Article(id=1319236589524464570, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236561179366013, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20220016, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1642262400000, receivedDateStr=2022-01-16, revisedDate=1643299200000, revisedDateStr=2022-01-28, acceptedDate=null, acceptedDateStr=null, onlineDate=1792460113173, onlineDateStr=2026-10-20, pubDate=1663603200000, pubDateStr=2022-09-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792460113173, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792460113173, creator=13701087609, updateTime=1792460113173, updator=13701087609, issue=Issue{id=1319236561179366013, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='9', pageStart='2351', pageEnd='2578', issueExtLink='null', onlineDate='null', pubDate='1663603200000', pubDateStr='2022-09-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792460106415, creator='13701087609', updateTime=1792460650608, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319238843744764843, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236561179366013, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319238843744764844, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236561179366013, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2380, endPage=2387, ext={EN=ArticleExt(id=1319236589759345595, articleId=1319236589524464570, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of Molar Ratio of Ca2+ and Co2+ on Infrared Radiation Properties of Co-doped LaAlO3 Ceramics, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

n(Ca2+)/n(Co2+)(n is mole) co-doped LaAlO3 ceramics were synthesized by a solid-phase reaction technique. The effect of n(Ca2+)/nCo2+ doping ratio on the infrared radiation performance of LaAlO3 ceramics (La1-xCaxAl0.8Co0.2O3, 0.25≤n(Ca2+)/n(Co2+)≤2.00) was investigated, and the mechanism for improving infrared radiation property was analyzed. The result reveals that n(Ca2+)/n(Co2+) co-doped LaAlO3 ceramics have a perovskite crystal structure. Increasing the doping ratio (0.25≤n(Ca2+)/n(Co2+)≤1.00) improves the emissivity in the wavelength range of 0.76-2.50 μm. The ceramic specimen with n(Ca2+)/n(Co2+) of 1.00 (La0.8Ca0.2Al0.8Co0.2O3) has the maximum average emissivity (0.87). In the 2.50-14.0 μm band, the average emissivity of all n(Ca2+)/n(Co2+) co-doped LaAlO3 ceramics is generally greater than 0.94. The improvement of emissivity can be attributed to the enhancement of free carrier absorption, impurity absorption and lattice vibration absorption. This novel infrared ceramic with a high emissivity has promising prospects for energy-saving applications of thermal equipment.

, authors=Xueqing WANG1, Qinghu WANG1, Xiong LIANG1, Yibiao XU1, Tianbin ZHU1, Shaobai SANG1, Yawei LI1, Yixiang CHEN2, Yong LI2, Jiangtao LI2, authorsList=Xueqing WANG, Qinghu WANG, Xiong LIANG, Yibiao XU, Tianbin ZHU, Shaobai SANG, Yawei LI, Yixiang CHEN, Yong LI, Jiangtao LI, authorCompany=null, correspAuthors=Qinghu WANG, authorNote=

WANG Xueqing (1997-), female, Master candidate. E-mail:

, correspAuthorsNote=
WANG Qinghu (1985-), male, Ph.D., Associate Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319236589990032316, articleId=1319236589524464570, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=Ca2+和Co2+摩尔比对共掺杂LaAlO3陶瓷红外辐射性能的影响, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

采用高温固相反应工艺制备n(Ca2+)/n(Co2+)(n为摩尔)共掺杂LaAlO3陶瓷,研究了n(Ca2+)/n(Co2+)掺杂比例对LaAlO3陶瓷[La1-xCaxAl0.8Co0.2O3,0.25≤n(Ca2+)/n(Co2+)≤2.00]红外辐射性能的影响,探讨了LaAlO3陶瓷发射率提高的机理。结果表明,n(Ca2+)/n(Co2+)共掺杂LaAlO3陶瓷具有钙钛矿结构。在0.76~2.50 μm波段,掺杂比例[0.25≤n(Ca2+)/n(Co2+)≤1.00]的增加有助于提升陶瓷的发射率,n(Ca2+)/n(Co2+)=1.00的陶瓷样品(La0.8Ca0.2Al0.8Co0.2O3)有最高的平均发射率(0.87);在2.50~14.0 μm波段,所有n(Ca2+)/n(Co2+)共掺杂LaAlO3陶瓷的平均发射率普遍高于0.94。发射率提高的原因为:n(Ca2+)/n(Co2+)共掺杂强化了自由载流子吸收、杂质能级吸收和晶格振动吸收。这种高发射红外陶瓷材料有望在热工装备的节能应用领域发挥作用。

, authors=王雪晴1, 王庆虎1, 梁雄1, 徐义彪1, 朱天彬1, 桑绍柏1, 李亚伟1, 陈义祥2, 李永2, 李江涛2, authorsList=王雪晴, 王庆虎, 梁雄, 徐义彪, 朱天彬, 桑绍柏, 李亚伟, 陈义祥, 李永, 李江涛, authorCompany=null, correspAuthors=王庆虎, authorNote=

王雪晴(1997—),女,硕士研究生。

, correspAuthorsNote=
王庆虎(1985—),男,副教授。
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Ca2+和Co2+摩尔比对共掺杂LaAlO3陶瓷红外辐射性能的影响
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王雪晴 1 , 王庆虎 1 , 梁雄 1 , 徐义彪 1 , 朱天彬 1 , 桑绍柏 1 , 李亚伟 1 , 陈义祥 2 , 李永 2 , 李江涛 2
硅酸盐学报 | 研究论文 2022,50(9): 2380-2387
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硅酸盐学报 |研究论文 2022 , 50 (9) : 2380 -2387
Ca2+和Co2+摩尔比对共掺杂LaAlO3陶瓷红外辐射性能的影响
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王雪晴1 , 王庆虎1 , 梁雄1, 徐义彪1, 朱天彬1, 桑绍柏1, 李亚伟1, 陈义祥2, 李永2, 李江涛2
作者信息
  • 1.武汉科技大学,省部共建耐火材料与冶金国家重点实验室,高温材料与炉衬技术国家地方联合工程研究中心,武汉 430081
  • 2.中国科学院理化技术研究所,北京 100190
通讯作者:
王庆虎(1985—),男,副教授。
作者简介:

王雪晴(1997—),女,硕士研究生。

Effect of Molar Ratio of Ca2+ and Co2+ on Infrared Radiation Properties of Co-doped LaAlO3 Ceramics
Xueqing WANG1 , Qinghu WANG1 , Xiong LIANG1, Yibiao XU1, Tianbin ZHU1, Shaobai SANG1, Yawei LI1, Yixiang CHEN2, Yong LI2, Jiangtao LI2
Affiliations
  • 1.Wuhan University of Science and Technology, The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, National-provincial Joint Engineering Research Center of High Temperature Materials and Lining Technology, Wuhan 430081, China
  • 2.Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • Corresponding Author:
    WANG Qinghu (1985-), male, Ph.D., Associate Professor. E-mail:

    WANG Xueqing (1997-), female, Master candidate. E-mail:

出版时间: 2022-09-20 doi: 10.14062/j.issn.0454-5648.20220016
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采用高温固相反应工艺制备n(Ca2+)/n(Co2+)(n为摩尔)共掺杂LaAlO3陶瓷,研究了n(Ca2+)/n(Co2+)掺杂比例对LaAlO3陶瓷[La1-xCaxAl0.8Co0.2O3,0.25≤n(Ca2+)/n(Co2+)≤2.00]红外辐射性能的影响,探讨了LaAlO3陶瓷发射率提高的机理。结果表明,n(Ca2+)/n(Co2+)共掺杂LaAlO3陶瓷具有钙钛矿结构。在0.76~2.50 μm波段,掺杂比例[0.25≤n(Ca2+)/n(Co2+)≤1.00]的增加有助于提升陶瓷的发射率,n(Ca2+)/n(Co2+)=1.00的陶瓷样品(La0.8Ca0.2Al0.8Co0.2O3)有最高的平均发射率(0.87);在2.50~14.0 μm波段,所有n(Ca2+)/n(Co2+)共掺杂LaAlO3陶瓷的平均发射率普遍高于0.94。发射率提高的原因为:n(Ca2+)/n(Co2+)共掺杂强化了自由载流子吸收、杂质能级吸收和晶格振动吸收。这种高发射红外陶瓷材料有望在热工装备的节能应用领域发挥作用。

铝酸镧陶瓷  /  钙钴共掺杂  /  红外辐射性能  /  发射率

n(Ca2+)/n(Co2+)(n is mole) co-doped LaAlO3 ceramics were synthesized by a solid-phase reaction technique. The effect of n(Ca2+)/nCo2+ doping ratio on the infrared radiation performance of LaAlO3 ceramics (La1-xCaxAl0.8Co0.2O3, 0.25≤n(Ca2+)/n(Co2+)≤2.00) was investigated, and the mechanism for improving infrared radiation property was analyzed. The result reveals that n(Ca2+)/n(Co2+) co-doped LaAlO3 ceramics have a perovskite crystal structure. Increasing the doping ratio (0.25≤n(Ca2+)/n(Co2+)≤1.00) improves the emissivity in the wavelength range of 0.76-2.50 μm. The ceramic specimen with n(Ca2+)/n(Co2+) of 1.00 (La0.8Ca0.2Al0.8Co0.2O3) has the maximum average emissivity (0.87). In the 2.50-14.0 μm band, the average emissivity of all n(Ca2+)/n(Co2+) co-doped LaAlO3 ceramics is generally greater than 0.94. The improvement of emissivity can be attributed to the enhancement of free carrier absorption, impurity absorption and lattice vibration absorption. This novel infrared ceramic with a high emissivity has promising prospects for energy-saving applications of thermal equipment.

lanthanum aluminate ceramics  /  calcium and cobalt co-doping  /  infrared radiation property  /  emissivity
王雪晴, 王庆虎, 梁雄, 徐义彪, 朱天彬, 桑绍柏, 李亚伟, 陈义祥, 李永, 李江涛. Ca2+和Co2+摩尔比对共掺杂LaAlO3陶瓷红外辐射性能的影响. 硅酸盐学报, 2022 , 50 (9) : 2380 -2387 . DOI: 10.14062/j.issn.0454-5648.20220016
Xueqing WANG, Qinghu WANG, Xiong LIANG, Yibiao XU, Tianbin ZHU, Shaobai SANG, Yawei LI, Yixiang CHEN, Yong LI, Jiangtao LI. Effect of Molar Ratio of Ca2+ and Co2+ on Infrared Radiation Properties of Co-doped LaAlO3 Ceramics[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (9) : 2380 -2387 . DOI: 10.14062/j.issn.0454-5648.20220016
  • 国家自然科学基金(U1904217; 52102028)
  • 国家重点研发计划(2019YFC1904903-02)
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doi: 10.14062/j.issn.0454-5648.20220016
  • 接收时间:2022-01-16
  • 首发时间:2026-10-20
  • 出版时间:2022-09-20
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  • 收稿日期:2022-01-16
  • 修回日期:2022-01-28
基金
国家自然科学基金(U1904217; 52102028)
国家重点研发计划(2019YFC1904903-02)
作者信息
    1.武汉科技大学,省部共建耐火材料与冶金国家重点实验室,高温材料与炉衬技术国家地方联合工程研究中心,武汉 430081
    2.中国科学院理化技术研究所,北京 100190

通讯作者:

王庆虎(1985—),男,副教授。
参考文献
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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