Article(id=1319222272641061847, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220658, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1660320000000, receivedDateStr=2022-08-13, revisedDate=1661788800000, revisedDateStr=2022-08-30, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456699761, onlineDateStr=2026-10-20, pubDate=1674144000000, pubDateStr=2023-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456699761, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456699761, creator=13701087609, updateTime=1792456699761, updator=13701087609, issue=Issue{id=1319222240177144549, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='1', pageStart='1', pageEnd='282', issueExtLink='null', onlineDate='null', pubDate='1674144000000', pubDateStr='2023-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456692021, creator='13701087609', updateTime=1792456863865, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319222960989262349, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319222960989262350, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=124, endPage=132, ext={EN=ArticleExt(id=1319222273031132122, articleId=1319222272641061847, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Facile Synthesis of High-Entropy (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O Nanopowder and Its Electrochemical Properties As Supercapacitor Electrode, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

High-entropy oxides (HEO) are a novel material with the unique electrochemical properties, which are stabilized due to the high configurational entropy. In this paper, a high-entropy (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O nanopowder with the sizes of 40-65 nm and a rocksalt structure was synthesized by a polyacrylamide gel method and subsequent calcination at 900 ℃ for 2 h in the presence of a mole ratio of acrylamide/metal cations of 120∶1. The results show that the temperature of forming a single-phase (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O nanopowder decreases with the increase of the mole ratio of acrylamide/metal cations. The HEO nanopowder has a specific capacitance of 402 F/g at a current density of 1 A/g. A rate capability of 62% appears at 20 A/g. The capacitance retention is 61% after 2 000 cycles at a current density of 5 A/g. It is indicted that (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O nanopowder could be used as a prospective electrode material for supercapacitors.

, authors=Pengchao JI, Jingxin YANG, Lin TAN, Fu SUN, Xinghua SU, authorsList=Pengchao JI, Jingxin YANG, Lin TAN, Fu SUN, Xinghua SU, authorCompany=null, correspAuthors=Xinghua SU, authorNote=

JI Pengchao (1999-), male, Master candidate. E-mail:

, correspAuthorsNote=
SU Xinghua (1981-), male, Ph.D., Professor. E-mail:
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高熵氧化物是一种由高构型熵稳定的新型材料,有望具有独特的电化学性能。采用聚丙烯酰胺凝胶法制备了(Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O纳米粉体并研究了其超级电容性能。结果表明:单相(Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O纳米粉体的制备温度随着丙烯酰胺/金属阳离子摩尔比的增加而降低。当丙烯酰胺/金属阳离子摩尔比为120∶1时,在900 ℃煅烧2 h所制备的岩盐相高熵纳米粉体呈现出球形形态,粒径为40~65 nm。该高熵纳米粉体在1 A/g的电流密度下具有402 F/g的比电容;当电流密度增大到20 A/g时,仍然能保持62%的初始比电容;在电流密度为5 A/g时,经过2 000次充放电循环后,电容保持率为61%,该研究表明高熵(Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O纳米粉体在超级电容器电极材料领域具有良好的应用前景。

, authors=纪彭超, 杨静歆, 谭琳, 孙福, 苏兴华, authorsList=纪彭超, 杨静歆, 谭琳, 孙福, 苏兴华, authorCompany=null, correspAuthors=苏兴华, authorNote=

纪彭超(1999—),男,硕士研究生。

, correspAuthorsNote=
苏兴华(1981—),男,博士,教授。
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JI Pengchao (1999-), male, Master candidate. E-mail:

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纪彭超(1999—),男,硕士研究生。

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高熵(Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O纳米粉体的简易制备及超电容性能
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纪彭超 , 杨静歆 , 谭琳 , 孙福 , 苏兴华
硅酸盐学报 | 研究论文 2023,51(1): 124-132
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硅酸盐学报 |研究论文 2023 , 51 (1) : 124 -132
高熵(Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O纳米粉体的简易制备及超电容性能
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纪彭超 , 杨静歆, 谭琳, 孙福, 苏兴华
作者信息
  • 长安大学材料科学与工程学院,西安 710061
通讯作者:
苏兴华(1981—),男,博士,教授。
作者简介:

