Article(id=1319222260985082847, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220593, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1658246400000, receivedDateStr=2022-07-20, revisedDate=1663084800000, revisedDateStr=2022-09-14, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456696983, onlineDateStr=2026-10-20, pubDate=1674144000000, pubDateStr=2023-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456696983, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456696983, creator=13701087609, updateTime=1792456696983, updator=13701087609, issue=Issue{id=1319222240177144549, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='1', pageStart='1', pageEnd='282', issueExtLink='null', onlineDate='null', pubDate='1674144000000', pubDateStr='2023-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456692021, creator='13701087609', updateTime=1792456863865, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319222960989262349, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319222960989262350, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222240177144549, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=117, endPage=123, ext={EN=ArticleExt(id=1319222262478255072, articleId=1319222260985082847, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Regeneration of Lithium Manganate Cathode Material from Malic Acid Leachate of High Manganese Cathode Material of Spent Lithium-ion Batteries, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

Waste lithium batteries have become a research hotspot due to their extremely high resources and hazards. Hygrometallurgical recycling is the main existing method for processing waste lithium battery cathode materials, and the recovery of valuable metal elements from the leaching solutions is the key to hygrometallurgical recovery of waste cathode materials. In this paper, nickel, cobalt and manganese were precipitated from a malic acid leaching solution of high manganese cathode material of waste lithium battery as raw material via ozone oxidation, and the optimal precipitation conditions were obtained. The results show that the precipitation rates of nickel, cobalt, and manganese are 18.2%, 41.5%, and 85.8%, and the contents of nickel, cobalt, and manganese in the ozone precipitation slag are 0.85%, 1.63%, and 41.3%, respectively under the optimal precipitation conditions. The ozone oxidation precipitation slag is a high manganese-based precursor, and the precursor is regenerated into LiMn2O4 cathode material after supplementing lithium. The first discharge specific capacity of this regenerate cathode material is 95.4 mA·h/g, and the first charge-discharge efficiency is 84%. The discharge specific capacity retention rate is 67.4% at a high rate, and the discharge specific capacity retention rate after 100 cycles is 80%.

, authors=Pengyuan CUI1, Xiaohua YU1, Yonggang LI2, Yan LIN1, Qingfeng SHEN1, Lu WANG1, Zhaoyang ZHANG1, authorsList=Pengyuan CUI, Xiaohua YU, Yonggang LI, Yan LIN, Qingfeng SHEN, Lu WANG, Zhaoyang ZHANG, authorCompany=null, correspAuthors=Xiaohua YU, authorNote=

CUI Pengyuan (1995-), male, Master candidate. E-mail:

, correspAuthorsNote=
YU Xiaohua (1978-), female, Associate Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319222263023514593, articleId=1319222260985082847, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=废旧锂电池高锰正极材料苹果酸浸出液再生锰酸锂正极材料, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

废旧锂电池因其具有极高的资源性和危害性成为研究的热点,湿法回收是目前处理废旧锂电正极材料的主要方法,而从废旧正极材料浸出液中回收有价金属元素已成为湿法回收的关键。因此,以废旧锂电池高锰正极材料苹果酸浸出液为原料,通过臭氧氧化沉淀镍、钴、锰得到最佳沉淀条件,并制备出高锰基前驱体。研究发现:在最佳沉淀条件下,镍、钴、锰的沉淀率分别为18.2%、41.5%、85.8%;臭氧沉淀渣中的镍、钴、锰含量分别为0.85%、1.63%、41.30%。可以看出,该臭氧氧化沉淀渣为高锰基前驱体,前驱体经补锂再生为LiMn2O4正极材料,该正极材料的首次放电比容量为95.4 mA·h/g,首次充放电效率为84%,高倍率下的放电比容量保持率为67.4%,100次循环后的放电比容量保持率为80%。

