Article(id=1319236899798110668, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236892848148894, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220124, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1645372800000, receivedDateStr=2022-02-21, revisedDate=1649174400000, revisedDateStr=2022-04-06, acceptedDate=null, acceptedDateStr=null, onlineDate=1792460187148, onlineDateStr=2026-10-20, pubDate=1668873600000, pubDateStr=2022-11-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792460187148, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792460187148, creator=13701087609, updateTime=1792460187148, updator=13701087609, issue=Issue{id=1319236892848148894, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='11', pageStart='2809', pageEnd='3090', issueExtLink='null', onlineDate='null', pubDate='1668873600000', pubDateStr='2022-11-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792460185491, creator='13701087609', updateTime=1792460700564, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319239053275411177, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236892848148894, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319239053275411178, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236892848148894, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2855, endPage=2867, ext={EN=ArticleExt(id=1319236900087517645, articleId=1319236899798110668, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of Magnesium Oxide Doping on Formation and Hydration of Aluminate, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

To investigate the occurrence of periclase in clinker aluminate and reveal the hydration mechanism, aluminates were synthesized via MgO doping at various contents. Their structure and hydrates were characterized by scanning electron microscopy, X-ray diffraction and Fourier transform infrared spectroscopy. The results indicate that higher sintering temperature and MgO content improve the formation and stability of C4AF and C12F7. A phase separation occurs in molten aluminum phase. The black phase includes the main minerals like C3A and periclase, while glass and yellow phases both have a low MgO content. The hydration heat of aluminate phase in the first day decreases with the increase of MgO content, indicating that MgO doping decreases the hydration rate of aluminate phase. In addition, the layered double hydroxides with a Mg∶Al ratio of 2 or 3 appear in the hydration products of aluminate incorporated with MgO.

, authors=Qiang SONG1, Jiao NIE1, Yanxin CHEN1, Yaru HU1, Yang DENG2, Hui LI1, authorsList=Qiang SONG, Jiao NIE, Yanxin CHEN, Yaru HU, Yang DENG, Hui LI, authorCompany=null, correspAuthors=Yanxin CHEN, Hui LI, authorNote=

SONG Qiang (1980-), male, Ph.D., Lecturer. E-mail:

, correspAuthorsNote=
CHEN Yanxin (1974-), male, Ph.D., Professor. E-mail:
LI Hui (1973-), female, Ph.D., Professor.
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319236901937205710, articleId=1319236899798110668, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=氧化镁掺杂对铝酸盐形成和水化的影响, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

为探究方镁石在熟料铝相中的赋存状态,揭示水化反应机制,合成了不同MgO含量的铝酸盐,采用扫描电子显微镜,X射线衍射,红外光谱等,研究了MgO对合成铝酸盐的形成和水化性质的影响。结果表明:提高煅烧温度,增加MgO含量有助于C4AF和C12F7的形成和稳定;含镁铝酸盐熔体发生分相现象,黑色相主要由C3A和MgO组成,玻璃体和黄色相中的MgO含量较低,形成了Ca20Al26Mg3Si3O68和Ca7MgAl10O23等含镁化合物;MgO掺杂降低了铝酸盐相的水化速率;随着MgO含量增加,铝酸盐相1 d的水化热降低。MgO掺杂的铝酸盐水化产物中存在Mg∶Al摩尔比约为2或3的镁铝双金属氢氧化物。

, authors=宋强1, 聂娇1, 陈延信1, 胡亚茹1, 邓洋2, 李辉1, authorsList=宋强, 聂娇, 陈延信, 胡亚茹, 邓洋, 李辉, authorCompany=null, correspAuthors=陈延信, 李辉, authorNote=

宋强(1980—),男,博士,讲师。

, correspAuthorsNote=
陈延信(1974—),男,博士,教授。
李辉(1973—),女,博士,教授。
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氧化镁掺杂对铝酸盐形成和水化的影响
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宋强 1 , 聂娇 1 , 陈延信 1 , 胡亚茹 1 , 邓洋 2 , 李辉 1
硅酸盐学报 | 研究论文 2022,50(11): 2855-2867
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硅酸盐学报 |研究论文 2022 , 50 (11) : 2855 -2867
氧化镁掺杂对铝酸盐形成和水化的影响
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宋强1 , 聂娇1, 陈延信1 , 胡亚茹1, 邓洋2, 李辉1
作者信息
  • 1.西安建筑科技大学材料科学与工程学院,西安 710055
  • 2.陕西富平生态水泥有限公司,陕西 渭南 711709
通讯作者:
陈延信(1974—),男,博士,教授。
李辉(1973—),女,博士,教授。
作者简介:

宋强(1980—),男,博士,讲师。

Effect of Magnesium Oxide Doping on Formation and Hydration of Aluminate
Qiang SONG1 , Jiao NIE1, Yanxin CHEN1 , Yaru HU1, Yang DENG2, Hui LI1
Affiliations
  • 1.College of Materials and Science and Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
  • 2.Shaanxi Fuping Eco-cement CO., LTD, Weinan 711709, Shaanxi, China
  • Corresponding Author:
    CHEN Yanxin (1974-), male, Ph.D., Professor. E-mail:
    LI Hui (1973-), female, Ph.D., Professor.

    SONG Qiang (1980-), male, Ph.D., Lecturer. E-mail:

出版时间: 2022-11-20 doi: 10.14062/j.issn.0454-5648.20220124
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为探究方镁石在熟料铝相中的赋存状态,揭示水化反应机制,合成了不同MgO含量的铝酸盐,采用扫描电子显微镜,X射线衍射,红外光谱等,研究了MgO对合成铝酸盐的形成和水化性质的影响。结果表明:提高煅烧温度,增加MgO含量有助于C4AF和C12F7的形成和稳定;含镁铝酸盐熔体发生分相现象,黑色相主要由C3A和MgO组成,玻璃体和黄色相中的MgO含量较低,形成了Ca20Al26Mg3Si3O68和Ca7MgAl10O23等含镁化合物;MgO掺杂降低了铝酸盐相的水化速率;随着MgO含量增加,铝酸盐相1 d的水化热降低。MgO掺杂的铝酸盐水化产物中存在Mg∶Al摩尔比约为2或3的镁铝双金属氢氧化物。

铝酸盐  /  氧化镁掺杂  /  晶体结构  /  水化  /  镁铝双金属氢氧化物

To investigate the occurrence of periclase in clinker aluminate and reveal the hydration mechanism, aluminates were synthesized via MgO doping at various contents. Their structure and hydrates were characterized by scanning electron microscopy, X-ray diffraction and Fourier transform infrared spectroscopy. The results indicate that higher sintering temperature and MgO content improve the formation and stability of C4AF and C12F7. A phase separation occurs in molten aluminum phase. The black phase includes the main minerals like C3A and periclase, while glass and yellow phases both have a low MgO content. The hydration heat of aluminate phase in the first day decreases with the increase of MgO content, indicating that MgO doping decreases the hydration rate of aluminate phase. In addition, the layered double hydroxides with a Mg∶Al ratio of 2 or 3 appear in the hydration products of aluminate incorporated with MgO.

aluminate  /  magnesium oxide doping  /  crystal structure  /  hydration  /  magnesium-aluminium layered double hydroxide
宋强, 聂娇, 陈延信, 胡亚茹, 邓洋, 李辉. 氧化镁掺杂对铝酸盐形成和水化的影响. 硅酸盐学报, 2022 , 50 (11) : 2855 -2867 . DOI: 10.14062/j.issn.0454-5648.20220124
Qiang SONG, Jiao NIE, Yanxin CHEN, Yaru HU, Yang DENG, Hui LI. Effect of Magnesium Oxide Doping on Formation and Hydration of Aluminate[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (11) : 2855 -2867 . DOI: 10.14062/j.issn.0454-5648.20220124
  • 陕西省科学技术研究计划(2021GY-203; 2021TD-53; 2022GY-418; 2022KXJ-008)
  • 陕西省教育厅重点研发计划(20JS079; 20JY040)
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2022年第50卷第11期
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doi: 10.14062/j.issn.0454-5648.20220124
  • 接收时间:2022-02-21
  • 首发时间:2026-10-20
  • 出版时间:2022-11-20
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  • 收稿日期:2022-02-21
  • 修回日期:2022-04-06
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陕西省科学技术研究计划(2021GY-203; 2021TD-53; 2022GY-418; 2022KXJ-008)
陕西省教育厅重点研发计划(20JS079; 20JY040)
作者信息
    1.西安建筑科技大学材料科学与工程学院,西安 710055
    2.陕西富平生态水泥有限公司,陕西 渭南 711709

通讯作者:

陈延信(1974—),男,博士,教授。
李辉(1973—),女,博士,教授。
参考文献
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20220124
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2种不同金属材料的力学参数
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属数
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genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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