Article(id=1319986925272937273, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986924727677753, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20211160, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1640620800000, receivedDateStr=2021-12-28, revisedDate=1642521600000, revisedDateStr=2022-01-19, acceptedDate=null, acceptedDateStr=null, onlineDate=1792639007155, onlineDateStr=2026-10-22, pubDate=1650384000000, pubDateStr=2022-04-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792639007155, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792639007155, creator=13701087609, updateTime=1792639007155, updator=13701087609, issue=Issue{id=1319986924727677753, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='4', pageStart='877', pageEnd='1200', issueExtLink='null', onlineDate='null', pubDate='1650384000000', pubDateStr='2022-04-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792639007026, creator='13701087609', updateTime=1792639269665, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319988026600702366, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986924727677753, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319988026600702367, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986924727677753, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=919, endPage=928, ext={EN=ArticleExt(id=1319986925558149946, articleId=1319986925272937273, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Optical Properties of B2O3-ZnO-SiO2 Gradient Index Fluorescent Glass, columnId=1321891873954837352, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on United Nations International Year of Glass—Research Articles, runingTitle=null, highlight=null, articleAbstract=

Phosphor in glass (PiG) is widely used as a fluorescent conversion material for light emitting diode (LED) device packaging. However, for the PiG with a single refractive index (SRIN) structure, the optical loss is large when light transmits from air through PiG to the packaging material due to large refractive index difference between the interfaces. In addition, the sintering temperature of PiG is high, thus reducing the light conversion efficiency of phosphor. To address the problems above, lead-free B2O3-ZnO-SiO2 matrix glass with gradient refractive index structure matching with yellow phosphor was prepared. Also, B2O3-ZnO-SiO2 system fluorescent glass (phosphor in matrix glass with gradient refractive index structure) was prepared via multi-layer screen printing and low-temperature sintering process. The glass was used in LED packaging to improve the optical performance of LED devices.

, authors=Hong LI, Yi YUE, Peng WANG, Jie YANG, authorsList=Hong LI, Yi YUE, Peng WANG, Jie YANG, authorCompany=null, correspAuthors=null, authorNote=

LI Hong (1964-), female, Ph.D., Professor. E-mail:

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荧光玻璃(PiG)作为荧光转换材料广泛应用于发光二极管(LED)器件封装。然而,使用单一折射率结构的荧光玻璃与封装材料和空气界面间的折射率跨度大,光在界面间传递时会产生很大的损耗。另外,荧光玻璃的烧结温度普遍较高,会降低荧光粉的光转换效率。针对上述问题,制备出梯度折射率结构且能够和黄色荧光粉折射率相匹配的无铅硼锌硅基质玻璃;结合多层丝网印刷和低温烧结工艺,制备得到梯度折射率结构的B2O3-ZnO-SiO2系荧光玻璃,将其用于LED封装,可提高LED器件的光学性能。

, authors=李宏, 乐毅, 王鹏, 杨洁, authorsList=李宏, 乐毅, 王鹏, 杨洁, authorCompany=null, correspAuthors=null, authorNote=

李宏(1964—),女,博士,研究员。

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B2O3-ZnO-SiO2系梯度折射率荧光玻璃的制备及其光学性能
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李宏 , 乐毅 , 王鹏 , 杨洁
硅酸盐学报 | “联合国国际玻璃年”特刊—研究论文 2022,50(4): 919-928
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硅酸盐学报 |“联合国国际玻璃年”特刊—研究论文 2022 , 50 (4) : 919 -928
B2O3-ZnO-SiO2系梯度折射率荧光玻璃的制备及其光学性能
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李宏 , 乐毅, 王鹏, 杨洁
作者信息
  • 武汉理工大学,硅酸盐建筑材料国家重点实验室,武汉 430070
作者简介:

李宏(1964—),女,博士,研究员。

Preparation and Optical Properties of B2O3-ZnO-SiO2 Gradient Index Fluorescent Glass
Hong LI , Yi YUE, Peng WANG, Jie YANG
Affiliations
  • State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China
  • LI Hong (1964-), female, Ph.D., Professor. E-mail:

出版时间: 2022-04-20 doi: 10.14062/j.issn.0454-5648.20211160
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荧光玻璃(PiG)作为荧光转换材料广泛应用于发光二极管(LED)器件封装。然而,使用单一折射率结构的荧光玻璃与封装材料和空气界面间的折射率跨度大,光在界面间传递时会产生很大的损耗。另外,荧光玻璃的烧结温度普遍较高,会降低荧光粉的光转换效率。针对上述问题,制备出梯度折射率结构且能够和黄色荧光粉折射率相匹配的无铅硼锌硅基质玻璃;结合多层丝网印刷和低温烧结工艺,制备得到梯度折射率结构的B2O3-ZnO-SiO2系荧光玻璃,将其用于LED封装,可提高LED器件的光学性能。

荧光玻璃  /  多层丝网印刷  /  梯度折射率  /  低温共烧  /  光学性能

Phosphor in glass (PiG) is widely used as a fluorescent conversion material for light emitting diode (LED) device packaging. However, for the PiG with a single refractive index (SRIN) structure, the optical loss is large when light transmits from air through PiG to the packaging material due to large refractive index difference between the interfaces. In addition, the sintering temperature of PiG is high, thus reducing the light conversion efficiency of phosphor. To address the problems above, lead-free B2O3-ZnO-SiO2 matrix glass with gradient refractive index structure matching with yellow phosphor was prepared. Also, B2O3-ZnO-SiO2 system fluorescent glass (phosphor in matrix glass with gradient refractive index structure) was prepared via multi-layer screen printing and low-temperature sintering process. The glass was used in LED packaging to improve the optical performance of LED devices.

fluorescent glass  /  multi-layer screen printing  /  gradient refractive index  /  low temperature co-firing  /  optical properties
李宏, 乐毅, 王鹏, 杨洁. B2O3-ZnO-SiO2系梯度折射率荧光玻璃的制备及其光学性能. 硅酸盐学报, 2022 , 50 (4) : 919 -928 . DOI: 10.14062/j.issn.0454-5648.20211160
Hong LI, Yi YUE, Peng WANG, Jie YANG. Preparation and Optical Properties of B2O3-ZnO-SiO2 Gradient Index Fluorescent Glass[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (4) : 919 -928 . DOI: 10.14062/j.issn.0454-5648.20211160
  • 国家自然科学基金(51772224; 51372179)
  • 武汉理工大学材料科学与工程学院创新创业训练计划(CY202021)
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doi: 10.14062/j.issn.0454-5648.20211160
  • 接收时间:2021-12-28
  • 首发时间:2026-10-22
  • 出版时间:2022-04-20
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出版历史
  • 收稿日期:2021-12-28
  • 修回日期:2022-01-19
基金
国家自然科学基金(51772224; 51372179)
武汉理工大学材料科学与工程学院创新创业训练计划(CY202021)
作者信息
    武汉理工大学,硅酸盐建筑材料国家重点实验室,武汉 430070
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20211160
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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