, authors=崔鹏媛1, 俞小花1, 李永刚2, 林艳1, 沈庆峰1, 王露1, 张钊洋1, authorsList=崔鹏媛, 俞小花, 李永刚, 林艳, 沈庆峰, 王露, 张钊洋, authorCompany=null, correspAuthors=俞小花, authorNote=

崔鹏媛(1995—),男,硕士研究生。

, correspAuthorsNote=
俞小花(1978—),女,副教授。
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=F7HT+8rPsDQeCpROaKUX6A==, magXml=/plO7D6nnIh7yYMiTBWC+A==, pdfUrl=null, pdf=Hx3ghqXz4wDFB7CmRvUkMA==, pdfFileSize=579515, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=PQWQevPOaPyRG4I/yarKXw==, mapNumber=null, fund=null)}, authors=[Author(id=1322521491380482219, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=2543629892@qq.com, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322521491468562605, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521491380482219, language=EN, stringName=Pengyuan CUI, firstName=Pengyuan, middleName=null, lastName=CUI, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China, bio={"content":"

CUI Pengyuan (1995-), male, Master candidate. E-mail:

"}, bioImg=null, bioContent=

CUI Pengyuan (1995-), male, Master candidate. E-mail:

, aboutCorrespAuthor=null), CN=AuthorExt(id=1322521491560837294, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521491380482219, language=CN, stringName=崔鹏媛, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.昆明理工大学冶金与能源工程学院,昆明 650093, bio={"content":"

