Article(id=1319986540848197914, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220050, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1642348800000, receivedDateStr=2022-01-17, revisedDate=1645632000000, revisedDateStr=2022-02-24, acceptedDate=null, acceptedDateStr=null, onlineDate=1792638915501, onlineDateStr=2026-10-22, pubDate=1655654400000, pubDateStr=2022-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792638915501, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792638915501, creator=13701087609, updateTime=1792638915501, updator=13701087609, issue=Issue{id=1319986532933555119, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='6', pageStart='1455', pageEnd='1774', issueExtLink='null', onlineDate='null', pubDate='1655654400000', pubDateStr='2022-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792638913615, creator='13701087609', updateTime=1792639299444, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319988151507075566, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319988151507075567, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1463, endPage=1474, ext={EN=ArticleExt(id=1319986541494120733, articleId=1319986540848197914, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Friction and Wear Characteristics of High Entropy (TiVTaMoW)C Ceramics Sliding Against Different Paired Balls, columnId=1321892005832151399, journalTitle=Journal of the Chinese Ceramic Society, columnName=Advanced High Entropy Ceramics—Research Articles, runingTitle=null, highlight=null, articleAbstract=

To explore the application prospects of high-entropy carbide ceramics as wear-resistant parts, a high-entropy (TiVTaMoW)C ceramic with a uniform distribution of elements was prepared via ball milling and subsequent two-step sintering with metal carbides as raw materials. The friction and wear properties of (TiVTaMoW)C ceramic at room temperature and 800 ℃ sliding against Al2O3, SiC, and Si3N4 balls were investigated, respectively. The results show that (TiVTaMoW)C ceramic exhibits superior tribological properties with low friction coefficients and wear rates at room temperature. Especially for sliding against SiC ball, the friction coefficient and wear rate are (0.38±0.01) and (1.52±0.36)×10-7 mm3/(N·m). The surface of (TiVTaMoW)C ceramic is severely oxidized during sliding and accompanied by aggravated wear when the temperature is 800 ℃. The wear rates of high-entropy carbide ceramic sliding against all of the friction pair balls can increase to 10-4 mm3/Nm. The oxidation products of MoO3 and V2O5 with low shear stress characteristics form self-lubricating and transferring films between the friction pairs, which made the friction coefficients maintain the same level as that at room temperature. In addition, SiC friction pair presents better tribological compatibility with (TiVTaMoW)C ceramic with a low friction coefficient and wear rate at room temperature and 800 ℃.

, authors=Jicheng LI1, 2, Shuna CHEN1, 2, Qiuan SUN1, 2, Hengzhong FAN1, Yunfeng SU1, Junjie SONG1, Litian HU1, Yongsheng ZHANG1, 2, authorsList=Jicheng LI, Shuna CHEN, Qiuan SUN, Hengzhong FAN, Yunfeng SU, Junjie SONG, Litian HU, Yongsheng ZHANG, authorCompany=null, correspAuthors=Hengzhong FAN, Yongsheng ZHANG, authorNote=

LI Jicheng (1994-), male, Master candidate. E-mail:

, correspAuthorsNote=
ZHANG Yongsheng (1977-), male, Ph.D., Professor. E-mail:
FAN Hengzhong (1987-), male, Ph.D., Associate Professor.
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319986541825470750, articleId=1319986540848197914, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=高熵(TiVTaMoW)C陶瓷与不同配副间的摩擦磨损特性, columnId=1321892006461297000, journalTitle=硅酸盐学报, columnName=新型高熵陶瓷材料专题—研究论文, runingTitle=null, highlight=null, articleAbstract=

为探究高熵碳化物陶瓷作为耐磨部件在摩擦学领域中的应用前景,以金属碳化物为原料,通过高能球磨和两步热压烧结法制备了一种元素分布均匀、无偏聚和偏析的高熵(TiVTaMoW)C陶瓷。研究了(TiVTaMoW)C与Al2O3、SiC和Si3N4 3种配副材料在室温及800 ℃条件下的摩擦磨损特性。结果表明:室温条件下,(TiVTaMoW)C与3种配副对摩均表现出优异的摩擦学性能,尤其与SiC对摩具有最低的摩擦系数和磨损率,分别可低至(0.38±0.01)和(1.52±0.36)×10-7 mm3/(N·m)。800 ℃条件下,(TiVTaMoW)C表面氧化严重,磨损明显加剧,磨损率上升至10-4 mm3/(N·m)数量级。高温氧化生成的MoO3和V2O5具有较低剪切强度,摩擦过程转移至配副球接触面上形成转移膜,有效保护了配副材料的磨损。综合比较,SiC作为配副在室温和800 ℃条件下均表现出更优异的摩擦相容性。

, authors=李继承1, 2, 陈淑娜1, 2, 孙秋安1, 2, 樊恒中1, 苏云峰1, 宋俊杰1, 胡丽天1, 张永胜1, 2, authorsList=李继承, 陈淑娜, 孙秋安, 樊恒中, 苏云峰, 宋俊杰, 胡丽天, 张永胜, authorCompany=null, correspAuthors=樊恒中, 张永胜, authorNote=

