Article(id=1319222690372768496, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222618356559896, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220717, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1661961600000, receivedDateStr=2022-09-01, revisedDate=1669996800000, revisedDateStr=2022-12-03, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456799357, onlineDateStr=2026-10-20, pubDate=1681920000000, pubDateStr=2023-04-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456799357, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456799357, creator=13701087609, updateTime=1792456799357, updator=13701087609, issue=Issue{id=1319222618356559896, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='4', pageStart='831', pageEnd='1090', issueExtLink='null', onlineDate='null', pubDate='1681920000000', pubDateStr='2023-04-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456782187, creator='13701087609', updateTime=1792456947953, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223313692472320, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222618356559896, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223313692472321, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222618356559896, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1025, endPage=1033, ext={EN=ArticleExt(id=1319222690574095089, articleId=1319222690372768496, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation of CaSn(OH)₆ Deposition on Calcium Zincate Surface and Application in Zinc-Nickel Secondary Battery, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

In order to improve the serious polarization problem of zinc negative electrode in zinc-nickel secondary batteries and to improve the electrochemical performance and cycling stability of zinc negative electrode, a hydrothermal-coprecipitation method was used to prepare CaSn(OH)₆ deposited on the surface of calcium zincate and used as a negative active substance of zinc-nickel batteries. The results show that the hydrothermal-coprecipitation method can be used to deposit CaSn(OH)₆ on the surface of calcium zincate, and the prepared calcium zincate has a high crystallinity. Based on the cyclic voltammetry test, the addition of CaSn(OH)₆ reduces the charge transfer resistance of calcium zincate and is beneficial to accelerating the electrochemical reaction rate of calcium zincate in alkaline electrolyte, thus improving the discharge rate in the reaction process. The results of electrochemical impedance spectroscopy confirm that calcium zincate with CaSn(OH)₆ deposited on the surface electrode charge transfers impedance less rather than that of pure calcium zincate. The capacity retention rate of the battery is 85.34% after 70 charge discharge cycles at 0.2 C when calcium zincate with CaSn(OH)₆ deposited on the surface is used as a negative active material of Zn-Ni battery.

, authors=Wei QIN¹, Xiaohua YU¹, Shuanglin YU², Wenzhi ZHANG¹, Zhanxin WU¹, Qingfen SHEN¹, Gang XIE^{1, 3}, authorsList=Wei QIN, Xiaohua YU, Shuanglin YU, Wenzhi ZHANG, Zhanxin WU, Qingfen SHEN, Gang XIE, authorCompany=null, correspAuthors=Xiaohua YU, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319222690813170418, articleId=1319222690372768496, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=锌酸钙表面沉积CaSn(OH)₆的制备及锌镍二次电池应用, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

为了改善锌镍二次电池中锌负极存在的严重极化问题，并提高锌负极的电化学性能和循环稳定性，采用水热-共沉淀法制备了表面沉积CaSn（OH）₆的锌酸钙，研究了CaSn（OH）₆的沉积对锌酸钙的形貌结构和电化学性能的影响。结果表明：水热-共沉淀法可以让CaSn（OH）₆沉积在锌酸钙表面，且制得的锌酸钙结晶度高。CaSn（OH）₆的沉积降低了锌酸钙的电荷转移电阻，加快了电化学反应速率，并提升了锌酸钙的耐腐蚀能力和电荷传递速率，有效的改善了锌电极的极化现象。将表面沉积CaSn（OH）₆的锌酸钙用作锌镍电池负极活性物质时，电池在0.2 C充放电循环70次后的容量保持率为85.34%。

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QIN Wei (1997-), male, Master candidate. E-mail: 1300604272@qq.com

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QIN Wei (1997-), male, Master candidate. E-mail: 1300604272@qq.com

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秦炜（1997—），男，硕士研究生。

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秦炜（1997—），男，硕士研究生。

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