崔鹏媛(1995—),男,硕士研究生。

"}, bioImg=null, bioContent=

崔鹏媛(1995—),男,硕士研究生。

, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322521491200127140, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, xref=1., ext=[AuthorCompanyExt(id=1322521491208515749, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China), AuthorCompanyExt(id=1322521491216904358, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.昆明理工大学冶金与能源工程学院,昆明 650093)])]), Author(id=1322521491627946160, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, orderNo=1, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=85208478@qq.com, emailSecond=null, emailThird=null, correspondingAuthor=1, authorType=1, ext={EN=AuthorExt(id=1322521491720220850, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521491627946160, language=EN, stringName=Xiaohua YU, firstName=Xiaohua, middleName=null, lastName=YU, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322521491795718323, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521491627946160, language=CN, stringName=俞小花, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.昆明理工大学冶金与能源工程学院,昆明 650093, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322521491200127140, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, xref=1., ext=[AuthorCompanyExt(id=1322521491208515749, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China), AuthorCompanyExt(id=1322521491216904358, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.昆明理工大学冶金与能源工程学院,昆明 650093)])]), Author(id=1322521491862827189, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, orderNo=2, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322521491929936055, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521491862827189, language=EN, stringName=Yonggang LI, firstName=Yonggang, middleName=null, lastName=LI, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2.Yunnan Copper Science & Technology Development Co., Ltd., Kunming 650101, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322521493607657657, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521491862827189, language=CN, stringName=李永刚, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2.云南铜业科技发展股份有限公司,昆明 650101, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322521491292401831, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, xref=2., ext=[AuthorCompanyExt(id=1322521491304984744, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491292401831, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.Yunnan Copper Science & Technology Development Co., Ltd., Kunming 650101, China), AuthorCompanyExt(id=1322521491313373353, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491292401831, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.云南铜业科技发展股份有限公司,昆明 650101)])]), Author(id=1322521493708320955, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, orderNo=3, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322521493800595645, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521493708320955, language=EN, stringName=Yan LIN, firstName=Yan, middleName=null, lastName=LIN, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322521493913841854, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521493708320955, language=CN, stringName=林艳, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.昆明理工大学冶金与能源工程学院,昆明 650093, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322521491200127140, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, xref=1., ext=[AuthorCompanyExt(id=1322521491208515749, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China), AuthorCompanyExt(id=1322521491216904358, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.昆明理工大学冶金与能源工程学院,昆明 650093)])]), Author(id=1322521493985145024, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, orderNo=4, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322521494064836802, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521493985145024, language=EN, stringName=Qingfeng SHEN, firstName=Qingfeng, middleName=null, lastName=SHEN, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322521494123557059, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521493985145024, language=CN, stringName=沈庆峰, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.昆明理工大学冶金与能源工程学院,昆明 650093, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322521491200127140, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, xref=1., ext=[AuthorCompanyExt(id=1322521491208515749, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China), AuthorCompanyExt(id=1322521491216904358, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.