Article(id=1319237175766528127, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220410, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1652803200000, receivedDateStr=2022-05-18, revisedDate=1662566400000, revisedDateStr=2022-09-08, acceptedDate=null, acceptedDateStr=null, onlineDate=1792460252943, onlineDateStr=2026-10-20, pubDate=1671465600000, pubDateStr=2022-12-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792460252943, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792460252943, creator=13701087609, updateTime=1792460252943, updator=13701087609, issue=Issue{id=1319237171312177253, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='12', pageStart='3091', pageEnd='3336', issueExtLink='null', onlineDate='null', pubDate='1671465600000', pubDateStr='2022-12-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792460251882, creator='13701087609', updateTime=1792460721974, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319239143067071226, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319239143067071227, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=3092, endPage=3102, ext={EN=ArticleExt(id=1319237175976243328, articleId=1319237175766528127, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=UV-Visible-NIR Ultrabroadband Mechanoluminesence from Sr3Y2Ge3O12:Bi3+ and Its Performance Regulation, columnId=1321891473390415997, journalTitle=Journal of the Chinese Ceramic Society, columnName=Advanced Rare Earth Luminescence Materials for Sensing and Detection—Research Articles, runingTitle=null, highlight=null, articleAbstract=

The existing mechanoluminesence has a single band. The 3P1→1S0 transition of Bi3+ ion can achieve an ultrabroadband emission in UV-Visible. However, the existing Bi3+ ion activated mechanoluminesence materials only emit blue light. To solve this problem, the UV-Visible-NIR ultrabroadband mechanoluminesence is realized in a multi-lattice garnet compound matrix, and its mechanoluminesent performance is regulated by the neighbor ion (i.e., Sc3+ ion) substitution strategy. The luminescence source is determined by steady-state fluorescence spectroscopy (at 465 nm, corresponding to the 3P1→1S0 transition of Bi3+ ion). The mechanism of mechanoluminesence is related to the persistent luminescence. The material defect distribution is obtained by thermoluminescence test, and the deep trap (>0.7 eV) contributes to the mechanoluminesence.

, authors=Peishan SHAO, Puxian XIONG, Yao XIAO, Kexin QIN, Yongsheng SUN, Kang CHEN, Dongdan CHEN, Zhongmin YANG, authorsList=Peishan SHAO, Puxian XIONG, Yao XIAO, Kexin QIN, Yongsheng SUN, Kang CHEN, Dongdan CHEN, Zhongmin YANG, authorCompany=null, correspAuthors=Puxian XIONG, Dongdan CHEN, authorNote=

SHAO Peishan (2000-), female, Master candidate. E-mail:

, correspAuthorsNote=
XIONG Puxian (1993-), male, Ph.D., Research Assistant. E-mail:
CHEN Dongdan (1976-), female, Ph.D., Associate Professor.
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319237176223707265, articleId=1319237175766528127, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=Sr3Y2Ge3O12:Bi3+:紫外-可见-近红外超宽带应力发光及性能调控探索, columnId=1321891473621102718, journalTitle=硅酸盐学报, columnName=稀土发光传感与探测新材料专题—研究论文, runingTitle=null, highlight=null, articleAbstract=

现有应力发光多局限于单一波段。铋(Bi)离子能实现紫外-近红外波段的超宽发射,但是现有Bi离子激活应力发光材料多限于蓝光发射。针对这一问题,本工作在多格点石榴石化合物(Sr3Y2Ge3O12)中率先实现了紫外-可见-近红外超宽带应力发光,并借助近邻离子(Sc3+)取代策略调控其应力发光性能。最后,利用热释光测试等得到材料缺陷分布信息,并探究其应力发光机理。最后,基于多模式发光,该材料有望用于信息储存领域。

, authors=邵佩珊, 熊普先, 肖窑, 覃可欣, 孙永胜, 陈康, 陈东丹, 杨中民, authorsList=邵佩珊, 熊普先, 肖窑, 覃可欣, 孙永胜, 陈康, 陈东丹, 杨中民, authorCompany=null, correspAuthors=熊普先, 陈东丹, authorNote=

邵佩珊(2000—),女,硕士研究生。

, correspAuthorsNote=
熊普先(1993—),男,博士,助理研究员。
陈东丹(1976—),女,博士,副教授。
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Sr3Y2Ge3O12:Bi3+:紫外-可见-近红外超宽带应力发光及性能调控探索
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邵佩珊 , 熊普先 , 肖窑 , 覃可欣 , 孙永胜 , 陈康 , 陈东丹 , 杨中民
硅酸盐学报 | 稀土发光传感与探测新材料专题—研究论文 2022,50(12): 3092-3102
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硅酸盐学报 |稀土发光传感与探测新材料专题—研究论文 2022 , 50 (12) : 3092 -3102
Sr3Y2Ge3O12:Bi3+:紫外-可见-近红外超宽带应力发光及性能调控探索
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邵佩珊 , 熊普先 , 肖窑, 覃可欣, 孙永胜, 陈康, 陈东丹 , 杨中民
作者信息
  • 华南理工大学材料科学与工程学院,华南理工大学物理与光电学院,发光材料与器件国家重点实验室,广东省光纤激光材料与应用技术重点实验室,广东省特种光纤材料与器件工程技术研究开发中心,广州 510000
通讯作者:
熊普先(1993—),男,博士,助理研究员。
陈东丹(1976—),女,博士,副教授。
作者简介:

邵佩珊(2000—),女,硕士研究生。

UV-Visible-NIR Ultrabroadband Mechanoluminesence from Sr3Y2Ge3O12:Bi3+ and Its Performance Regulation
Peishan SHAO , Puxian XIONG , Yao XIAO, Kexin QIN, Yongsheng SUN, Kang CHEN, Dongdan CHEN , Zhongmin YANG
Affiliations
  • School of Materials Science and Engineering, School of Physics and Optoelectronics, The State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, Guangdong Engineering Technology Research and Development Center of Special Optical Fiber Materials and Devices, South China University of Technology, Guangzhou 510000, China
  • Corresponding Author:
    XIONG Puxian (1993-), male, Ph.D., Research Assistant. E-mail:
    CHEN Dongdan (1976-), female, Ph.D., Associate Professor.

    SHAO Peishan (2000-), female, Master candidate. E-mail:

出版时间: 2022-12-20 doi: 10.14062/j.issn.0454-5648.20220410
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现有应力发光多局限于单一波段。铋(Bi)离子能实现紫外-近红外波段的超宽发射,但是现有Bi离子激活应力发光材料多限于蓝光发射。针对这一问题,本工作在多格点石榴石化合物(Sr3Y2Ge3O12)中率先实现了紫外-可见-近红外超宽带应力发光,并借助近邻离子(Sc3+)取代策略调控其应力发光性能。最后,利用热释光测试等得到材料缺陷分布信息,并探究其应力发光机理。最后,基于多模式发光,该材料有望用于信息储存领域。

应力发光  /  铋离子  /  近邻离子取代  /  晶格工程

The existing mechanoluminesence has a single band. The 3P1→1S0 transition of Bi3+ ion can achieve an ultrabroadband emission in UV-Visible. However, the existing Bi3+ ion activated mechanoluminesence materials only emit blue light. To solve this problem, the UV-Visible-NIR ultrabroadband mechanoluminesence is realized in a multi-lattice garnet compound matrix, and its mechanoluminesent performance is regulated by the neighbor ion (i.e., Sc3+ ion) substitution strategy. The luminescence source is determined by steady-state fluorescence spectroscopy (at 465 nm, corresponding to the 3P1→1S0 transition of Bi3+ ion). The mechanism of mechanoluminesence is related to the persistent luminescence. The material defect distribution is obtained by thermoluminescence test, and the deep trap (>0.7 eV) contributes to the mechanoluminesence.

mechanoluminesence  /  bismuth ion  /  neighbor ion substitution  /  lattice engineering
邵佩珊, 熊普先, 肖窑, 覃可欣, 孙永胜, 陈康, 陈东丹, 杨中民. Sr3Y2Ge3O12:Bi3+:紫外-可见-近红外超宽带应力发光及性能调控探索. 硅酸盐学报, 2022 , 50 (12) : 3092 -3102 . DOI: 10.14062/j.issn.0454-5648.20220410
Peishan SHAO, Puxian XIONG, Yao XIAO, Kexin QIN, Yongsheng SUN, Kang CHEN, Dongdan CHEN, Zhongmin YANG. UV-Visible-NIR Ultrabroadband Mechanoluminesence from Sr3Y2Ge3O12:Bi3+ and Its Performance Regulation[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (12) : 3092 -3102 . DOI: 10.14062/j.issn.0454-5648.20220410
  • 国家自然科学基金项目(52202003)
  • 广东省“珠江人才计划”本土创新科研团队(2017BT01X137)
  • 广州市重点领域研发计划项目-新材料重大科技专项(202007020003)
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2022年第50卷第12期
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doi: 10.14062/j.issn.0454-5648.20220410
  • 接收时间:2022-05-18
  • 首发时间:2026-10-20
  • 出版时间:2022-12-20
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  • 收稿日期:2022-05-18
  • 修回日期:2022-09-08
基金
国家自然科学基金项目(52202003)
广东省“珠江人才计划”本土创新科研团队(2017BT01X137)
广州市重点领域研发计划项目-新材料重大科技专项(202007020003)
作者信息
    华南理工大学材料科学与工程学院,华南理工大学物理与光电学院,发光材料与器件国家重点实验室,广东省光纤激光材料与应用技术重点实验室,广东省特种光纤材料与器件工程技术研究开发中心,广州 510000

通讯作者:

熊普先(1993—),男,博士,助理研究员。
陈东丹(1976—),女,博士,副教授。
参考文献
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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