Article(id=1319222295923638402, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220608, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1658937600000, receivedDateStr=2022-07-28, revisedDate=1660579200000, revisedDateStr=2022-08-16, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456705312, onlineDateStr=2026-10-20, pubDate=1674144000000, pubDateStr=2023-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456705312, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456705312, creator=13701087609, updateTime=1792456705312, updator=13701087609, issue=Issue{id=1319222240177144549, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='1', pageStart='1', pageEnd='282', issueExtLink='null', onlineDate='null', pubDate='1674144000000', pubDateStr='2023-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456692021, creator='13701087609', updateTime=1792456863865, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319222960989262349, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319222960989262350, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=178, endPage=186, ext={EN=ArticleExt(id=1319222296116576387, articleId=1319222295923638402, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Properties of Polyvinyl Chloride/Vermiculite Nanosheet Composite Plastic, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

With the enhancement of people's awareness of environmental protection, environmentally friendly polyvinyl chloride (PVC) plastic additives are constantly promoted, and the use of natural mineral vermidemite to replace non-environmentally friendly PVC plastic additives has become a new trend in the industry. A vermiculite sheet suspension was obtained by a liquid high-speed shear/grading centrifugal method, and the vermiculite nanosheet/polyvinyl chloride (PVC) composite plastic was prepared via solvent substitution. The influence of the content of vermiculite nanosheet on the ultraviolet, thermal conductivity, thermal stability and flame-retardant performance, tensile properties was investigated. The results show that the sizes of vermiculite are 150 nm-1.1 μm, and the original structure of vermiculite preserves. When the content of vermiculite nanosheet is 15% (in mass), the tensile strength of vermiculite nanosheet/PVC composite plastic is increased by 50.8%, the limit oxygen index value is increased by 7.3%, the thermal conductivity is decreased by 17.8%, and the aging heat stability time is increased by 140 min, and the dehydrothermal degradation time is increased by 24 min. This composite plastic has superior thermal stability and ultraviolet resistance. Adding vermiculite nanosheet into PVC can improve the properties of composite plastic, which has a practical significance in the preparation of high-performance PVC product.

, authors=Xiangkun ZHANG, Haowen LIU, Jinpeng HOU, Houmei YOU, Xun DAI, Zhong LI, Weiliang TIAN, authorsList=Xiangkun ZHANG, Haowen LIU, Jinpeng HOU, Houmei YOU, Xun DAI, Zhong LI, Weiliang TIAN, authorCompany=null, correspAuthors=Weiliang TIAN, authorNote=

ZHANG Xiangkun (1997-), male, Master candidate. E-mail:

, correspAuthorsNote=
TIAN Weiliang (1977-), male, Ph.D., Professor. E-mail:
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随着人们环保意识的增强,环保型聚氯乙烯(PVC)塑料添加剂正在不断推进,利用天然矿物蛭石代替非环保PVC塑料添加剂成为行业新趋势。采用液相高速剪切/分级离心法制备了纳米蛭石片悬浮液,通过溶剂置换法制备了纳米蛭石片/PVC复合塑料,研究了纳米蛭石片含量对其紫外、导热性能,阻燃性能、热稳定性和拉伸性能的影响。结果表明:纳米蛭石片尺寸在150 nm~1.1 μm,保持了蛭石原有结构特征。纳米蛭石片添加量为15%(质量分数)时,纳米蛭石片/PVC复合塑料的拉伸强度提高了50.8%,极限氧指数提高了7.3%,导热系数降低了17.8%,老化热稳定时间提高了140 min,脱氢热解时间提高了24 min,具有优异的热稳定性能和抗紫外性能。在PVC制品中加入蛭石将会提高复合塑料的各项性能,对于高性能PVC制品制备具有重要的实际意义。

, authors=张祥坤, 刘昊文, 侯进鹏, 尤厚美, 戴勋, 李仲, 田维亮, authorsList=张祥坤, 刘昊文, 侯进鹏, 尤厚美, 戴勋, 李仲, 田维亮, authorCompany=null, correspAuthors=田维亮, authorNote=

张祥坤(1997—),男,硕士研究生。

, correspAuthorsNote=
田维亮(1977—),男,博士,教授。
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纳米蛭石片/聚氯乙烯复合塑料的制备及其性能
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张祥坤 , 刘昊文 , 侯进鹏 , 尤厚美 , 戴勋 , 李仲 , 田维亮
硅酸盐学报 | 研究论文 2023,51(1): 178-186
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硅酸盐学报 |研究论文 2023 , 51 (1) : 178 -186
纳米蛭石片/聚氯乙烯复合塑料的制备及其性能
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张祥坤 , 刘昊文, 侯进鹏, 尤厚美, 戴勋, 李仲, 田维亮
作者信息
  • 塔里木大学化学化工学院,兵团南疆化工资源利用工程实验室,新疆 阿拉尔 843300
通讯作者:
田维亮(1977—),男,博士,教授。
作者简介:

