Article(id=1319237187036631865, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220387, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1652371200000, receivedDateStr=2022-05-13, revisedDate=1653494400000, revisedDateStr=2022-05-26, acceptedDate=null, acceptedDateStr=null, onlineDate=1792460255630, onlineDateStr=2026-10-20, pubDate=1671465600000, pubDateStr=2022-12-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792460255630, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792460255630, creator=13701087609, updateTime=1792460255630, updator=13701087609, issue=Issue{id=1319237171312177253, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='12', pageStart='3091', pageEnd='3336', issueExtLink='null', onlineDate='null', pubDate='1671465600000', pubDateStr='2022-12-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792460251882, creator='13701087609', updateTime=1792460721974, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319239143067071226, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319239143067071227, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319237171312177253, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=3222, endPage=3229, ext={EN=ArticleExt(id=1319237188756296506, articleId=1319237187036631865, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Sintering Process Optimization and Grain Growth Mechanism of BaBiO3 Ceramic Targets, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

High quality ceramic targets is crucial to produce BaBiO3-based negative temperature coefficient (NTC) thermosensitive films via RF magnetron sputtering. In this paper, the shrinkage, flatness and volume density of pure BaBiO3 target were measured, and the orthogonal experiment was designed via changing the major factors (i.e., compressive time, sintering temperature, holding time and heating rate), and the structure-activity relationship between each factor and the target material quality index was analyzed. Also, based on the influence of sintering behaviors on the grain growth of BaBiO3 ceramic targets, the key sintering process factors such as sintering temperature, holding time and heating rate were regulated by the phenomenological equation and intercept method to discuss the intrinsic relationship among the grain growth mechanism, growth index n and key influencing factors. According to the results by X-ray diffraction, Raman spectroscopy and scanning electron microscopy-enery dispersive spectroscopy, the phase structure and elemental composition of the target samples obtained at the given process factors were analyzed. The results show that BaBiO3 ceramic targets with slight deformation, high density and good apparent quality can be obtained under the optimum conditions (i.e., compressive time of 12 min, sintering temperature of 750 ℃, holding time of 120 min and heating rate of 2 ℃/min).

, authors=Jingjing QU1, 3, Qi SU2, Fei LIU2, Nairui SHEN2, Changlai YUAN4, Xiao LIU4, Liufang MENG4, authorsList=Jingjing QU, Qi SU, Fei LIU, Nairui SHEN, Changlai YUAN, Xiao LIU, Liufang MENG, authorCompany=null, correspAuthors=Fei LIU, authorNote=

QU Jingjing (1988-), female, Ph.D., associate Professor. E-mail:

, correspAuthorsNote=
LIU Fei (1985-), male, Ph.D., associate Professor. E-mail:
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高质量的陶瓷靶材对于射频磁控溅射法可镀制出综合性能优异的BaBiO3基负温度系数热敏薄膜至关重要。基于此,本工作以纯BaBiO3靶材样品的收缩率、平整度和体积密度为主要质量特性衡量指标,通过改变保压时间、烧结温度、保温时间和升温速率等4个因素,设计了正交实验并加以分析各因素与靶材质量指标的构效关系。同时,基于烧结行为对BaBiO3靶材晶粒生长的影响关系,包括调控烧结温度、保温时间和升温速率等关键烧结工艺参数,结合唯象方程和截距法,探讨了晶粒生长机制、生长指数n与关键影响因素间的内在关联性。基于此,进一步联合X射线衍射、Raman光谱、扫描电子显微镜和能谱等表征方法分析了不同工艺参数条件下靶材样品的相结构和元素构成,从而验证了正交化实验的有效性。结果表明,获得综合质量较优(变形程度小、致密度高和表观质量良好)的BaBiO3陶瓷靶材的烧制工艺为:保压时间12 min、烧结温度750 ℃、保温时间120 min和升温速率2 ℃/min。

, authors=屈婧婧1, 3, 苏琪2, 刘飞2, 沈乃瑞2, 袁昌来4, 刘笑4, 蒙柳方4, authorsList=屈婧婧, 苏琪, 刘飞, 沈乃瑞, 袁昌来, 刘笑, 蒙柳方, authorCompany=null, correspAuthors=刘飞, authorNote=

屈婧婧(1988—),女,博士,副教授。

, correspAuthorsNote=
刘飞(1985—),男,博士,副教授。
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BaBiO3陶瓷靶材的烧制工艺优化及其晶粒生长机制
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屈婧婧 1, 3 , 苏琪 2 , 刘飞 2 , 沈乃瑞 2 , 袁昌来 4 , 刘笑 4 , 蒙柳方 4
硅酸盐学报 | 研究论文 2022,50(12): 3222-3229
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硅酸盐学报 |研究论文 2022 , 50 (12) : 3222 -3229
BaBiO3陶瓷靶材的烧制工艺优化及其晶粒生长机制
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屈婧婧1, 3 , 苏琪2, 刘飞2 , 沈乃瑞2, 袁昌来4, 刘笑4, 蒙柳方4
作者信息
  • 1.桂林电子科技大学电子工程与自动化学院,广西 桂林 541004
  • 2.桂林电子科技大学机电工程学院,广西 桂林 541004
  • 3.桂林航天工业学院科技处,广西 桂林 541004
  • 4.桂林电子科技大学材料科学与工程学院,广西 桂林 541004
通讯作者:
刘飞(1985—),男,博士,副教授。
作者简介:

