时间: 2022-12-20 doi: 10.14062/j.issn.0454-5648.20220725
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稀土金属-有机框架是一种由稀土金属离子或稀土金属簇与有机桥联配体通过配位作用组装形成的新型无机-有机多孔材料。由于其高配位数和独特的稀土金属离子(Ln3+)的光学特性赋予稀土金属-有机框架以丰富的分子构筑单元以及高的荧光量子效率。总结了稀土金属-有机框架的最新研究成果,介绍了稀土金属-有机框架在温度传感、小分子传感、气体传感等光子学领域的应用。另外,还介绍了包括稀土金属-有机框架的设计思路和可控制备方法,以及有机染料等在稀土金属-有机框架孔道中的组装和稀土金属离子在金属-有机框架材料孔道中的组装,并对今后的发展方向和应用前景进行了展望。

稀土金属-有机框架  /  温度计  /  荧光传感  /  后合成

Lanthanide metal-organic framework (Ln-MOF) is a novel inorganic-organic porous material, which is composed of organic ligands and lanthanide metal ions or metal clusters. Ln-MOFs have abundant molecular building blocks and a high fluorescence quantum efficiency due to the high coordination number and unique optical properties of lanthanide metal ions. This review summarized recent work on Ln-MOFs, mainly focusing on the application of Ln-MOFs in photonics such as temperature detection, small molecule detection, gas detection, etc. The design and controllable preparation methods of Ln-MOFs as well as the assembly of organic dyes, perovskite quantum dots, etc. in the Ln-MOFs channel and the assembly of Ln3+ in the MOFs channel were introduced. In addition, the future development and application prospects of the Ln-MOFs were also proposed.

lanthanide metal-organic framework  /  thermometer  /  fluorescence sensing  /  post-synthesis
郑和奇, 崔元靖, 钱国栋. 稀土金属-有机框架材料的荧光传感应用研究进展. 硅酸盐学报, 2022 , 50 (12) : 3165 -3184 . DOI: 10.14062/j.issn.0454-5648.20220725
Heqi ZHENG, Yuanjing CUI, Guodong QIAN. Development on Fluorescence Sensing Properties of Lanthanide Metal-Organic Frameworks[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (12) : 3165 -3184 . DOI: 10.14062/j.issn.0454-5648.20220725
  • 国家自然科学基金(52025131)
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doi: 10.14062/j.issn.0454-5648.20220725
  • 接收时间:2022-09-02
  • 首发时间:2026-10-20
  • 出版时间:2022-12-20
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出版历史
  • 收稿日期:2022-09-02
  • 修回日期:2022-09-27
基金
国家自然科学基金(52025131)
作者信息
    硅材料国家重点实验室,浙江大学材料科学与工程学院,杭州 310027

通讯作者:

崔元靖(1975—),男,博士,教授;
钱国栋(1966—),男,博士,教授。
参考文献
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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