昆明理工大学冶金与能源工程学院,昆明 650093)])]), Author(id=1322521494190665925, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, orderNo=5, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322521494261969095, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521494190665925, language=EN, stringName=Lu WANG, firstName=Lu, middleName=null, lastName=WANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322521494329077960, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521494190665925, language=CN, stringName=王露, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.昆明理工大学冶金与能源工程学院,昆明 650093, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322521491200127140, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, xref=1., ext=[AuthorCompanyExt(id=1322521491208515749, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China), AuthorCompanyExt(id=1322521491216904358, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.昆明理工大学冶金与能源工程学院,昆明 650093)])]), Author(id=1322521494387798218, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, orderNo=6, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322521494467489996, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521494387798218, language=EN, stringName=Zhaoyang ZHANG, firstName=Zhaoyang, middleName=null, lastName=ZHANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322521494538793165, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521494387798218, language=CN, stringName=张钊洋, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.昆明理工大学冶金与能源工程学院,昆明 650093, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322521491200127140, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, xref=1., ext=[AuthorCompanyExt(id=1322521491208515749, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China), AuthorCompanyExt(id=1322521491216904358, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.昆明理工大学冶金与能源工程学院,昆明 650093)])])], keywords=[Keyword(id=1322521494668816590, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, language=EN, orderNo=1, keyword=spent lithium-ion batteries), Keyword(id=1322521494727536847, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, language=EN, orderNo=2, keyword=ozone), Keyword(id=1322521494798840016, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, language=EN, orderNo=3, keyword=oxidation precipitation), Keyword(id=1322521494865948881, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, language=EN, orderNo=4, keyword=regenerated cathode material), Keyword(id=1322521494928863442, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, language=EN, orderNo=5, keyword=charge-discharge performance), Keyword(id=1322521495000166611, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, language=CN, orderNo=1, keyword=废旧锂电池), Keyword(id=1322521495071469780, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, language=CN, orderNo=2, keyword=臭氧), Keyword(id=1322521495142772949, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, language=CN, orderNo=3, keyword=氧化沉淀), Keyword(id=1322521495222464726, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, language=CN, orderNo=4, keyword=再生正极材料), Keyword(id=1322521495289573591, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, language=CN, orderNo=5, keyword=充放电性能)], refs=null, funds=[Fund(id=1322521495427985624, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, awardId=2019YFC1907900, language=CN, fundingSource=国家重点研发计划项目(2019YFC1907900), fundOrder=null, country=null), Fund(id=1322521495490900185, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, awardId=YNWR-QNBJ-2018-327, language=CN, fundingSource=云南省万人计划项目(YNWR-QNBJ-2018-327), fundOrder=null, country=null)], companyList=[AuthorCompany(id=1322521491200127140, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, xref=1., ext=[AuthorCompanyExt(id=1322521491208515749, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China), AuthorCompanyExt(id=1322521491216904358, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.昆明理工大学冶金与能源工程学院,昆明 650093)]), AuthorCompany(id=1322521491292401831, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, xref=2., ext=[AuthorCompanyExt(id=1322521491304984744, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491292401831, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.Yunnan Copper Science & Technology Development Co., Ltd., Kunming 650101, China), AuthorCompanyExt(id=1322521491313373353, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491292401831, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.