Article(id=1319986540453937192, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220259, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1649174400000, receivedDateStr=2022-04-06, revisedDate=1650211200000, revisedDateStr=2022-04-18, acceptedDate=null, acceptedDateStr=null, onlineDate=1792638915408, onlineDateStr=2026-10-22, pubDate=1655654400000, pubDateStr=2022-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792638915408, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792638915408, creator=13701087609, updateTime=1792638915408, updator=13701087609, issue=Issue{id=1319986532933555119, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='6', pageStart='1455', pageEnd='1774', issueExtLink='null', onlineDate='null', pubDate='1655654400000', pubDateStr='2022-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792638913615, creator='13701087609', updateTime=1792639299444, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319988151507075566, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319988151507075567, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1456, endPage=1462, ext={EN=ArticleExt(id=1319986540680429609, articleId=1319986540453937192, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Fabrication and CaO-MgO-Al2O3-SiO2 Corrosion Resistance of Multi-Component BaO-SrO-CaO-MgO-Al2O3-2SiO2 Environmental Barrier Coatings, columnId=1321892005832151399, journalTitle=Journal of the Chinese Ceramic Society, columnName=Advanced High Entropy Ceramics—Research Articles, runingTitle=null, highlight=null, articleAbstract=

The multi-component ceramics of BaO-SrO-CaO-MgO-Al2O3-2SiO2(BSCMAS) with different molar ratio of Ba, Sr, Ca, Mg were prepared by a conventional solid-state reaction. The fabrication procedure, CMAS corrosion resistance, and microstructures of BSCMAS were investigated. The results show that the multi-component ceramics of Ba0.3Sr0.3Ca0.35Mg0.05Al2Si2O8 (B0.3S0.3C0.35M0.05AS) can form a single-phase solid solution by adjusting the concentration of MgO. The CMAS corrosion of B0.3S0.3C0.35M0.05AS were carried out at 1 250, 1 300 ℃ and 1 350 ℃. The B0.3S0.3C0.35M0.05AS showed better CMAS corrosion resistance than Ba0.5Sr0.5Al2Si2O8. The sluggish diffusion of multi-component cations in B0.3S0.3C0.35M0.05AS leads to suppressing the interdiffusion of Ba—Sr with Ca—Mg, combined with the quick formation of anorthite to block the out-diffusion of Ba and Sr, resulting in the improved CMAS corrosion resistance of B0.3S0.3C0.35M0.05AS material.

, authors=Shiliang LUAN, Shuai ZHANG, Ke REN, Yiguang WANG, authorsList=Shiliang LUAN, Shuai ZHANG, Ke REN, Yiguang WANG, authorCompany=null, correspAuthors=Yiguang WANG, authorNote=

LUAN Shiliang (1991-), male, Doctoral candidate. E-mail:

, correspAuthorsNote=
WANG Yiguang (1973-), male, Ph.D., Professor. E-mail:
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采用固相法制备不同摩尔Ba、Sr、Ca、Mg配比的BaO-SrO-CaO-MgO-Al2O3-SiO2(BSCMAS)陶瓷材料,研究多组元陶瓷的制备工艺、显微结构及其抗CMAS腐蚀性能。结果表明:通过调控MgO的含量,在1400 ℃条件下制备了Ba0.3Sr0.3Ca0.35Mg0.05Al2Si2O8(B0.3S0.3C0.35M0.05AS)单相多组元陶瓷材料。在1250、1300 ℃和1350 ℃对B0.3S0.3C0.35M0.05AS进行CMAS腐蚀实验,相比于Ba0.5Sr0.5Al2Si2O8材料,B0.3S0.3C0.35M0.05AS表现出更好的抗CMAS腐蚀性能,这是由于多组元阳离子的迟滞扩散效应减缓了Ba、Sr与Ca、Mg的相互扩散,并快速形成钙长石腐蚀过渡层阻挡Ba、Sr的流失,进而显著改善了材料的抗CMAS腐蚀性能。

, authors=栾世梁, 张帅, 任科, 王一光, authorsList=栾世梁, 张帅, 任科, 王一光, authorCompany=null, correspAuthors=王一光, authorNote=

栾世梁(1991—),男,博士研究生。

, correspAuthorsNote=
王一光(1973—),男,博士,教授。
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LUAN Shiliang (1991-), male, Doctoral candidate. E-mail:

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栾世梁(1991—),男,博士研究生。

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多组元BaO-SrO-CaO-MgO-Al2O3-2SiO2环境障涂层的制备与抗CaO-MgO-Al2O3-SiO2腐蚀性能
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栾世梁 , 张帅 , 任科 , 王一光
硅酸盐学报 | 新型高熵陶瓷材料专题—研究论文 2022,50(6): 1456-1462
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硅酸盐学报 |新型高熵陶瓷材料专题—研究论文 2022 , 50 (6) : 1456 -1462
多组元BaO-SrO-CaO-MgO-Al2O3-2SiO2环境障涂层的制备与抗CaO-MgO-Al2O3-SiO2腐蚀性能
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栾世梁 , 张帅, 任科, 王一光
作者信息
  • 北京理工大学先进结构技术研究院,北京 100081
通讯作者:
王一光(1973—),男,博士,教授。
作者简介:

