Article(id=1319222757989142678, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222668956643677, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220679, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1660838400000, receivedDateStr=2022-08-19, revisedDate=1669392000000, revisedDateStr=2022-11-26, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456815478, onlineDateStr=2026-10-20, pubDate=1684512000000, pubDateStr=2023-05-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456815478, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456815478, creator=13701087609, updateTime=1792456815478, updator=13701087609, issue=Issue{id=1319222668956643677, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='5', pageStart='1091', pageEnd='1372', issueExtLink='null', onlineDate='null', pubDate='1684512000000', pubDateStr='2023-05-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456794251, creator='13701087609', updateTime=1792456976356, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223432827490920, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222668956643677, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223432827490921, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222668956643677, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1136, endPage=1145, ext={EN=ArticleExt(id=1319222758173692055, articleId=1319222757989142678, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Experiment and Molecular Dynamics Simulation of Interfacial Bonding Degradation of Fiber/Resin Under Chloride Corrosion, columnId=1321891041012200067, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Progress on Cement-Based Materials—Research Articles, runingTitle=null, highlight=null, articleAbstract=

The force transferring between fiber and matrix is closely related to the interfacial bonding properties of fiber-resin during the loading process of fiber reinforced polymer (FRP) bars. However, its bonding properties are degraded by the diffusion of chloride ions in the pore solution of seawater sea-sand concrete into the interfacial zone of fiber-resin. In this paper, a micro-debonding device was independently designed and combined with the digital image correlation (DIC) technique to track the degradation process of basalt/glass fiber-resin bonding property during the corrosion in chloride solution for 28 d. The results show that the bonding property between glass fiber and resin is better than that of basalt fiber. The interface bonding force of basalt/glass fibers is decreased by 73.9% and 71.8% after the corrosion of 28 d in NaCl solution. Matrix cracking and fiber pulling out are the main failure modes during the pull-out process. The formation of the hydrogen bond is dominated due to the bonding mode between resin and fiber matrix. However, the number of hydrogen bond atoms is reduced by the interaction between the chloride ions and the atoms at the matrix interface, thus accelerating the debonding between the fiber and resin.

, authors=Shicai LI1, Zuquan JIN1, Huamiao SONG1, 2, authorsList=Shicai LI, Zuquan JIN, Huamiao SONG, authorCompany=null, correspAuthors=Zuquan JIN, authorNote=

LI Shicai (1995-), male, Doctoral candidate. E-mail:

, correspAuthorsNote=
JIN Zuquan (1977-), male, Ph.D., Professor. E-mail:
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纤维/树脂界面黏结性能对纤维增强聚合物(FRP)筋承载过程中纤维与基体之间力的传递至关重要,但海水海砂混凝土孔溶液中氯离子扩散至纤维/树脂界面区会使得其黏结性能退化。自制纤维/树脂微脱黏装置,并与数字图像相关(DIC)技术相结合,追踪玄武岩/玻璃纤维与树脂在氯盐溶液中腐蚀28 d的黏结性能退化过程,并通过分子动力学模拟揭示了腐蚀离子导致界面黏结性能退化机制。结果表明:玻璃纤维与树脂间的黏结性能优于玄武岩纤维;玄武岩/玻璃纤维与树脂在NaCl溶液腐蚀28 d,其界面黏结力分别下降了73.9%和71.8%,拉拔过程中破坏模式以基体开裂和纤维拔出为主;树脂与纤维基底主要通过形成氢键黏结,氯离子与基底界面原子的相互作用使原有氢键原子对数量减少,加速了纤维与树脂的脱黏。

, authors=李师财1, 金祖权1, 宋华苗1, 2, authorsList=李师财, 金祖权, 宋华苗, authorCompany=null, correspAuthors=金祖权, authorNote=

李师财(1995—),男,博士研究生。

, correspAuthorsNote=
金祖权(1977—),男,博士,教授。
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LI Shicai (1995-), male, Doctoral candidate. E-mail:

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LI Shicai (1995-), male, Doctoral candidate. E-mail:

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李师财(1995—),男,博士研究生。

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李师财(1995—),男,博士研究生。

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氯盐腐蚀下纤维/树脂界面黏结退化试验与分子动力学模拟
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李师财 1 , 金祖权 1 , 宋华苗 1, 2
硅酸盐学报 | 水泥基材料研究新进展—研究论文 2023,51(5): 1136-1145
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硅酸盐学报 |水泥基材料研究新进展—研究论文 2023 , 51 (5) : 1136 -1145
氯盐腐蚀下纤维/树脂界面黏结退化试验与分子动力学模拟
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李师财1 , 金祖权1 , 宋华苗1, 2
作者信息
  • 1.海洋环境混凝土技术教育部工程研究中心,青岛理工大学,山东 青岛 266520
  • 2.中国华西工程设计建设有限公司,山东 青岛 266000
通讯作者:
金祖权(1977—),男,博士,教授。
作者简介:

李师财(1995—),男,博士研究生。

Experiment and Molecular Dynamics Simulation of Interfacial Bonding Degradation of Fiber/Resin Under Chloride Corrosion
Shicai LI1 , Zuquan JIN1 , Huamiao SONG1, 2
Affiliations
  • 1.Engineering Research Center of Concrete technology in marine environment, Ministry of Education, Qingdao University of Technology, Qingdao 266520, Shandong, China
  • 2.China Huaxi Engineering Design & Construction Co., Ltd, Qingdao 266000, Shandong, China
  • Corresponding Author:
    JIN Zuquan (1977-), male, Ph.D., Professor. E-mail:

    LI Shicai (1995-), male, Doctoral candidate. E-mail:

出版时间: 2023-05-20 doi: 10.14062/j.issn.0454-5648.20220679
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纤维/树脂界面黏结性能对纤维增强聚合物(FRP)筋承载过程中纤维与基体之间力的传递至关重要,但海水海砂混凝土孔溶液中氯离子扩散至纤维/树脂界面区会使得其黏结性能退化。自制纤维/树脂微脱黏装置,并与数字图像相关(DIC)技术相结合,追踪玄武岩/玻璃纤维与树脂在氯盐溶液中腐蚀28 d的黏结性能退化过程,并通过分子动力学模拟揭示了腐蚀离子导致界面黏结性能退化机制。结果表明:玻璃纤维与树脂间的黏结性能优于玄武岩纤维;玄武岩/玻璃纤维与树脂在NaCl溶液腐蚀28 d,其界面黏结力分别下降了73.9%和71.8%,拉拔过程中破坏模式以基体开裂和纤维拔出为主;树脂与纤维基底主要通过形成氢键黏结,氯离子与基底界面原子的相互作用使原有氢键原子对数量减少,加速了纤维与树脂的脱黏。

纤维/树脂  /  界面黏结性能  /  分子动力学  /  数字图像相关技术  /  氯离子

The force transferring between fiber and matrix is closely related to the interfacial bonding properties of fiber-resin during the loading process of fiber reinforced polymer (FRP) bars. However, its bonding properties are degraded by the diffusion of chloride ions in the pore solution of seawater sea-sand concrete into the interfacial zone of fiber-resin. In this paper, a micro-debonding device was independently designed and combined with the digital image correlation (DIC) technique to track the degradation process of basalt/glass fiber-resin bonding property during the corrosion in chloride solution for 28 d. The results show that the bonding property between glass fiber and resin is better than that of basalt fiber. The interface bonding force of basalt/glass fibers is decreased by 73.9% and 71.8% after the corrosion of 28 d in NaCl solution. Matrix cracking and fiber pulling out are the main failure modes during the pull-out process. The formation of the hydrogen bond is dominated due to the bonding mode between resin and fiber matrix. However, the number of hydrogen bond atoms is reduced by the interaction between the chloride ions and the atoms at the matrix interface, thus accelerating the debonding between the fiber and resin.

fiber/resin  /  interfacial bond property  /  molecular dynamics  /  digital image correlation technique  /  chloride ions
李师财, 金祖权, 宋华苗. 氯盐腐蚀下纤维/树脂界面黏结退化试验与分子动力学模拟. 硅酸盐学报, 2023 , 51 (5) : 1136 -1145 . DOI: 10.14062/j.issn.0454-5648.20220679
Shicai LI, Zuquan JIN, Huamiao SONG. Experiment and Molecular Dynamics Simulation of Interfacial Bonding Degradation of Fiber/Resin Under Chloride Corrosion[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (5) : 1136 -1145 . DOI: 10.14062/j.issn.0454-5648.20220679
  • 国家自然科学基金(52225905; U1806225)
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2023年第51卷第5期
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doi: 10.14062/j.issn.0454-5648.20220679
  • 接收时间:2022-08-19
  • 首发时间:2026-10-20
  • 出版时间:2023-05-20
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  • 收稿日期:2022-08-19
  • 修回日期:2022-11-26
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国家自然科学基金(52225905; U1806225)
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    1.海洋环境混凝土技术教育部工程研究中心,青岛理工大学,山东 青岛 266520
    2.中国华西工程设计建设有限公司,山东 青岛 266000

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金祖权(1977—),男,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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