云南铜业科技发展股份有限公司,昆明 650101)])], figs=null, attaches=null, journal=Journal(id=1263186332462366751, delFlag=0, nameCn=硅酸盐学报, nameEn=Journal of the Chinese Ceramic Society, nameHistory1=null, nameHistory2=null, issn=0454-5648, eissn=null, cn=11-2310/TQ, coden=null, periodic=0, language=CN, oaType=null, ccby=null, superviseOffice=null, ownerOffice=null, pubOffice=null, editorOffice=null, officeType=null, aims=null, clcCode=null, officeProv=null, officeCity=null, officeAddr=null, officeZip=null, officeEmail=null, officePhone=null, editDirector=null, officeDirector=null, officeDirectorPhone=null, officeStaffNum=null, officeEmpNum=null, coverPicUrl=8Qg1+Is+LeRD1Lv6UJcXRg==, journalPrice=null, startedYear=null, abbrevIsoEn=Journal of the Chinese Ceramic Society, journalRemark=null, publicationField=null, createdTime=1779096690528, updatedTime=1788951192520, createdBy=18614031015, updatedBy=13041195026, firstLetterCn=G, firstLetterEn=G, subjectCode=Engineering, subjectName=null, subjectCodeEn=Engineering, subjectNameEn=null, picCn=8Qg1+Is+LeRD1Lv6UJcXRg==, picEn=AY9tl+TwuKtB81GF+w4WAg==, jcr=null, cjcr=null, exts=[JournalExt(id=1304519110767960749, language=CN, name=硅酸盐学报, nameHistory1=null, nameHistory2=null, managedBy=, sponsoredBy=, publishedBy=, editorOffice=, officeProv=null, officeCity=null, officeAddr=, officeZip=, editDirector=, officeDirector=null, officePhone=null, coverPicUrl=null, journalRemark=, submitArticleUrl=null, websiteUrl=, createdTime=1788951192800, updatedTime=1788951192800, createdBy=13041195026, updatedBy=13041195026, submissionGuidelinesUrl=, submissionAuthorUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=1, submissionEditorUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=3, submissionReviewUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=2, submissionCeEditorUrl=, submissionAeEditorUrl=, option={"copyright":""}), JournalExt(id=1304519110839263918, language=EN, name=Journal of the Chinese Ceramic Society, nameHistory1=null, nameHistory2=null, managedBy=, sponsoredBy=, publishedBy=, editorOffice=, officeProv=null, officeCity=null, officeAddr=, officeZip=, editDirector=, officeDirector=null, officePhone=null, coverPicUrl=null, journalRemark=, submitArticleUrl=null, websiteUrl=, createdTime=1788951192817, updatedTime=1788951192817, createdBy=13041195026, updatedBy=13041195026, submissionGuidelinesUrl=, submissionAuthorUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=1, submissionEditorUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=3, submissionReviewUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=2, submissionCeEditorUrl=, submissionAeEditorUrl=, option={"copyright":""})], databaseList=null, tenantJournalId=1263187385517883426, websiteList=[Website(id=1263188159895093557, webName=null, webTitle=null, webDomain=null, webCopyrigh=null, webIpcNo=null, seoTitle=null, seoKeywords=null, seoDescription=null, tenantJournalId=null, journalId=1263187385517883426, journalNameCn=null, journalNameEn=null, grayFlag=null, tenantId=1146029695717560320, platformId=null, journalGroupId=null, journalGroupNameCn=null, journalGroupNameEn=null, type=1, domain=https://castjournals.cast.org.cn/joweb/gsyxb/CN, language=CN, createTime=1779097126220, createBy=18614031015, updateTime=1779097837121, updateBy=18614031015, name=硅酸盐学报-中文, tplId=1146099689490845704, title=硅酸盐学报, delFlag=0, indexPage=/home, props=[WebsiteProps(id=1263191261578649862, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=articleTextType, value=kx, createTime=1779097865719, updateTime=1779097865719, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261545095427, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=banner, value=null, createTime=1779097865711, updateTime=1779097865711, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261599621385, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=grayFlag, value=0, createTime=1779097865724, updateTime=1779097865724, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261532512514, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=logo, value=https://castjournals.cast.org.cn/joweb/gsyxb/CN/file/pic?fileId=Oqq9gXZG0JiYeHvLNwX/eg==, createTime=1779097865708, updateTime=1779097865708, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261620592907, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=minRunFlag, value=0, createTime=1779097865729, updateTime=1779097865729, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261574455557, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=picServerUrl, value=https://castjournals.cast.org.cn/joweb/gsyxb/CN/file/pic, createTime=1779097865718, updateTime=1779097865718, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261616398602, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=silenceFlag, value=0, createTime=1779097865728, updateTime=1779097865728, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261566066948, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=staticResourcePath, value=https://castjournals.cast.org.cn/joweb/cast_kjdb_cn_619/, createTime=1779097865716, updateTime=1779097865716, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261587038471, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=themeColor, value=null, createTime=1779097865721, updateTime=1779097865721, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261591232776, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=themeStyle, value=null, createTime=1779097865722, updateTime=1779097865722, creator=18614031015, updator=18614031015)]), Website(id=1263188160188694841, webName=null, webTitle=null, webDomain=null, webCopyrigh=null, webIpcNo=null, seoTitle=null, seoKeywords=null, seoDescription=null, tenantJournalId=null, journalId=1263187385517883426, journalNameCn=null, journalNameEn=null, grayFlag=null, tenantId=1146029695717560320, platformId=null, journalGroupId=null, journalGroupNameCn=null, journalGroupNameEn=null, type=1, domain=https://castjournals.cast.org.cn/joweb/gsyxb/EN, language=EN, createTime=1779097126348, createBy=18614031015, updateTime=1779097825280, updateBy=18614031015, name=硅酸盐学报-英文, tplId=1146101810881728533, title=Journal