Article(id=1319222641043550410, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222618356559896, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220428, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1653580800000, receivedDateStr=2022-05-27, revisedDate=1670947200000, revisedDateStr=2022-12-14, acceptedDate=null, acceptedDateStr=null, onlineDate=1792456787595, onlineDateStr=2026-10-20, pubDate=1681920000000, pubDateStr=2023-04-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792456787595, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792456787595, creator=13701087609, updateTime=1792456787595, updator=13701087609, issue=Issue{id=1319222618356559896, tenantId=1146029695717560320, journalId=1263187385517883426, year='2023', volume='51', issue='4', pageStart='831', pageEnd='1090', issueExtLink='null', onlineDate='null', pubDate='1681920000000', pubDateStr='2023-04-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792456782187, creator='13701087609', updateTime=1792456947953, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319223313692472320, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222618356559896, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319223313692472321, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319222618356559896, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1007, endPage=1014, ext={EN=ArticleExt(id=1319222641253265611, articleId=1319222641043550410, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Properties of Nickel Doped Praseodymium Ferrate as a Symmetrical Solid Oxide Fuel Cell Electrode, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

Solid oxide fuel cell (SOFC) is an energy conversion device that converts chemical energy stored in fuel and oxidizer into electrical energy. Since SOFC has some advantages of high efficiency, low product clean pollution and low noise, it thus becomes a hot research topic in recent years. The perovskite type of mixed electron-ion conductor is extensively investigated as a SOFC electrode material. In this paper, PrFe0.7Ni0.3O3-δ (PFN) with an orthorhombic structure was synthesized by a solid-phase method. The results show that the conductivity values are 46.500 and 0.007 S/cm in air and in H2, respectively, when PFN is at 800 ℃. The interfacial polarization impedance values are 0.08 and 0.24 Ω·cm2 in air and H2, respectively. The maximum power densities of the PFN/LSGM/PFN symmetric cell are 475 and 180 mW/cm2 at 800 ℃ when using hydrogen or ethanol as a fuel, respectively. It is indicated that Ni-doped PrFeO3 is a promising SOFC electrode material with the superior performance.

, authors=Yuankui TENG1, Jiangxin LI1, Pengcheng WANG1, Yufu YANG1, Yingjiao ZHAI1, Fangjun JIN1, 2, authorsList=Yuankui TENG, Jiangxin LI, Pengcheng WANG, Yufu YANG, Yingjiao ZHAI, Fangjun JIN, authorCompany=null, correspAuthors=Yingjiao ZHAI, Fangjun JIN, authorNote=

TENG Yuankui (1999-), male, Master candidate. E-mail:

, correspAuthorsNote=
ZHAI Yingjiao (1986-), female, Ph.D., Associate Professor; E-mail:
JIN Fangjun (1987-), male, Ph.D., Associate Professor.
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319222641467175116, articleId=1319222641043550410, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=镍掺杂铁酸镨作为对称固体氧化物燃料电池电极的性能, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

固体氧化物燃料电池(SOFC)是一种将储存在燃料和氧化剂中的化学能转化为电能的能量转化装置。SOFC具有高效、产物清洁污染小和噪声低等优点,因此成为近年来国内外研究的热点。混合电子-离子导体的钙钛矿型SOFC电极材料被广泛研究。采用固相法在空气中合成了具有正交钙钛矿结构的PrFe0.7Ni0.3O3-δ(PFN)。结果表明:PFN在800 ℃时,在空气和H2条件下最大电导率分别为46.500 S/cm和0.007 S/cm,在空气气氛条件下的界面极化阻抗为0.08 Ω·cm2,在H2气氛条件下阻抗为0.24 Ω·cm2,在乙醇气氛条件下的阻抗为1.52 Ω·cm2;PFN/La0.9Sr0.1Ga0.8Mg0.2O3-δ(LSGM)/PFN对称电池在800 ℃时,氢气气氛条件下的最大功率密度为475 mW/cm2,以乙醇为燃料时最大功率密度为180 mW/cm2。这表明,Ni掺杂PrFeO3的样品作为电极材料性能优异,是一种有前景的SOFC电极材料。

, authors=滕元魁1, 李江馨1, 王鹏程1, 杨淯夫1, 翟英娇1, 金芳军1, 2, authorsList=滕元魁, 李江馨, 王鹏程, 杨淯夫, 翟英娇, 金芳军, authorCompany=null, correspAuthors=翟英娇, 金芳军, authorNote=

滕元魁(1999—),男,硕士研究生。

, correspAuthorsNote=
翟英娇(1986—),女,博士,副教授;
金芳军(1987—),男,博士,副教授。
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TENG Yuankui (1999-), male, Master candidate. E-mail:

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滕元魁(1999—),男,硕士研究生。

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滕元魁(1999—),男,硕士研究生。

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镍掺杂铁酸镨作为对称固体氧化物燃料电池电极的性能
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滕元魁 1 , 李江馨 1 , 王鹏程 1 , 杨淯夫 1 , 翟英娇 1 , 金芳军 1, 2
硅酸盐学报 | 研究论文 2023,51(4): 1007-1014
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硅酸盐学报 |研究论文 2023 , 51 (4) : 1007 -1014
镍掺杂铁酸镨作为对称固体氧化物燃料电池电极的性能
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滕元魁1 , 李江馨1, 王鹏程1, 杨淯夫1, 翟英娇1 , 金芳军1, 2
作者信息
  • 1.长春理工大学物理学院,长春 130022
  • 2.中国矿业大学材料与物理学院,江苏 徐州 221116
通讯作者:
翟英娇(1986—),女,博士,副教授;
金芳军(1987—),男,博士,副教授。
作者简介:

滕元魁(1999—),男,硕士研究生。

Properties of Nickel Doped Praseodymium Ferrate as a Symmetrical Solid Oxide Fuel Cell Electrode
Yuankui TENG1 , Jiangxin LI1, Pengcheng WANG1, Yufu YANG1, Yingjiao ZHAI1 , Fangjun JIN1, 2
Affiliations
  • 1.College of Physics, Changchun University of Science and Technology, Changchun 130022, China
  • 2.School of Materials Science and Physics, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China
  • Corresponding Author:
    ZHAI Yingjiao (1986-), female, Ph.D., Associate Professor; E-mail:
    JIN Fangjun (1987-), male, Ph.D., Associate Professor.

    TENG Yuankui (1999-), male, Master candidate. E-mail:

出版时间: 2023-04-20 doi: 10.14062/j.issn.0454-5648.20220428
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固体氧化物燃料电池(SOFC)是一种将储存在燃料和氧化剂中的化学能转化为电能的能量转化装置。SOFC具有高效、产物清洁污染小和噪声低等优点,因此成为近年来国内外研究的热点。混合电子-离子导体的钙钛矿型SOFC电极材料被广泛研究。采用固相法在空气中合成了具有正交钙钛矿结构的PrFe0.7Ni0.3O3-δ(PFN)。结果表明:PFN在800 ℃时,在空气和H2条件下最大电导率分别为46.500 S/cm和0.007 S/cm,在空气气氛条件下的界面极化阻抗为0.08 Ω·cm2,在H2气氛条件下阻抗为0.24 Ω·cm2,在乙醇气氛条件下的阻抗为1.52 Ω·cm2;PFN/La0.9Sr0.1Ga0.8Mg0.2O3-δ(LSGM)/PFN对称电池在800 ℃时,氢气气氛条件下的最大功率密度为475 mW/cm2,以乙醇为燃料时最大功率密度为180 mW/cm2。这表明,Ni掺杂PrFeO3的样品作为电极材料性能优异,是一种有前景的SOFC电极材料。

固体氧化物燃料电池  /  钙钛矿  /  电极材料  /  电化学性能

Solid oxide fuel cell (SOFC) is an energy conversion device that converts chemical energy stored in fuel and oxidizer into electrical energy. Since SOFC has some advantages of high efficiency, low product clean pollution and low noise, it thus becomes a hot research topic in recent years. The perovskite type of mixed electron-ion conductor is extensively investigated as a SOFC electrode material. In this paper, PrFe0.7Ni0.3O3-δ (PFN) with an orthorhombic structure was synthesized by a solid-phase method. The results show that the conductivity values are 46.500 and 0.007 S/cm in air and in H2, respectively, when PFN is at 800 ℃. The interfacial polarization impedance values are 0.08 and 0.24 Ω·cm2 in air and H2, respectively. The maximum power densities of the PFN/LSGM/PFN symmetric cell are 475 and 180 mW/cm2 at 800 ℃ when using hydrogen or ethanol as a fuel, respectively. It is indicated that Ni-doped PrFeO3 is a promising SOFC electrode material with the superior performance.

solid oxide fuel cell  /  perovskite  /  electrode  /  electrochemical performance
滕元魁, 李江馨, 王鹏程, 杨淯夫, 翟英娇, 金芳军. 镍掺杂铁酸镨作为对称固体氧化物燃料电池电极的性能. 硅酸盐学报, 2023 , 51 (4) : 1007 -1014 . DOI: 10.14062/j.issn.0454-5648.20220428
Yuankui TENG, Jiangxin LI, Pengcheng WANG, Yufu YANG, Yingjiao ZHAI, Fangjun JIN. Properties of Nickel Doped Praseodymium Ferrate as a Symmetrical Solid Oxide Fuel Cell Electrode[J]. Journal of the Chinese Ceramic Society, 2023 , 51 (4) : 1007 -1014 . DOI: 10.14062/j.issn.0454-5648.20220428
  • 吉林省教育厅项目(JJKH20220723KJ)
  • 长春市科技局青年科技创新人才项目(21QC02)
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doi: 10.14062/j.issn.0454-5648.20220428
  • 接收时间:2022-05-27
  • 首发时间:2026-10-20
  • 出版时间:2023-04-20
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  • 收稿日期:2022-05-27
  • 修回日期:2022-12-14
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吉林省教育厅项目(JJKH20220723KJ)
长春市科技局青年科技创新人才项目(21QC02)
作者信息
    1.长春理工大学物理学院,长春 130022
    2.中国矿业大学材料与物理学院,江苏 徐州 221116

通讯作者:

翟英娇(1986—),女,博士,副教授;
金芳军(1987—),男,博士,副教授。
参考文献
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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