Article(id=1319236728330760545, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236705027207343, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220103, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1644076800000, receivedDateStr=2022-02-06, revisedDate=1645200000000, revisedDateStr=2022-02-19, acceptedDate=null, acceptedDateStr=null, onlineDate=1792460146267, onlineDateStr=2026-10-20, pubDate=1666195200000, pubDateStr=2022-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792460146267, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792460146267, creator=13701087609, updateTime=1792460146267, updator=13701087609, issue=Issue{id=1319236705027207343, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='10', pageStart='2579', pageEnd='2808', issueExtLink='null', onlineDate='null', pubDate='1666195200000', pubDateStr='2022-10-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792460140711, creator='13701087609', updateTime=1792460672919, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319238937323884737, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236705027207343, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319238937323884738, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236705027207343, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2800, endPage=2808, ext={EN=ArticleExt(id=1319236728741802338, articleId=1319236728330760545, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Application of Attapulgite in Negative Electrode Protection of Lithium Metal Battery, columnId=1321898011471496112, journalTitle=Journal of the Chinese Ceramic Society, columnName=Advanced Founctional Geomaterials—Review, runingTitle=null, highlight=null, articleAbstract=

Lithium metal batteries are considered as one of the most promising energy storage batteries due to their high energy density. However, the growth of lithium dendrites in the lithium metal anode can lead to the capacity degradation and even safety problems. In this paper, attapulgite was loaded on fiber membrane for the application of lithium metal anode protection, assembling them into symmetrical cells and lithium iron phosphate full cells for electrochemical testing. The results show that the growth of lithium dendrites can be effectively inhibited due to the addition of attapulgite to the fibrous membrane. The polarization voltage of the symmetric cell is only 83.2 mV at a current density of 2 mA/cm2 and deposition capacity of 1 mA·h/cm2 for 500 h. The specific capacity of the full cell with attapulgite added to the fibrous membrane remains 84.92 mA·h/g after 1 000 cycles at 1 C. The inhibition of lithium dendrites by attapulgite provides an approach for the protection of lithium metal batteries with negative electrodes.

, authors=Ying ZHANG1, 2, 3, Caihong YANG1, 2, 3, Aidong TANG1, 2, 3, 4, Huaming YANG1, 2, 3, 5, authorsList=Ying ZHANG, Caihong YANG, Aidong TANG, Huaming YANG, authorCompany=null, correspAuthors=Caihong YANG, authorNote=

ZHANG Ying (1998-), female, Master candidate. E-mail:

, correspAuthorsNote=
YANG Caihong (1993-), female, Ph.D. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319236729169621347, articleId=1319236728330760545, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=凹凸棒石在锂金属电池负极保护中的应用, columnId=1321898011626685361, journalTitle=硅酸盐学报, columnName=高性能矿物功能材料专题—综合评述, runingTitle=null, highlight=null, articleAbstract=

锂金属电池因能量密度高被认为是极具发展潜力的储能电池之一。然而锂金属负极上锂枝晶的生长会导致容量衰减甚至安全问题。为此,将凹凸棒石负载至纤维膜上应用于锂金属电池的负极保护,组装成对称电池及磷酸铁锂全电池进行电化学测试。结果表明:添加凹凸棒石的纤维膜可有效抑制锂枝晶的生长,其对称电池在沉积容量为1 mA·h/cm2、电流密度为2 mA/cm2下循环500 h时极化电压仅为83.2 mV,1 C倍率下加入凹凸棒石纤维膜的全电池循环1 000圈后放电比容量仍有84.92 mA·h/g。综上,凹凸棒石对锂枝晶有抑制作用,为锂金属电池负极保护提供了新思路。

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张莹(1998—),女,硕士研究生。

, correspAuthorsNote=
杨彩虹(1993—),女,博士。
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张莹 1, 2, 3 , 杨彩虹 1, 2, 3 , 唐爱东 1, 2, 3, 4 , 杨华明 1, 2, 3, 5
硅酸盐学报 | 高性能矿物功能材料专题—综合评述 2022,50(10): 2800-2808
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凹凸棒石在锂金属电池负极保护中的应用
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张莹1, 2, 3 , 杨彩虹1, 2, 3 , 唐爱东1, 2, 3, 4, 杨华明1, 2, 3, 5
作者信息
  • 1.中国地质大学(武汉)纳米矿物材料及应用教育部工程研究中心
  • 2.中国地质大学(武汉)材料与化学学院
  • 3.中国非金属矿行业矿物功能材料重点实验室,中国地质大学(武汉),武汉 430074
  • 4.中南大学化学化工学院,长沙 410083
  • 5.中南大学资源加工与生物工程学院,长沙 410083
通讯作者:
杨彩虹(1993—),女,博士。
作者简介:

张莹(1998—),女,硕士研究生。

Application of Attapulgite in Negative Electrode Protection of Lithium Metal Battery
Ying ZHANG1, 2, 3 , Caihong YANG1, 2, 3 , Aidong TANG1, 2, 3, 4, Huaming YANG1, 2, 3, 5
Affiliations
  • 1.Engineering Research Center of Nano-Geomaterials of Ministry of Education, Wuhan, 430074, China
  • 2.Faculty of Materials Science and Chemistry, Wuhan, 430074, China
  • 3.Key Laboratory of Functional Geomaterials in China Nonmetallic Minerals Industry, China University of Geosciences, Wuhan 430074
  • 4.School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China
  • 5.School of Minerals Processing and Bioengineering, Central South University, Changsha 410083, China
  • Corresponding Author:
    YANG Caihong (1993-), female, Ph.D. E-mail:

    ZHANG Ying (1998-), female, Master candidate. E-mail:

出版时间: 2022-10-20 doi: 10.14062/j.issn.0454-5648.20220103
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锂金属电池因能量密度高被认为是极具发展潜力的储能电池之一。然而锂金属负极上锂枝晶的生长会导致容量衰减甚至安全问题。为此,将凹凸棒石负载至纤维膜上应用于锂金属电池的负极保护,组装成对称电池及磷酸铁锂全电池进行电化学测试。结果表明:添加凹凸棒石的纤维膜可有效抑制锂枝晶的生长,其对称电池在沉积容量为1 mA·h/cm2、电流密度为2 mA/cm2下循环500 h时极化电压仅为83.2 mV,1 C倍率下加入凹凸棒石纤维膜的全电池循环1 000圈后放电比容量仍有84.92 mA·h/g。综上,凹凸棒石对锂枝晶有抑制作用,为锂金属电池负极保护提供了新思路。

凹凸棒石  /  多孔结构  /  锂金属负极  /  锂枝晶

Lithium metal batteries are considered as one of the most promising energy storage batteries due to their high energy density. However, the growth of lithium dendrites in the lithium metal anode can lead to the capacity degradation and even safety problems. In this paper, attapulgite was loaded on fiber membrane for the application of lithium metal anode protection, assembling them into symmetrical cells and lithium iron phosphate full cells for electrochemical testing. The results show that the growth of lithium dendrites can be effectively inhibited due to the addition of attapulgite to the fibrous membrane. The polarization voltage of the symmetric cell is only 83.2 mV at a current density of 2 mA/cm2 and deposition capacity of 1 mA·h/cm2 for 500 h. The specific capacity of the full cell with attapulgite added to the fibrous membrane remains 84.92 mA·h/g after 1 000 cycles at 1 C. The inhibition of lithium dendrites by attapulgite provides an approach for the protection of lithium metal batteries with negative electrodes.

attapulgite  /  porous structure  /  lithium metal anode  /  lithium dendrites
张莹, 杨彩虹, 唐爱东, 杨华明. 凹凸棒石在锂金属电池负极保护中的应用. 硅酸盐学报, 2022 , 50 (10) : 2800 -2808 . DOI: 10.14062/j.issn.0454-5648.20220103
Ying ZHANG, Caihong YANG, Aidong TANG, Huaming YANG. Application of Attapulgite in Negative Electrode Protection of Lithium Metal Battery[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (10) : 2800 -2808 . DOI: 10.14062/j.issn.0454-5648.20220103
  • 国家自然科学基金(51225403)
  • 纳米矿物材料及应用教育部工程研究中心开放课题(NGM2020KF001)
  • 中国博士后科学基金面上(2022M712948)
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2022年第50卷第10期
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doi: 10.14062/j.issn.0454-5648.20220103
  • 接收时间:2022-02-06
  • 首发时间:2026-10-20
  • 出版时间:2022-10-20
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  • 收稿日期:2022-02-06
  • 修回日期:2022-02-19
基金
国家自然科学基金(51225403)
纳米矿物材料及应用教育部工程研究中心开放课题(NGM2020KF001)
中国博士后科学基金面上(2022M712948)
作者信息
    1.中国地质大学(武汉)纳米矿物材料及应用教育部工程研究中心
    2.中国地质大学(武汉)材料与化学学院
    3.中国非金属矿行业矿物功能材料重点实验室,中国地质大学(武汉),武汉 430074
    4.中南大学化学化工学院,长沙 410083
    5.中南大学资源加工与生物工程学院,长沙 410083

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杨彩虹(1993—),女,博士。
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20220103
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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