of the Chinese Ceramic Society, delFlag=0, indexPage=/home, props=[WebsiteProps(id=1263191231102836987, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=articleTextType, value=kx, createTime=1779097858453, updateTime=1779097858453, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231052505336, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=banner, value=null, createTime=1779097858441, updateTime=1779097858441, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231186723070, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=grayFlag, value=0, createTime=1779097858473, updateTime=1779097858473, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231039922423, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=logo, value=https://castjournals.cast.org.cn/joweb/gsyxb/EN/file/pic?fileId=Oqq9gXZG0JiYeHvLNwX/eg==, createTime=1779097858438, updateTime=1779097858438, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231358689536, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=minRunFlag, value=0, createTime=1779097858514, updateTime=1779097858514, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231094448378, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=picServerUrl, value=https://castjournals.cast.org.cn/joweb/gsyxb/EN/file/pic, createTime=1779097858451, updateTime=1779097858451, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231195111679, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=silenceFlag, value=0, createTime=1779097858475, updateTime=1779097858475, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231086059769, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=staticResourcePath, value=https://castjournals.cast.org.cn/joweb/cast_kjdb_en_623/, createTime=1779097858449, updateTime=1779097858449, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231111225596, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=themeColor, value=null, createTime=1779097858455, updateTime=1779097858455, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231144780029, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=themeStyle, value=null, createTime=1779097858463, updateTime=1779097858463, creator=18614031015, updator=18614031015)])], journalTitle=硅酸盐学报, weixinUrl=null, journalUrl=https://jccsoc.cbpt.cnki.net/, iacademicId=null, status=1, seqNo=null, journalTitleEn=Journal of the Chinese Ceramic Society, journalPhotoCn=8Qg1+Is+LeRD1Lv6UJcXRg==, journalPhotoEn=AY9tl+TwuKtB81GF+w4WAg==, journalFirstLetter=G, journalRecommend=null, journalNew=null, journalCollection=null, jcrJf=null, cjcrJf=null, jcrJfStr=null, cjcrJfStr=null, submissionFirstDecision=null, sciSubjectClassification=null, casSubjectClassification=null, citeScore=null, totalCitationFrequency=null, icpCode=null, psCode=null, advertisingLicenseCode=null, copyrightInformation=null, country=null, option=, provinceCode=null, provinceName=null, collectFlag=false, interPubPlatform=, interPubPlatformUrl=null), detailUrlCn=https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20220593, detailUrlEn=https://castjournals.cast.org.cn/joweb/gsyxb/EN/10.14062/j.issn.0454-5648.20220593, pdfUrlCn=https://castjournals.cast.org.cn/joweb/gsyxb/CN/PDF/10.14062/j.issn.0454-5648.20220593, pdfUrlEn=https://castjournals.cast.org.cn/joweb/gsyxb/EN/PDF/10.14062/j.issn.0454-5648.20220593, aliStartDate=0, aliEndDate=0, collectionFlag=false, citedCount=null, citedUrl=null, previewStatus=0, delFlag=0, hasFullText=0, orderTime=1674144000000, fullTextJson=null, articleText=null, reference=null)
收藏切换
废旧锂电池高锰正极材料苹果酸浸出液再生锰酸锂正极材料
收藏切换
PDF下载
崔鹏媛 1 , 俞小花 1 , 李永刚 2 , 林艳 1 , 沈庆峰 1 , 王露 1 , 张钊洋 1
硅酸盐学报 | 研究论文 2023,51(1): 117-123
收起
收藏切换
硅酸盐学报 |研究论文 2023 , 51 (1) : 117 -123
废旧锂电池高锰正极材料苹果酸浸出液再生锰酸锂正极材料
全屏
[Author(id=1322521491380482219, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=2543629892@qq.com, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322521491468562605, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521491380482219, language=EN, stringName=Pengyuan CUI, firstName=Pengyuan, middleName=null, lastName=CUI, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China, bio={"content":"

