Article(id=1319237199854416186, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220471, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1654876800000, receivedDateStr=2022-06-11, revisedDate=1660147200000, revisedDateStr=2022-08-11, acceptedDate=null, acceptedDateStr=null, onlineDate=1792460258686, onlineDateStr=2026-10-20, pubDate=1671465600000, pubDateStr=2022-12-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792460258686, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792460258686, creator=13701087609, updateTime=1792460258686, updator=13701087609, issue=Issue{id=1319237171312177253, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='12', pageStart='3091', pageEnd='3336', issueExtLink='null', onlineDate='null', pubDate='1671465600000', pubDateStr='2022-12-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792460251882, creator='13701087609', updateTime=1792460721974, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319239143067071226, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319239143067071227, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=3230, endPage=3235, ext={EN=ArticleExt(id=1319237200076714299, articleId=1319237199854416186, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of Sintering Process on Phase, Microstructure and Optical Properties of MgAl2O4 Transparent Ceramics, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

MgAl2O4 transparent ceramic is a superior mid-infrared material, which is widely used in military and civil fields. In this paper, the effect of sintering process on the phase, microstructure and optical properties of magnesia alumina spinel transparent ceramics was investigated, and the sintering process route suitable for high-quality magnesia alumina spinel transparent ceramics was determined, which is of great significance for accelerating the industrialization of large-scale transparent ceramic armor materials. The results show that Li ions in hot pressed (HP) MgAl2O4 transparent ceramics may exist in the form of LiAlO2. The preferential growth surface of MgAl2O4 transparent ceramics obtained by hot isostatic pressing (HIP) sintering process is (311). Al and Mg ions of MgAl2O4 ceramics prepared by HP and HIP sintering deviate from the stoichiometric ratio, and Al/Mg ratio is greater than 2. The small grains in the ceramics increase with the increase of HIP pressure, and the grain size of MgAl2O4 ceramics is within 20-40 μm, which is conducive to improving the average transmittance of 3-5 μm. Based on the results by hot isostatic pressing test, the HIP sintering temperature of 1 750 ℃ and the pressure of 170 MPa are conducive to improving the average infrared transmittance (>85 %). In addition, the HIP sintering time has little effect on improving the infrared transmittance of MgAl2O4 transparent ceramics.

, authors=Li GUO1, Yongtian ZHAO1, Hongchun SHI1, Bo CAO1, Yuyang LIU2, Guantong CHEN3, Ansheng ZHENG1, Yuanfei MA1, Quan LIN1, Xiaohua LIU1, authorsList=Li GUO, Yongtian ZHAO, Hongchun SHI, Bo CAO, Yuyang LIU, Guantong CHEN, Ansheng ZHENG, Yuanfei MA, Quan LIN, Xiaohua LIU, authorCompany=null, correspAuthors=Hongchun SHI, authorNote=

GUO Li (1991-), male, Master, Engineer. E-mail:

, correspAuthorsNote=
SHI Hongchun (1977-), male, Master, Senior Engineer. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319237200559059260, articleId=1319237199854416186, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=烧结工艺对镁铝尖晶石透明陶瓷物相、显微结构及光学性能的影响, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

镁铝尖晶石透明陶瓷是一种优异的中红外材料,被广泛应用在军事领域和民用领域,具有典型的军民通用特点。本工作研究了烧结工艺对镁铝尖晶石透明陶瓷物相、显微结构及光学性能的影响,确定了适合高质量镁铝尖晶石透明陶瓷烧结工艺路线,对加快大尺寸透明陶瓷装甲材料产业化具有重要意义。结果表明:热压MgAl2O4透明陶瓷中Li离子可能以LiAlO2形式存在;热等静压MgAl2O4透明陶瓷的优先取向生长面为(311);热压和热等静压工艺制备的MgAl2O4陶瓷中Al离子、Mg离子偏离化学计量配比且Al和Mg摩尔比大于2,随着热等静压压力增大,陶瓷内部小晶粒增多,同时发现MgAl2O4陶瓷晶粒尺寸控制在20~40 μm有利于提升3~5 μm平均透过率,处理温度1 750 ℃、压力170 MPa条件下有利于提升MgAl2O4透明陶瓷3~5 μm波段的平均透过率,平均透过率大于85 %。同时,发现热等静压烧结时间对提升MgAl2O4透明陶瓷的红外透过率作用较小。