屈婧婧(1988—),女,博士,副教授。

Sintering Process Optimization and Grain Growth Mechanism of BaBiO3 Ceramic Targets
Jingjing QU1, 3 , Qi SU2, Fei LIU2 , Nairui SHEN2, Changlai YUAN4, Xiao LIU4, Liufang MENG4
Affiliations
  • 1.School of Electronic Engineering and Automation, Guilin University of Electronic Technology, Guilin 541004, Guangxi, China
  • 2.School of Mechanical and Electrical Engineering, Guilin University of Electronic Technology, Guilin 541004, Guangxi, China
  • 3.Technology Department, Guilin University of Aerospace Technology, Guilin 541004, Guangxi, China
  • 4.School of Materials Science and Engineering, Guilin University of Electronic Technology, Guilin 541004, Guangxi, China
  • Corresponding Author:
    LIU Fei (1985-), male, Ph.D., associate Professor. E-mail:

    QU Jingjing (1988-), female, Ph.D., associate Professor. E-mail:

出版时间: 2022-12-20 doi: 10.14062/j.issn.0454-5648.20220387
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高质量的陶瓷靶材对于射频磁控溅射法可镀制出综合性能优异的BaBiO3基负温度系数热敏薄膜至关重要。基于此,本工作以纯BaBiO3靶材样品的收缩率、平整度和体积密度为主要质量特性衡量指标,通过改变保压时间、烧结温度、保温时间和升温速率等4个因素,设计了正交实验并加以分析各因素与靶材质量指标的构效关系。同时,基于烧结行为对BaBiO3靶材晶粒生长的影响关系,包括调控烧结温度、保温时间和升温速率等关键烧结工艺参数,结合唯象方程和截距法,探讨了晶粒生长机制、生长指数n与关键影响因素间的内在关联性。基于此,进一步联合X射线衍射、Raman光谱、扫描电子显微镜和能谱等表征方法分析了不同工艺参数条件下靶材样品的相结构和元素构成,从而验证了正交化实验的有效性。结果表明,获得综合质量较优(变形程度小、致密度高和表观质量良好)的BaBiO3陶瓷靶材的烧制工艺为:保压时间12 min、烧结温度750 ℃、保温时间120 min和升温速率2 ℃/min。

铋酸钡  /  烧制工艺  /  正交实验  /  晶粒生长机制  /  靶材  /  质量衡量指标

High quality ceramic targets is crucial to produce BaBiO3-based negative temperature coefficient (NTC) thermosensitive films via RF magnetron sputtering. In this paper, the shrinkage, flatness and volume density of pure BaBiO3 target were measured, and the orthogonal experiment was designed via changing the major factors (i.e., compressive time, sintering temperature, holding time and heating rate), and the structure-activity relationship between each factor and the target material quality index was analyzed. Also, based on the influence of sintering behaviors on the grain growth of BaBiO3 ceramic targets, the key sintering process factors such as sintering temperature, holding time and heating rate were regulated by the phenomenological equation and intercept method to discuss the intrinsic relationship among the grain growth mechanism, growth index n and key influencing factors. According to the results by X-ray diffraction, Raman spectroscopy and scanning electron microscopy-enery dispersive spectroscopy, the phase structure and elemental composition of the target samples obtained at the given process factors were analyzed. The results show that BaBiO3 ceramic targets with slight deformation, high density and good apparent quality can be obtained under the optimum conditions (i.e., compressive time of 12 min, sintering temperature of 750 ℃, holding time of 120 min and heating rate of 2 ℃/min).

barium bismuth oxide  /  sintering process  /  orthogonal experiment  /  grain growth mechanism  /  target  /  quality measurement indexs
屈婧婧, 苏琪, 刘飞, 沈乃瑞, 袁昌来, 刘笑, 蒙柳方. BaBiO3陶瓷靶材的烧制工艺优化及其晶粒生长机制. 硅酸盐学报, 2022 , 50 (12) : 3222 -3229 . DOI: 10.14062/j.issn.0454-5648.20220387
Jingjing QU, Qi SU, Fei LIU, Nairui SHEN, Changlai YUAN, Xiao LIU, Liufang MENG. Sintering Process Optimization and Grain Growth Mechanism of BaBiO3 Ceramic Targets[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (12) : 3222 -3229 . DOI: 10.14062/j.issn.0454-5648.20220387
  • 广西制造系统与先进制造技术重点实验室主任课题(20-065-40-001Z)
  • 国家自然科学基金青年科学基金(61801135)
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2022年第50卷第12期
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doi: 10.14062/j.issn.0454-5648.20220387
  • 接收时间:2022-05-13
  • 首发时间:2026-10-20
  • 出版时间:2022-12-20
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  • 收稿日期:2022-05-13
  • 修回日期:2022-05-26
基金
广西制造系统与先进制造技术重点实验室主任课题(20-065-40-001Z)
国家自然科学基金青年科学基金(61801135)
作者信息
    1.桂林电子科技大学电子工程与自动化学院,广西 桂林 541004
    2.桂林电子科技大学机电工程学院,广西 桂林 541004
    3.桂林航天工业学院科技处,广西 桂林 541004
    4.桂林电子科技大学材料科学与工程学院,广西 桂林 541004

通讯作者:

刘飞(1985—),男,博士,副教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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