CUI Pengyuan (1995-), male, Master candidate. E-mail:

"}, bioImg=null, bioContent=

CUI Pengyuan (1995-), male, Master candidate. E-mail:

, aboutCorrespAuthor=null), CN=AuthorExt(id=1322521491560837294, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521491380482219, language=CN, stringName=崔鹏媛, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.昆明理工大学冶金与能源工程学院,昆明 650093, bio={"content":"

崔鹏媛(1995—),男,硕士研究生。

"}, bioImg=null, bioContent=

崔鹏媛(1995—),男,硕士研究生。

, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322521491200127140, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, xref=1., ext=[AuthorCompanyExt(id=1322521491208515749, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China), AuthorCompanyExt(id=1322521491216904358, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.昆明理工大学冶金与能源工程学院,昆明 650093)])]), Author(id=1322521491627946160, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, orderNo=1, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=85208478@qq.com, emailSecond=null, emailThird=null, correspondingAuthor=1, authorType=1, ext={EN=AuthorExt(id=1322521491720220850, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521491627946160, language=EN, stringName=Xiaohua YU, firstName=Xiaohua, middleName=null, lastName=YU, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322521491795718323, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521491627946160, language=CN, stringName=俞小花, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.昆明理工大学冶金与能源工程学院,昆明 650093, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322521491200127140, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, xref=1., ext=[AuthorCompanyExt(id=1322521491208515749, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China), AuthorCompanyExt(id=1322521491216904358, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.昆明理工大学冶金与能源工程学院,昆明 650093)])]), Author(id=1322521491862827189, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, orderNo=2, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322521491929936055, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521491862827189, language=EN, stringName=Yonggang LI, firstName=Yonggang, middleName=null, lastName=LI, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2.Yunnan Copper Science & Technology Development Co., Ltd., Kunming 650101, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322521493607657657, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521491862827189, language=CN, stringName=李永刚, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2.云南铜业科技发展股份有限公司,昆明 650101, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322521491292401831, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, xref=2., ext=[AuthorCompanyExt(id=1322521491304984744, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491292401831, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.Yunnan Copper Science & Technology Development Co., Ltd., Kunming 650101, China), AuthorCompanyExt(id=1322521491313373353, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491292401831, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.云南铜业科技发展股份有限公司,昆明 650101)])]), Author(id=1322521493708320955, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, orderNo=3, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322521493800595645, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521493708320955, language=EN, stringName=Yan LIN, firstName=Yan, middleName=null, lastName=LIN, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322521493913841854, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521493708320955, language=CN, stringName=林艳, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.昆明理工大学冶金与能源工程学院,昆明 650093, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322521491200127140, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, xref=1., ext=[AuthorCompanyExt(id=1322521491208515749, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China), AuthorCompanyExt(id=1322521491216904358, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.昆明理工大学冶金与能源工程学院,昆明 650093)])]), Author(id=1322521493985145024, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, orderNo=4, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322521494064836802, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521493985145024, language=EN, stringName=Qingfeng SHEN, firstName=Qingfeng, middleName=null, lastName=SHEN, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322521494123557059, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521493985145024, language=CN, stringName=沈庆峰, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.昆明理工大学冶金与能源工程学院,昆明 650093, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322521491200127140, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, xref=1., ext=[AuthorCompanyExt(id=1322521491208515749, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China), AuthorCompanyExt(id=1322521491216904358, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.昆明理工大学冶金与能源工程学院,昆明 650093)])]), Author(id=1322521494190665925, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, orderNo=5, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322521494261969095, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521494190665925, language=EN, stringName=Lu WANG, firstName=Lu, middleName=null, lastName=WANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322521494329077960, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521494190665925, language=CN, stringName=王露, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.昆明理工大学冶金与能源工程学院,昆明 650093, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322521491200127140, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, xref=1., ext=[AuthorCompanyExt(id=1322521491208515749, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China), AuthorCompanyExt(id=1322521491216904358, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.昆明理工大学冶金与能源工程学院,昆明 650093)])]), Author(id=1322521494387798218, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, orderNo=6, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322521494467489996, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521494387798218, language=EN, stringName=Zhaoyang ZHANG, firstName=Zhaoyang, middleName=null, lastName=ZHANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322521494538793165, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, authorId=1322521494387798218, language=CN, stringName=张钊洋, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.昆明理工大学冶金与能源工程学院,昆明 650093, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322521491200127140, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, xref=1., ext=[AuthorCompanyExt(id=1322521491208515749, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China), AuthorCompanyExt(id=1322521491216904358, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319222260985082847, companyId=1322521491200127140, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.昆明理工大学冶金与能源工程学院,昆明 650093)])])]
崔鹏媛1 , 俞小花1 , 李永刚2, 林艳1, 沈庆峰1, 王露1, 张钊洋1
作者信息
  • 1.昆明理工大学冶金与能源工程学院,昆明 650093
  • 2.云南铜业科技发展股份有限公司,昆明 650101
通讯作者:
俞小花(1978—),女,副教授。
作者简介:

崔鹏媛(1995—),男,硕士研究生。

Regeneration of Lithium Manganate Cathode Material from Malic Acid Leachate of High Manganese Cathode Material of Spent Lithium-ion Batteries
Pengyuan CUI1 , Xiaohua YU1 , Yonggang LI2, Yan LIN1, Qingfeng SHEN1, Lu WANG1, Zhaoyang ZHANG1
Affiliations
  • 1.Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
  • 2.Yunnan Copper Science & Technology Development Co., Ltd., Kunming 650101, China
  • Corresponding Author:
    YU Xiaohua (1978-), female, Associate Professor. E-mail:

    CUI Pengyuan (1995-), male, Master candidate. E-mail:

出版时间: 2023-01-20 doi: 10.14062/j.issn.0454-5648.20220593
文章导航
收藏切换

废旧锂电池因其具有极高的资源性和危害性成为研究的热点,湿法回收是目前处理废旧锂电正极材料的主要方法,而从废旧正极材料浸出液中回收有价金属元素已成为湿法回收的关键。因此,以废旧锂电池高锰正极材料苹果酸浸出液为原料,通过臭氧氧化沉淀镍、钴、锰得到最佳沉淀条件,并制备出高锰基前驱体。研究发现:在最佳沉淀条件下,镍、钴、锰的沉淀率分别为18.2%、41.5%、85.8%;臭氧沉淀渣中的镍、钴、锰含量分别为0.85%、1.63%、41.30%。可以看出,该臭氧氧化沉淀渣为高锰基前驱体,前驱体经补锂再生为LiMn2O4正极材料,该正极材料的首次放电比容量为95.4 mA·h/g,首次充放电效率为84%,高倍率下的放电比容量保持率为67.4%,100次循环后的放电比容量保持率为80%。

废旧锂电池  /  臭氧  /  氧化沉淀  /  再生正极材料  /  充放电性能

Waste lithium batteries have become a research hotspot due to their extremely high resources and hazards. Hygrometallurgical recycling is the main existing method for processing waste lithium battery cathode materials, and the recovery of valuable metal elements from the leaching solutions is the key to hygrometallurgical recovery of waste cathode materials. In this paper, nickel, cobalt and manganese were precipitated from a malic acid leaching solution of high manganese cathode material of waste lithium battery as raw material via ozone oxidation, and the optimal precipitation conditions were obtained. The results show that the precipitation rates of nickel, cobalt, and manganese are 18.2%, 41.5%, and 85.8%, and the contents of nickel, cobalt, and manganese in the ozone precipitation slag are 0.85%, 1.63%, and 41.3%, respectively under the optimal precipitation conditions. The ozone oxidation precipitation slag is a high manganese-based precursor, and the precursor is regenerated into LiMn2O4 cathode material after supplementing lithium. The first discharge specific capacity of this regenerate cathode material is 95.4 mA·h/g, and the first charge-discharge efficiency is 84%. The discharge specific capacity retention rate is 67.4% at a high rate, and the discharge specific capacity retention rate after 100 cycles is 80%.

spent lithium-ion batteries  /  ozone  /  oxidation precipitation  /  regenerated cathode material  /  charge-discharge performance
崔鹏媛, 俞小花, 李永刚, 林艳, 沈庆峰, 王露, 张钊洋. 废旧锂电池高锰正极材料苹果酸浸出液再生锰酸锂正极材料. 硅酸盐学报, 2023 , 51 (1) : 117 -123 . DOI: 10.14062/j.issn.0454-5648.20220593
Pengyuan CUI, Xiaohua YU, Yonggang LI, Yan LIN, Qingfeng SHEN, Lu WANG, Zhaoyang ZHANG. Regeneration of Lithium Manganate Cathode Material from Malic Acid Leachate of High Manganese Cathode Material of Spent Lithium-ion Batteries[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (1) : 117 -123 . DOI: 10.14062/j.issn.0454-5648.20220593
  • 国家重点研发计划项目(2019YFC1907900)
  • 云南省万人计划项目(YNWR-QNBJ-2018-327)
参考文献 引证文献
排序方式:
2023年第51卷第1期
PDF下载
56
14
引用本文
BibTeX
文章信息
doi: 10.14062/j.issn.0454-5648.20220593
  • 接收时间:2022-07-20
  • 首发时间:2026-10-20
  • 出版时间:2023-01-20
补充材料
相关文章
文章信息
作者
出版历史
  • 收稿日期:2022-07-20
  • 修回日期:2022-09-14
基金
国家重点研发计划项目(2019YFC1907900)
云南省万人计划项目(YNWR-QNBJ-2018-327)
作者信息
    1.昆明理工大学冶金与能源工程学院,昆明 650093
    2.云南铜业科技发展股份有限公司,昆明 650101

通讯作者:

俞小花(1978—),女,副教授。
参考文献
分享链接
https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20220593
分享至
全文二维码

扫描看全文

引用本文
BibTeX
本文的引用情况
2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
关闭全屏