Article(id=1319237182787801873, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220401, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1652716800000, receivedDateStr=2022-05-17, revisedDate=1658851200000, revisedDateStr=2022-07-27, acceptedDate=null, acceptedDateStr=null, onlineDate=1792460254618, onlineDateStr=2026-10-20, pubDate=1671465600000, pubDateStr=2022-12-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792460254618, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792460254617, creator=13701087609, updateTime=1792460254617, updator=13701087609, issue=Issue{id=1319237171312177253, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='12', pageStart='3091', pageEnd='3336', issueExtLink='null', onlineDate='null', pubDate='1671465600000', pubDateStr='2022-12-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792460251882, creator='13701087609', updateTime=1792460721974, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319239143067071226, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319239143067071227, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=3141, endPage=3146, ext={EN=ArticleExt(id=1319237184297751315, articleId=1319237182787801873, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Mechanoluminescent Properties of Sm3+ Doped Double Perovskite Sr3Sn2O7, columnId=1321891473390415997, journalTitle=Journal of the Chinese Ceramic Society, columnName=Advanced Rare Earth Luminescence Materials for Sensing and Detection—Research Articles, runingTitle=null, highlight=null, articleAbstract=

Sr3Sn2O7:Sm3+ is a widely studied mechanoluminescent material, but there is still a lack of research on the doping amount of Sm3+. In this paper, Sr3-xSn2O7: xSm3+ was prepared by a high-temperature solid-state method. A sample of Sr3Sn2O7 with a small amount of Sm3+ still maintains a non-centrosymmetric double perovskite structure. The sample prepared has a stable photoluminescence, a long afterglow and mechanoluminescence after UV excitation or load application. The mechanoluminescence originates from the electron transition from the 4G5/2 excited state of Sm3+ to the 6HJ (J=5/2, 7/2, 9/2) ground state. The luminescence performance was optimized by adjusting the value of x, and the optimum performance was achieved when x = 0.020. This study can provide a guidance for the future related research.

, authors=Qiangke WANG1, 2, Yujun LIANG2, Dong TU1, 3, authorsList=Qiangke WANG, Yujun LIANG, Dong TU, authorCompany=null, correspAuthors=Dong TU, authorNote=

WANG Qiangke (1998-), male, Master candidate. E-mail:

, correspAuthorsNote=
TU Dong (1986-), male, Ph.D., Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319237184599741204, articleId=1319237182787801873, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=Sm3+掺杂双钙钛矿结构Sr3Sn2O7的应力发光特性, columnId=1321891473621102718, journalTitle=硅酸盐学报, columnName=稀土发光传感与探测新材料专题—研究论文, runingTitle=null, highlight=null, articleAbstract=

Sr3Sn2O7:Sm3+是一种被广泛研究的应力法光材料,但关于Sm3+掺杂量的研究仍然存在缺失。本工作采用高温固相法制备Sr3-xSn2O7:xSm3+。在Sr3Sn2O7中掺入少量Sm3+后,样品仍然保持着非中心对称的双钙钛矿结构。样品在受到紫外灯激励或应力施加之后,能展现出稳定的光致发光、长余辉和应力发光性能,且这三者的光谱显示出一致性。应力发光来源于Sm3+的4G5/2激发态向6HJ(J=5/2,7/2,9/2)基态的电子跃迁。通过调控x值对其发光性能进行优化,在x=0.020时性能最好。Sm3+掺杂量的变化对应力发光性能的影响,既对现有的相关工作进行了补充,同时也能为未来的相关研究起到参考或指导的作用。

, authors=王强科1, 2, 梁玉军2, 涂东1, 3, authorsList=王强科, 梁玉军, 涂东, authorCompany=null, correspAuthors=涂东, authorNote=

王强科(1998—),男,硕士研究生。

, correspAuthorsNote=
涂东(1986—),男,博士,研究员
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王强科(1998—),男,硕士研究生。

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Sm3+掺杂双钙钛矿结构Sr3Sn2O7的应力发光特性
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王强科 1, 2 , 梁玉军 2 , 涂东 1, 3
硅酸盐学报 | 稀土发光传感与探测新材料专题—研究论文 2022,50(12): 3141-3146
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硅酸盐学报 |稀土发光传感与探测新材料专题—研究论文 2022 , 50 (12) : 3141 -3146
Sm3+掺杂双钙钛矿结构Sr3Sn2O7的应力发光特性
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王强科1, 2 , 梁玉军2, 涂东1, 3
作者信息
  • 1.武汉大学物理科学与技术学院,武汉 430064
  • 2.中国地质大学(武汉)材料与化学学院,武汉 430070
  • 3.武汉大学苏州研究院,江苏 苏州 215125
通讯作者:
涂东(1986—),男,博士,研究员
作者简介:

王强科(1998—),男,硕士研究生。

Mechanoluminescent Properties of Sm3+ Doped Double Perovskite Sr3Sn2O7
Qiangke WANG1, 2 , Yujun LIANG2, Dong TU1, 3
Affiliations
  • 1.School of Physics and Technology, Wuhan University, Wuhan 430064, China
  • 2.Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430070, China
  • 3.Suzhou Research Institute of Wuhan University, Suzhou 215125, Jiangsu, China
  • Corresponding Author:
    TU Dong (1986-), male, Ph.D., Professor. E-mail:

    WANG Qiangke (1998-), male, Master candidate. E-mail:

出版时间: 2022-12-20 doi: 10.14062/j.issn.0454-5648.20220401
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Sr3Sn2O7:Sm3+是一种被广泛研究的应力法光材料,但关于Sm3+掺杂量的研究仍然存在缺失。本工作采用高温固相法制备Sr3-xSn2O7:xSm3+。在Sr3Sn2O7中掺入少量Sm3+后,样品仍然保持着非中心对称的双钙钛矿结构。样品在受到紫外灯激励或应力施加之后,能展现出稳定的光致发光、长余辉和应力发光性能,且这三者的光谱显示出一致性。应力发光来源于Sm3+的4G5/2激发态向6HJ(J=5/2,7/2,9/2)基态的电子跃迁。通过调控x值对其发光性能进行优化,在x=0.020时性能最好。Sm3+掺杂量的变化对应力发光性能的影响,既对现有的相关工作进行了补充,同时也能为未来的相关研究起到参考或指导的作用。

锡锶氧化物  /  三价钐离子  /  双钙钛矿  /  应力发光

Sr3Sn2O7:Sm3+ is a widely studied mechanoluminescent material, but there is still a lack of research on the doping amount of Sm3+. In this paper, Sr3-xSn2O7: xSm3+ was prepared by a high-temperature solid-state method. A sample of Sr3Sn2O7 with a small amount of Sm3+ still maintains a non-centrosymmetric double perovskite structure. The sample prepared has a stable photoluminescence, a long afterglow and mechanoluminescence after UV excitation or load application. The mechanoluminescence originates from the electron transition from the 4G5/2 excited state of Sm3+ to the 6HJ (J=5/2, 7/2, 9/2) ground state. The luminescence performance was optimized by adjusting the value of x, and the optimum performance was achieved when x = 0.020. This study can provide a guidance for the future related research.

tin strontium oxide  /  trivalent samarium ion  /  double perovskite  /  mechanoluminescence
王强科, 梁玉军, 涂东. Sm3+掺杂双钙钛矿结构Sr3Sn2O7的应力发光特性. 硅酸盐学报, 2022 , 50 (12) : 3141 -3146 . DOI: 10.14062/j.issn.0454-5648.20220401
Qiangke WANG, Yujun LIANG, Dong TU. Mechanoluminescent Properties of Sm3+ Doped Double Perovskite Sr3Sn2O7[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (12) : 3141 -3146 . DOI: 10.14062/j.issn.0454-5648.20220401
  • 中国自然科学基金(11804255; 12074298)
  • 江苏省自然科学基金(BK20190212)
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2022年第50卷第12期
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doi: 10.14062/j.issn.0454-5648.20220401
  • 接收时间:2022-05-17
  • 首发时间:2026-10-20
  • 出版时间:2022-12-20
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  • 收稿日期:2022-05-17
  • 修回日期:2022-07-27
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中国自然科学基金(11804255; 12074298)
江苏省自然科学基金(BK20190212)
作者信息
    1.武汉大学物理科学与技术学院,武汉 430064
    2.中国地质大学(武汉)材料与化学学院,武汉 430070
    3.武汉大学苏州研究院,江苏 苏州 215125

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涂东(1986—),男,博士,研究员
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2种不同金属材料的力学参数
科
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属数
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genus
种数
Number of
species
占总种数比例
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total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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