, authors=郭立1, 赵永田1, 石红春1, 曹波1, 刘宇阳2, 陈观通3, 郑安生1, 马远飞1, 林泉1, 刘晓华1, authorsList=郭立, 赵永田, 石红春, 曹波, 刘宇阳, 陈观通, 郑安生, 马远飞, 林泉, 刘晓华, authorCompany=null, correspAuthors=石红春, authorNote=

郭立(1991—),男,硕士,工程师。

, correspAuthorsNote=
石红春(1977—),男,硕士,高级工程师。
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烧结工艺对镁铝尖晶石透明陶瓷物相、显微结构及光学性能的影响
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郭立 1 , 赵永田 1 , 石红春 1 , 曹波 1 , 刘宇阳 2 , 陈观通 3 , 郑安生 1 , 马远飞 1 , 林泉 1 , 刘晓华 1
硅酸盐学报 | 研究论文 2022,50(12): 3230-3235
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硅酸盐学报 |研究论文 2022 , 50 (12) : 3230 -3235
烧结工艺对镁铝尖晶石透明陶瓷物相、显微结构及光学性能的影响
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郭立1 , 赵永田1, 石红春1 , 曹波1, 刘宇阳2, 陈观通3, 郑安生1, 马远飞1, 林泉1, 刘晓华1
作者信息
  • 1.北京有色金属研究总院有研国晶辉新材料有限公司,河北 廊坊 065001
  • 2.北京有色金属研究总院有研资源环境技术研究院(北京)有限公司,北京 101407
  • 3.北京有色金属研究总院有研稀土新材料股份有限公司,河北 三河 065201
通讯作者:
石红春(1977—),男,硕士,高级工程师。
作者简介:

郭立(1991—),男,硕士,工程师。

Effect of Sintering Process on Phase, Microstructure and Optical Properties of MgAl2O4 Transparent Ceramics
Li GUO1 , Yongtian ZHAO1, Hongchun SHI1 , Bo CAO1, Yuyang LIU2, Guantong CHEN3, Ansheng ZHENG1, Yuanfei MA1, Quan LIN1, Xiaohua LIU1
Affiliations
  • 1.GRIRNM Guojing Advanbced Material Co., Ltd., Langfang 065001, Hebei, China
  • 2.GRINM Griret Resources and Environment Technology Research Institute (Beijing) Co., Ltd, Beijing 101407, China
  • 3.GRINM Grirem Advanced Materials Co., Ltd., Sanhe 065201, Hebei, China
  • Corresponding Author:
    SHI Hongchun (1977-), male, Master, Senior Engineer. E-mail:

    GUO Li (1991-), male, Master, Engineer. E-mail:

出版时间: 2022-12-20 doi: 10.14062/j.issn.0454-5648.20220471
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镁铝尖晶石透明陶瓷是一种优异的中红外材料,被广泛应用在军事领域和民用领域,具有典型的军民通用特点。本工作研究了烧结工艺对镁铝尖晶石透明陶瓷物相、显微结构及光学性能的影响,确定了适合高质量镁铝尖晶石透明陶瓷烧结工艺路线,对加快大尺寸透明陶瓷装甲材料产业化具有重要意义。结果表明:热压MgAl2O4透明陶瓷中Li离子可能以LiAlO2形式存在;热等静压MgAl2O4透明陶瓷的优先取向生长面为(311);热压和热等静压工艺制备的MgAl2O4陶瓷中Al离子、Mg离子偏离化学计量配比且Al和Mg摩尔比大于2,随着热等静压压力增大,陶瓷内部小晶粒增多,同时发现MgAl2O4陶瓷晶粒尺寸控制在20~40 μm有利于提升3~5 μm平均透过率,处理温度1 750 ℃、压力170 MPa条件下有利于提升MgAl2O4透明陶瓷3~5 μm波段的平均透过率,平均透过率大于85 %。同时,发现热等静压烧结时间对提升MgAl2O4透明陶瓷的红外透过率作用较小。