张祥坤(1997—),男,硕士研究生。

Preparation and Properties of Polyvinyl Chloride/Vermiculite Nanosheet Composite Plastic
Xiangkun ZHANG , Haowen LIU, Jinpeng HOU, Houmei YOU, Xun DAI, Zhong LI, Weiliang TIAN
Affiliations
  • College of Chemistry and Chemical Engineering, Tarim University, Engineering Laboratory of Chemical Resources Utilization in South Xinjiang of Xinjiang Production and Construction Corps, Alar 843300, Xinjiang, China
  • Corresponding Author:
    TIAN Weiliang (1977-), male, Ph.D., Professor. E-mail:

    ZHANG Xiangkun (1997-), male, Master candidate. E-mail:

出版时间: 2023-01-20 doi: 10.14062/j.issn.0454-5648.20220608
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随着人们环保意识的增强,环保型聚氯乙烯(PVC)塑料添加剂正在不断推进,利用天然矿物蛭石代替非环保PVC塑料添加剂成为行业新趋势。采用液相高速剪切/分级离心法制备了纳米蛭石片悬浮液,通过溶剂置换法制备了纳米蛭石片/PVC复合塑料,研究了纳米蛭石片含量对其紫外、导热性能,阻燃性能、热稳定性和拉伸性能的影响。结果表明:纳米蛭石片尺寸在150 nm~1.1 μm,保持了蛭石原有结构特征。纳米蛭石片添加量为15%(质量分数)时,纳米蛭石片/PVC复合塑料的拉伸强度提高了50.8%,极限氧指数提高了7.3%,导热系数降低了17.8%,老化热稳定时间提高了140 min,脱氢热解时间提高了24 min,具有优异的热稳定性能和抗紫外性能。在PVC制品中加入蛭石将会提高复合塑料的各项性能,对于高性能PVC制品制备具有重要的实际意义。

液相剥离  /  分级离心  /  纳米蛭石片  /  溶剂置换  /  有机无机复合  /  聚氯乙烯塑料

With the enhancement of people's awareness of environmental protection, environmentally friendly polyvinyl chloride (PVC) plastic additives are constantly promoted, and the use of natural mineral vermidemite to replace non-environmentally friendly PVC plastic additives has become a new trend in the industry. A vermiculite sheet suspension was obtained by a liquid high-speed shear/grading centrifugal method, and the vermiculite nanosheet/polyvinyl chloride (PVC) composite plastic was prepared via solvent substitution. The influence of the content of vermiculite nanosheet on the ultraviolet, thermal conductivity, thermal stability and flame-retardant performance, tensile properties was investigated. The results show that the sizes of vermiculite are 150 nm-1.1 μm, and the original structure of vermiculite preserves. When the content of vermiculite nanosheet is 15% (in mass), the tensile strength of vermiculite nanosheet/PVC composite plastic is increased by 50.8%, the limit oxygen index value is increased by 7.3%, the thermal conductivity is decreased by 17.8%, and the aging heat stability time is increased by 140 min, and the dehydrothermal degradation time is increased by 24 min. This composite plastic has superior thermal stability and ultraviolet resistance. Adding vermiculite nanosheet into PVC can improve the properties of composite plastic, which has a practical significance in the preparation of high-performance PVC product.

liquid phase exfoliation  /  grading centrifugal  /  vermiculite nanosheet  /  solvent substitution  /  organic-inorganic composite  /  polyvinylchloride plastics
张祥坤, 刘昊文, 侯进鹏, 尤厚美, 戴勋, 李仲, 田维亮. 纳米蛭石片/聚氯乙烯复合塑料的制备及其性能. 硅酸盐学报, 2023 , 51 (1) : 178 -186 . DOI: 10.14062/j.issn.0454-5648.20220608
Xiangkun ZHANG, Haowen LIU, Jinpeng HOU, Houmei YOU, Xun DAI, Zhong LI, Weiliang TIAN. Preparation and Properties of Polyvinyl Chloride/Vermiculite Nanosheet Composite Plastic[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (1) : 178 -186 . DOI: 10.14062/j.issn.0454-5648.20220608
  • 兵团中央引导地方科技发展资金(Z135050009017; 2022ZY015)
  • 兵团财政科技计划资助项目(2020CB019)
  • 创新群体项目(TDZKCQ201901)
  • 国家自然科学基金项目(21761029)
  • 师市科技计划项目(2019GJJ04)
  • 北京化工大学有机无机复合材料国家重点实验室开放课题(oic-202101011)
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2023年第51卷第1期
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doi: 10.14062/j.issn.0454-5648.20220608
  • 接收时间:2022-07-28
  • 首发时间:2026-10-20
  • 出版时间:2023-01-20
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出版历史
  • 收稿日期:2022-07-28
  • 修回日期:2022-08-16
基金
兵团中央引导地方科技发展资金(Z135050009017; 2022ZY015)
兵团财政科技计划资助项目(2020CB019)
创新群体项目(TDZKCQ201901)
国家自然科学基金项目(21761029)
师市科技计划项目(2019GJJ04)
北京化工大学有机无机复合材料国家重点实验室开放课题(oic-202101011)
作者信息
    塔里木大学化学化工学院,兵团南疆化工资源利用工程实验室,新疆 阿拉尔 843300

通讯作者:

田维亮(1977—),男,博士,教授。
参考文献
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20220608
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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