栾世梁(1991—),男,博士研究生。

Fabrication and CaO-MgO-Al2O3-SiO2 Corrosion Resistance of Multi-Component BaO-SrO-CaO-MgO-Al2O3-2SiO2 Environmental Barrier Coatings
Shiliang LUAN , Shuai ZHANG, Ke REN, Yiguang WANG
Affiliations
  • Institute of Advanced Structure Technology, Beijing Institute of Technology, Beijing 100081, China
  • Corresponding Author:
    WANG Yiguang (1973-), male, Ph.D., Professor. E-mail:

    LUAN Shiliang (1991-), male, Doctoral candidate. E-mail:

出版时间: 2022-06-20 doi: 10.14062/j.issn.0454-5648.20220259
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采用固相法制备不同摩尔Ba、Sr、Ca、Mg配比的BaO-SrO-CaO-MgO-Al2O3-SiO2(BSCMAS)陶瓷材料,研究多组元陶瓷的制备工艺、显微结构及其抗CMAS腐蚀性能。结果表明:通过调控MgO的含量,在1400 ℃条件下制备了Ba0.3Sr0.3Ca0.35Mg0.05Al2Si2O8(B0.3S0.3C0.35M0.05AS)单相多组元陶瓷材料。在1250、1300 ℃和1350 ℃对B0.3S0.3C0.35M0.05AS进行CMAS腐蚀实验,相比于Ba0.5Sr0.5Al2Si2O8材料,B0.3S0.3C0.35M0.05AS表现出更好的抗CMAS腐蚀性能,这是由于多组元阳离子的迟滞扩散效应减缓了Ba、Sr与Ca、Mg的相互扩散,并快速形成钙长石腐蚀过渡层阻挡Ba、Sr的流失,进而显著改善了材料的抗CMAS腐蚀性能。

多组元材料  /  固溶体  /  环境障涂层  /  迟滞扩散

The multi-component ceramics of BaO-SrO-CaO-MgO-Al2O3-2SiO2(BSCMAS) with different molar ratio of Ba, Sr, Ca, Mg were prepared by a conventional solid-state reaction. The fabrication procedure, CMAS corrosion resistance, and microstructures of BSCMAS were investigated. The results show that the multi-component ceramics of Ba0.3Sr0.3Ca0.35Mg0.05Al2Si2O8 (B0.3S0.3C0.35M0.05AS) can form a single-phase solid solution by adjusting the concentration of MgO. The CMAS corrosion of B0.3S0.3C0.35M0.05AS were carried out at 1 250, 1 300 ℃ and 1 350 ℃. The B0.3S0.3C0.35M0.05AS showed better CMAS corrosion resistance than Ba0.5Sr0.5Al2Si2O8. The sluggish diffusion of multi-component cations in B0.3S0.3C0.35M0.05AS leads to suppressing the interdiffusion of Ba—Sr with Ca—Mg, combined with the quick formation of anorthite to block the out-diffusion of Ba and Sr, resulting in the improved CMAS corrosion resistance of B0.3S0.3C0.35M0.05AS material.

multi-component materials  /  solid solution  /  environmental barrier coatings  /  sluggish diffusion
栾世梁, 张帅, 任科, 王一光. 多组元BaO-SrO-CaO-MgO-Al2O3-2SiO2环境障涂层的制备与抗CaO-MgO-Al2O3-SiO2腐蚀性能. 硅酸盐学报, 2022 , 50 (6) : 1456 -1462 . DOI: 10.14062/j.issn.0454-5648.20220259
Shiliang LUAN, Shuai ZHANG, Ke REN, Yiguang WANG. Fabrication and CaO-MgO-Al2O3-SiO2 Corrosion Resistance of Multi-Component BaO-SrO-CaO-MgO-Al2O3-2SiO2 Environmental Barrier Coatings[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (6) : 1456 -1462 . DOI: 10.14062/j.issn.0454-5648.20220259
  • 国家科技重点专项(2017-VI-0020-0093)
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2022年第50卷第6期
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doi: 10.14062/j.issn.0454-5648.20220259
  • 接收时间:2022-04-06
  • 首发时间:2026-10-22
  • 出版时间:2022-06-20
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  • 收稿日期:2022-04-06
  • 修回日期:2022-04-18
基金
国家科技重点专项(2017-VI-0020-0093)
作者信息
    北京理工大学先进结构技术研究院,北京 100081

通讯作者:

王一光(1973—),男,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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