李继承(1994—),男,硕士研究生。

, correspAuthorsNote=
张永胜(1977—),男,博士,研究员。
樊恒中(1987—),男,博士,副研究员。
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高熵(TiVTaMoW)C陶瓷与不同配副间的摩擦磨损特性
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李继承 1, 2 , 陈淑娜 1, 2 , 孙秋安 1, 2 , 樊恒中 1 , 苏云峰 1 , 宋俊杰 1 , 胡丽天 1 , 张永胜 1, 2
硅酸盐学报 | 新型高熵陶瓷材料专题—研究论文 2022,50(6): 1463-1474
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硅酸盐学报 |新型高熵陶瓷材料专题—研究论文 2022 , 50 (6) : 1463 -1474
高熵(TiVTaMoW)C陶瓷与不同配副间的摩擦磨损特性
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李继承1, 2 , 陈淑娜1, 2, 孙秋安1, 2, 樊恒中1 , 苏云峰1, 宋俊杰1, 胡丽天1, 张永胜1, 2
作者信息
  • 1.中国科学院兰州化学物理研究所,固体润滑国家重点实验室,兰州 730000
  • 2.中国科学院大学材料科学与光电技术学院,北京 100049
通讯作者:
张永胜(1977—),男,博士,研究员。
樊恒中(1987—),男,博士,副研究员。
作者简介:

李继承(1994—),男,硕士研究生。

Friction and Wear Characteristics of High Entropy (TiVTaMoW)C Ceramics Sliding Against Different Paired Balls
Jicheng LI1, 2 , Shuna CHEN1, 2, Qiuan SUN1, 2, Hengzhong FAN1 , Yunfeng SU1, Junjie SONG1, Litian HU1, Yongsheng ZHANG1, 2
Affiliations
  • 1.State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, Gansu, China
  • 2.Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
  • Corresponding Author:
    ZHANG Yongsheng (1977-), male, Ph.D., Professor. E-mail:
    FAN Hengzhong (1987-), male, Ph.D., Associate Professor.

    LI Jicheng (1994-), male, Master candidate. E-mail:

出版时间: 2022-06-20 doi: 10.14062/j.issn.0454-5648.20220050
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为探究高熵碳化物陶瓷作为耐磨部件在摩擦学领域中的应用前景,以金属碳化物为原料,通过高能球磨和两步热压烧结法制备了一种元素分布均匀、无偏聚和偏析的高熵(TiVTaMoW)C陶瓷。研究了(TiVTaMoW)C与Al2O3、SiC和Si3N4 3种配副材料在室温及800 ℃条件下的摩擦磨损特性。结果表明:室温条件下,(TiVTaMoW)C与3种配副对摩均表现出优异的摩擦学性能,尤其与SiC对摩具有最低的摩擦系数和磨损率,分别可低至(0.38±0.01)和(1.52±0.36)×10-7 mm3/(N·m)。800 ℃条件下,(TiVTaMoW)C表面氧化严重,磨损明显加剧,磨损率上升至10-4 mm3/(N·m)数量级。高温氧化生成的MoO3和V2O5具有较低剪切强度,摩擦过程转移至配副球接触面上形成转移膜,有效保护了配副材料的磨损。综合比较,SiC作为配副在室温和800 ℃条件下均表现出更优异的摩擦相容性。

高熵  /  碳化物  /  摩擦磨损  /  高温氧化

To explore the application prospects of high-entropy carbide ceramics as wear-resistant parts, a high-entropy (TiVTaMoW)C ceramic with a uniform distribution of elements was prepared via ball milling and subsequent two-step sintering with metal carbides as raw materials. The friction and wear properties of (TiVTaMoW)C ceramic at room temperature and 800 ℃ sliding against Al2O3, SiC, and Si3N4 balls were investigated, respectively. The results show that (TiVTaMoW)C ceramic exhibits superior tribological properties with low friction coefficients and wear rates at room temperature. Especially for sliding against SiC ball, the friction coefficient and wear rate are (0.38±0.01) and (1.52±0.36)×10-7 mm3/(N·m). The surface of (TiVTaMoW)C ceramic is severely oxidized during sliding and accompanied by aggravated wear when the temperature is 800 ℃. The wear rates of high-entropy carbide ceramic sliding against all of the friction pair balls can increase to 10-4 mm3/Nm. The oxidation products of MoO3 and V2O5 with low shear stress characteristics form self-lubricating and transferring films between the friction pairs, which made the friction coefficients maintain the same level as that at room temperature. In addition, SiC friction pair presents better tribological compatibility with (TiVTaMoW)C ceramic with a low friction coefficient and wear rate at room temperature and 800 ℃.

high entropy  /  carbide  /  friction and wear  /  high temperature oxidation
李继承, 陈淑娜, 孙秋安, 樊恒中, 苏云峰, 宋俊杰, 胡丽天, 张永胜. 高熵(TiVTaMoW)C陶瓷与不同配副间的摩擦磨损特性. 硅酸盐学报, 2022 , 50 (6) : 1463 -1474 . DOI: 10.14062/j.issn.0454-5648.20220050
Jicheng LI, Shuna CHEN, Qiuan SUN, Hengzhong FAN, Yunfeng SU, Junjie SONG, Litian HU, Yongsheng ZHANG. Friction and Wear Characteristics of High Entropy (TiVTaMoW)C Ceramics Sliding Against Different Paired Balls[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (6) : 1463 -1474 . DOI: 10.14062/j.issn.0454-5648.20220050
  • 国家自然科学基金(51902317)
  • 甘肃省重点研发计划(21YF5WA140)
  • 中国科学院“西部之光”人才培养计划(2021)
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doi: 10.14062/j.issn.0454-5648.20220050
  • 接收时间:2022-01-17
  • 首发时间:2026-10-22
  • 出版时间:2022-06-20
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  • 收稿日期:2022-01-17
  • 修回日期:2022-02-24
基金
国家自然科学基金(51902317)
甘肃省重点研发计划(21YF5WA140)
中国科学院“西部之光”人才培养计划(2021)
作者信息
    1.中国科学院兰州化学物理研究所,固体润滑国家重点实验室,兰州 730000
    2.中国科学院大学材料科学与光电技术学院,北京 100049

通讯作者:

张永胜(1977—),男,博士,研究员。
樊恒中(1987—),男,博士,副研究员。
参考文献
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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