Article(id=1319222303397888189, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220668, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1660579200000, receivedDateStr=2022-08-16, revisedDate=1663171200000, revisedDateStr=2022-09-15, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456707095, onlineDateStr=2026-10-20, pubDate=1674144000000, pubDateStr=2023-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456707095, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456707095, creator=13701087609, updateTime=1792456707095, updator=13701087609, issue=Issue{id=1319222240177144549, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='1', pageStart='1', pageEnd='282', issueExtLink='null', onlineDate='null', pubDate='1674144000000', pubDateStr='2023-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456692021, creator='13701087609', updateTime=1792456863865, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319222960989262349, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319222960989262350, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=133, endPage=144, ext={EN=ArticleExt(id=1319222303607603390, articleId=1319222303397888189, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Glutathione-Assisted Hydrothermal Synthesis and Electrochemical Performance of NiCo₂S₄ Electrode Material, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

As an energy storage device, supercapacitors are practically used in many fields due to their high power density and long service life. Among the components of supercapacitors, electrode materials play a key role in the performance of the device, it is thus of great significance to prepare electrode materials with superior electrochemical performance. NiCo₂S₄ was prepared by a hydrothermal method using nickel acetate and cobalt acetate as raw materials, glutathione as a morphology control agent and a sulfur source. The effect of hydrothermal reaction time on the microstructure, morphology and electrochemical performance of NiCo₂S₄ was investigated. The results show that the NiCo₂S₄ material prepared under the action of glutathione has a yolk-shell structure. The specific capacitance is 1 552.7 F/g when the current density is 0.5 A/g, and the specific capacitance can be maintained at 61.3% at 10 A/g. After 2 000 cycles, the specific capacitance retention of the material can be maintained at 79.3%. A supercapacitor can be assembled with NiCo₂S₄ and activated carbon as positive and negative electrodes, respectively. This hybrid supercapacitor can provide 33.9 W·h/kg energy density when the power density is 800 W/kg. After 2 000 charge and discharge cycles, the specific capacitance retention rate is 89%.

, authors=Jiahong ZHENG, Jiajun SHEN, authorsList=Jiahong ZHENG, Jiajun SHEN, authorCompany=null, correspAuthors=null, authorNote=, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319222303880233151, articleId=1319222303397888189, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=谷胱甘肽辅助水热合成NiCo₂S₄电极材料及其电化学性能, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

超级电容器作为一种新型储能器件，凭借其高功率密度和超长的使用寿命等优点，已被实际应用于多个领域。在超级电容器组成部件中，电极材料对器件性能优劣起着关键作用，因此制备电化学性能优异的电极材料具有重要意义。采用乙酸镍、乙酸钴为原料，还原型谷胱甘肽（GSH）为形貌控制剂和硫源，通过水热法制备NiCo₂S₄电极材料，并研究了水热反应时间对NiCo₂S₄微观结构、形貌、电化学性能的影响。结果表明：在GSH作用下制备的NiCo₂S₄材料呈现“蛋黄-蛋壳”结构；当电流密度为0.5 A/g时，比电容为1 552.7 F/g；在电流密度为10 A/g条件下可以保持61.3%的比电容；经过2 000次循环后，NiCo₂S₄电极材料的比电容保持率可以维持在79.3%。分别以NiCo₂S₄与活性炭为正负极组装一个混合型超级电容器，在功率密度为800 W/kg时可以提供33.9 W·h/kg能量密度，在2 000次充放电循环后样品的比电容保持率为89%。

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ZHENG Jiahong (1983-), female, Ph.D., Associate Professor. E-mail: jhzheng@chd.edu.cn

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ZHENG Jiahong (1983-), female, Ph.D., Associate Professor. E-mail: jhzheng@chd.edu.cn

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郑佳红（1983—），女，博士，副教授。

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郑佳红（1983—），女，博士，副教授。

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