纪彭超(1999—),男,硕士研究生。

Facile Synthesis of High-Entropy (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O Nanopowder and Its Electrochemical Properties As Supercapacitor Electrode
Pengchao JI , Jingxin YANG, Lin TAN, Fu SUN, Xinghua SU
Affiliations
  • School of Materials Science and Engineering, Chang'an University, Xi'an 710061, China
  • Corresponding Author:
    SU Xinghua (1981-), male, Ph.D., Professor. E-mail:

    JI Pengchao (1999-), male, Master candidate. E-mail:

出版时间: 2023-01-20 doi: 10.14062/j.issn.0454-5648.20220658
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高熵氧化物是一种由高构型熵稳定的新型材料,有望具有独特的电化学性能。采用聚丙烯酰胺凝胶法制备了(Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O纳米粉体并研究了其超级电容性能。结果表明:单相(Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O纳米粉体的制备温度随着丙烯酰胺/金属阳离子摩尔比的增加而降低。当丙烯酰胺/金属阳离子摩尔比为120∶1时,在900 ℃煅烧2 h所制备的岩盐相高熵纳米粉体呈现出球形形态,粒径为40~65 nm。该高熵纳米粉体在1 A/g的电流密度下具有402 F/g的比电容;当电流密度增大到20 A/g时,仍然能保持62%的初始比电容;在电流密度为5 A/g时,经过2 000次充放电循环后,电容保持率为61%,该研究表明高熵(Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O纳米粉体在超级电容器电极材料领域具有良好的应用前景。

高熵氧化物  /  丙烯酰胺  /  超级电容器  /  电化学性能  /  电极材料

High-entropy oxides (HEO) are a novel material with the unique electrochemical properties, which are stabilized due to the high configurational entropy. In this paper, a high-entropy (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O nanopowder with the sizes of 40-65 nm and a rocksalt structure was synthesized by a polyacrylamide gel method and subsequent calcination at 900 ℃ for 2 h in the presence of a mole ratio of acrylamide/metal cations of 120∶1. The results show that the temperature of forming a single-phase (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O nanopowder decreases with the increase of the mole ratio of acrylamide/metal cations. The HEO nanopowder has a specific capacitance of 402 F/g at a current density of 1 A/g. A rate capability of 62% appears at 20 A/g. The capacitance retention is 61% after 2 000 cycles at a current density of 5 A/g. It is indicted that (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O nanopowder could be used as a prospective electrode material for supercapacitors.

high-entropy oxides  /  acrylamide  /  supercapacitors  /  electrochemical properties  /  electrode materials
纪彭超, 杨静歆, 谭琳, 孙福, 苏兴华. 高熵(Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O纳米粉体的简易制备及超电容性能. 硅酸盐学报, 2023 , 51 (1) : 124 -132 . DOI: 10.14062/j.issn.0454-5648.20220658
Pengchao JI, Jingxin YANG, Lin TAN, Fu SUN, Xinghua SU. Facile Synthesis of High-Entropy (Mg0.2Co0.2Ni0.2Cu0.2Zn0.2)O Nanopowder and Its Electrochemical Properties As Supercapacitor Electrode[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (1) : 124 -132 . DOI: 10.14062/j.issn.0454-5648.20220658
  • 陕西省重点研发计划项目(2021GY-250)
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2023年第51卷第1期
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doi: 10.14062/j.issn.0454-5648.20220658
  • 接收时间:2022-08-13
  • 首发时间:2026-10-20
  • 出版时间:2023-01-20
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  • 收稿日期:2022-08-13
  • 修回日期:2022-08-30
基金
陕西省重点研发计划项目(2021GY-250)
作者信息
    长安大学材料科学与工程学院,西安 710061

通讯作者:

苏兴华(1981—),男,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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