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Article(id=1319236743371542838, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236705027207343, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220224, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1648396800000, receivedDateStr=2022-03-28, revisedDate=1649692800000, revisedDateStr=2022-04-12, acceptedDate=null, acceptedDateStr=null, onlineDate=1792460149853, onlineDateStr=2026-10-20, pubDate=1666195200000, pubDateStr=2022-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792460149853, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792460149853, creator=13701087609, updateTime=1792460149853, updator=13701087609, issue=Issue{id=1319236705027207343, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='10', pageStart='2579', pageEnd='2808', issueExtLink='null', onlineDate='null', pubDate='1666195200000', pubDateStr='2022-10-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792460140711, creator='13701087609', updateTime=1792460672919, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319238937323884737, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236705027207343, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319238937323884738, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236705027207343, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2611, endPage=2621, ext={EN=ArticleExt(id=1319236743891636535, articleId=1319236743371542838, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Synthesis and Catalytic Performance of Core-shell Micro-Mesoporous Composite Zeolite MCM-41@TS-1 Catalysts, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

To solve the problem of a narrow pore applicability of zeolite molecular sieves with MFI topology (TS-1), a core-shell mesoporous composite molecular sieve xMCM-41@TS-1 was synthesized by an in-situ crystallization method. The results show that xMCM-41@TS-1 has a well-crystallized microporous core and mesoporous shell with regular pores, thus effectively improving the reaction mass transfer efficiency, reducing the diffusion resistance, and promoting the effective utilization of active titanium centers. Also, the core-shell mesoporous composite structure is beneficial to shortening the diffusion path of the material, so that the carbon deposition precursor in the microporous can diffuse to the surface in time. According to the catalytic performance results, the catalytic activity of xMCM-41-41@TS-1 in butadiene epoxidation and cyclohexane oxidation can reach 3 times and 2 times greater than that of TS-1, respectively, and the cycle stability is greater than that of TS-1.

, authors=Yingjie WANG1, Bowen LI1, Jiali HE1, Xing WANG1, Jiajie XU1, Jiani LI1, Mei WU1, 2, Jinlong JIANG1, Lingjun CHOU2, Huanling SONG2, authorsList=Yingjie WANG, Bowen LI, Jiali HE, Xing WANG, Jiajie XU, Jiani LI, Mei WU, Jinlong JIANG, Lingjun CHOU, Huanling SONG, authorCompany=null, correspAuthors=Mei WU, authorNote=

WANG Ying Jie (1995-), male, Master candidate. E-mail:

, correspAuthorsNote=
WU Mei (1986-), female, Ph.D., Associate Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319236746387247418, articleId=1319236743371542838, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=核壳型介微孔复合分子筛MCM-41@TS-1的合成及其催化性能, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

为解决具有MFI拓扑结构的沸石类分子筛（TS-1）孔道适用性窄的问题，以原位晶化法合成核壳型介微孔复合分子筛xMCM-41@TS-1。结果表明：xMCM-41@S-1具有结晶完整的微孔核相和孔道规整的介孔壳层，可以有效提高反应传质效率、降低扩散阻力，促使活性钛中心的有效利用，同时介孔复合结构有利于缩短物质的扩散路径，使微孔中的积碳前驱体能及时扩散到表面。催化性能结果表明，xMCM-41-41@TS-1在丁二烯环氧化和环己烷氧化反应中的催化活性分别可以达到TS-1的3倍和2倍，且循环稳定性远高于TS-1。

, authors=王英杰1, 李博文1, 何佳丽1, 王星1, 许佳洁1, 李佳妮1, 吴妹1, 2, 蒋金龙1, 丑凌军2, 宋焕玲2, authorsList=王英杰, 李博文, 何佳丽, 王星, 许佳洁, 李佳妮, 吴妹, 蒋金龙, 丑凌军, 宋焕玲, authorCompany=null, correspAuthors=吴妹, authorNote=

王英杰（1995—），男，硕士研究生。

, correspAuthorsNote=
吴妹（1986—），女，博士，副教授。
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WANG Ying Jie (1995-), male, Master candidate. E-mail:

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核壳型介微孔复合分子筛MCM-41@TS-1的合成及其催化性能
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王英杰 1 , 李博文 1 , 何佳丽 1 , 王星 1 , 许佳洁 1 , 李佳妮 1 , 吴妹 1, 2 , 蒋金龙 1 , 丑凌军 2 , 宋焕玲 2
硅酸盐学报 | 研究论文 2022,50(10): 2611-2621
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硅酸盐学报 |研究论文 2022 , 50 (10) : 2611 -2621
核壳型介微孔复合分子筛MCM-41@TS-1的合成及其催化性能
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王英杰1 , 李博文1, 何佳丽1, 王星1, 许佳洁1, 李佳妮1, 吴妹1, 2 , 蒋金龙1, 丑凌军2, 宋焕玲2
作者信息
  • 1．淮阴工学院化学工程学院，江苏省凹土资源利用重点实验室，江苏 淮安 223003
  • 2．中国科学院兰州化学物理研究所，羰基合成与选择性氧化国家重点实验室，兰州 730000
通讯作者:
吴妹（1986—），女，博士，副教授。
作者简介:

王英杰（1995—），男，硕士研究生。

Synthesis and Catalytic Performance of Core-shell Micro-Mesoporous Composite Zeolite MCM-41@TS-1 Catalysts
Yingjie WANG1 , Bowen LI1, Jiali HE1, Xing WANG1, Jiajie XU1, Jiani LI1, Mei WU1, 2 , Jinlong JIANG1, Lingjun CHOU2, Huanling SONG2
Affiliations
  • 1.Faculty of Chemical Engineering, Huaiyin Institute of Technology, Key Laboratory for Palygorskite Science and Applied Technology of Jiangsu Province, Huai'an 223003, Jiangsu China
  • 2.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
    • Corresponding Author:
    WU Mei (1986-), female, Ph.D., Associate Professor. E-mail:

    WANG Ying Jie (1995-), male, Master candidate. E-mail:

出版时间: 2022-10-20 doi: 10.14062/j.issn.0454-5648.20220224
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为解决具有MFI拓扑结构的沸石类分子筛（TS-1）孔道适用性窄的问题，以原位晶化法合成核壳型介微孔复合分子筛xMCM-41@TS-1。结果表明：xMCM-41@S-1具有结晶完整的微孔核相和孔道规整的介孔壳层，可以有效提高反应传质效率、降低扩散阻力，促使活性钛中心的有效利用，同时介孔复合结构有利于缩短物质的扩散路径，使微孔中的积碳前驱体能及时扩散到表面。催化性能结果表明，xMCM-41-41@TS-1在丁二烯环氧化和环己烷氧化反应中的催化活性分别可以达到TS-1的3倍和2倍，且循环稳定性远高于TS-1。

核壳结构  /  介微孔复合结构  /  活性钛中心  /  丁二烯环氧化  /  环己烷氧化

To solve the problem of a narrow pore applicability of zeolite molecular sieves with MFI topology (TS-1), a core-shell mesoporous composite molecular sieve xMCM-41@TS-1 was synthesized by an in-situ crystallization method. The results show that xMCM-41@TS-1 has a well-crystallized microporous core and mesoporous shell with regular pores, thus effectively improving the reaction mass transfer efficiency, reducing the diffusion resistance, and promoting the effective utilization of active titanium centers. Also, the core-shell mesoporous composite structure is beneficial to shortening the diffusion path of the material, so that the carbon deposition precursor in the microporous can diffuse to the surface in time. According to the catalytic performance results, the catalytic activity of xMCM-41-41@TS-1 in butadiene epoxidation and cyclohexane oxidation can reach 3 times and 2 times greater than that of TS-1, respectively, and the cycle stability is greater than that of TS-1.

active titanium center  /  butadiene epoxidation  /  core-shell structure  /  cyclohexane oxidation  /  micro-mesoporous
王英杰, 李博文, 何佳丽, 王星, 许佳洁, 李佳妮, 吴妹, 蒋金龙, 丑凌军, 宋焕玲. 核壳型介微孔复合分子筛MCM-41@TS-1的合成及其催化性能. 硅酸盐学报, 2022 , 50 (10) : 2611 -2621 . DOI: 10.14062/j.issn.0454-5648.20220224
Yingjie WANG, Bowen LI, Jiali HE, Xing WANG, Jiajie XU, Jiani LI, Mei WU, Jinlong JIANG, Lingjun CHOU, Huanling SONG. Synthesis and Catalytic Performance of Core-shell Micro-Mesoporous Composite Zeolite MCM-41@TS-1 Catalysts[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (10) : 2611 -2621 . DOI: 10.14062/j.issn.0454-5648.20220224
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  • 江苏省青蓝工程“优秀青年骨干教师”项目
  • 江苏省高校自然科学研究重大项目(20KJA530002)
  • 江苏省凹土资源利用重点实验室自主课题(HPZ202001)
  • 江苏省医用材料及高端医疗器械工程研究中心开放课题(CEMD-2001)
  • 江苏省研究生科研与实践创新计划项目(SJCX21_1498)
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doi: 10.14062/j.issn.0454-5648.20220224
  • 接收时间：2022-03-28
  • 首发时间：2026-10-20
  • 出版时间：2022-10-20
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  • 收稿日期：2022-03-28
  • 修回日期：2022-04-12
基金
江苏省青蓝工程“优秀青年骨干教师”项目
江苏省高校自然科学研究重大项目(20KJA530002)
江苏省凹土资源利用重点实验室自主课题(HPZ202001)
江苏省医用材料及高端医疗器械工程研究中心开放课题(CEMD-2001)
江苏省研究生科研与实践创新计划项目(SJCX21_1498)
作者信息
    1．淮阴工学院化学工程学院，江苏省凹土资源利用重点实验室，江苏 淮安 223003
    2．中国科学院兰州化学物理研究所，羰基合成与选择性氧化国家重点实验室，兰州 730000

通讯作者:

吴妹（1986—），女，博士，副教授。
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2种不同金属材料的力学参数
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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