镁铝尖晶石透明陶瓷  /  热压  /  热等静压  /  物相分析  /  显微结构  /  光学性能

MgAl2O4 transparent ceramic is a superior mid-infrared material, which is widely used in military and civil fields. In this paper, the effect of sintering process on the phase, microstructure and optical properties of magnesia alumina spinel transparent ceramics was investigated, and the sintering process route suitable for high-quality magnesia alumina spinel transparent ceramics was determined, which is of great significance for accelerating the industrialization of large-scale transparent ceramic armor materials. The results show that Li ions in hot pressed (HP) MgAl2O4 transparent ceramics may exist in the form of LiAlO2. The preferential growth surface of MgAl2O4 transparent ceramics obtained by hot isostatic pressing (HIP) sintering process is (311). Al and Mg ions of MgAl2O4 ceramics prepared by HP and HIP sintering deviate from the stoichiometric ratio, and Al/Mg ratio is greater than 2. The small grains in the ceramics increase with the increase of HIP pressure, and the grain size of MgAl2O4 ceramics is within 20-40 μm, which is conducive to improving the average transmittance of 3-5 μm. Based on the results by hot isostatic pressing test, the HIP sintering temperature of 1 750 ℃ and the pressure of 170 MPa are conducive to improving the average infrared transmittance (>85 %). In addition, the HIP sintering time has little effect on improving the infrared transmittance of MgAl2O4 transparent ceramics.

magnesia-alumina spinel transparent ceramic  /  hot pressing  /  hot isostatic pressing  /  phase analysis  /  microstructure  /  optical performance
郭立, 赵永田, 石红春, 曹波, 刘宇阳, 陈观通, 郑安生, 马远飞, 林泉, 刘晓华. 烧结工艺对镁铝尖晶石透明陶瓷物相、显微结构及光学性能的影响. 硅酸盐学报, 2022 , 50 (12) : 3230 -3235 . DOI: 10.14062/j.issn.0454-5648.20220471
Li GUO, Yongtian ZHAO, Hongchun SHI, Bo CAO, Yuyang LIU, Guantong CHEN, Ansheng ZHENG, Yuanfei MA, Quan LIN, Xiaohua LIU. Effect of Sintering Process on Phase, Microstructure and Optical Properties of MgAl2O4 Transparent Ceramics[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (12) : 3230 -3235 . DOI: 10.14062/j.issn.0454-5648.20220471
  • 有研科技集团有限公司科技创新基金(2020TS0204)
  • 有研新材料股份有限公司科技创新基金(G2021KC0202)
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2022年第50卷第12期
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doi: 10.14062/j.issn.0454-5648.20220471
  • 接收时间:2022-06-11
  • 首发时间:2026-10-20
  • 出版时间:2022-12-20
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  • 收稿日期:2022-06-11
  • 修回日期:2022-08-11
基金
有研科技集团有限公司科技创新基金(2020TS0204)
有研新材料股份有限公司科技创新基金(G2021KC0202)
作者信息
    1.北京有色金属研究总院有研国晶辉新材料有限公司,河北 廊坊 065001
    2.北京有色金属研究总院有研资源环境技术研究院(北京)有限公司,北京 101407
    3.北京有色金属研究总院有研稀土新材料股份有限公司,河北 三河 065201

通讯作者:

石红春(1977—),男,硕士,高级工程师。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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