Article(id=1319236576186577751, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236561179366013, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20211155, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1640707200000, receivedDateStr=2021-12-29, revisedDate=1647446400000, revisedDateStr=2022-03-17, acceptedDate=null, acceptedDateStr=null, onlineDate=1792460109993, onlineDateStr=2026-10-20, pubDate=1663603200000, pubDateStr=2022-09-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792460109993, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792460109993, creator=13701087609, updateTime=1792460109993, updator=13701087609, issue=Issue{id=1319236561179366013, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='9', pageStart='2351', pageEnd='2578', issueExtLink='null', onlineDate='null', pubDate='1663603200000', pubDateStr='2022-09-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792460106415, creator='13701087609', updateTime=1792460650608, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319238843744764843, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236561179366013, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319238843744764844, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319236561179366013, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2358, endPage=2365, ext={EN=ArticleExt(id=1319236576417264472, articleId=1319236576186577751, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Growth, Structure and Electrical Properties of Tantalum Pentoxide and Manganese Dioxide Co-Doped Potassium Sodium Niobate Based Piezoelectric Single Crystals Prepared by Seed-Free Solid-State Crystal Growth Method, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

The 99.7K_0.5Na_0.5(Nb_(1-x)Ta_x)O₃-0.3BaBiO₃ lead-free piezoelectric single crystals of tantalum pentoxide and manganese dioxide doped were prepared by a seed-free solid-state crystal growth method, and the effects of mono-doping and co-doping of Ta and Mn on the growth, structure and electrical properties of the crystals were investigated. The result shows that a proper amount of Ta and Mn co-doping is beneficial to the growth of the single crystal. The single crystal surface becomes more regular and compact, and the maximum size of the obtained crystal can reach 30.0 mm×9.2 mm×2.6 mm when 0.9% (mole fraction) Ta and 0.1% Mn are co-doped. When 0.1% Mn doping is fixed and the amount of Ta is changed, the single crystals with a greater amount of tantalum pentoxide doping have higher piezoelectric properties. When the co-doping amounts of Ta and Mn are 0.9% and 0.1%, the crystals have greater remanent polarization (i.e., P_r = 26.96 μC/cm²) and piezoelectric constant (i.e., d₃₃ = 227 pC/N), respectively.

, authors=Zhaowei ZHANG, Minhong JIANG, Lin LI, Huan LU, Wei WANG, Shuai CHENG, Guanghui RAO, authorsList=Zhaowei ZHANG, Minhong JIANG, Lin LI, Huan LU, Wei WANG, Shuai CHENG, Guanghui RAO, authorCompany=null, correspAuthors=Minhong JIANG, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319236576769586009, articleId=1319236576186577751, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=Ta、Mn共掺铌酸钾钠基压电单晶的无籽晶固相生长、结构和电学性能, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

采用无籽晶固相法制备Ta₂O₅、MnO₂掺杂的99.7K_0.5Na_0.5[Nb_（1-x）Ta_x]O₃-0.3BaBiO₃无铅压电单晶，研究了Ta、Mn单掺杂和共掺杂对晶体生长、结构和性能的影响。结果表明：适量Ta和Mn共掺杂有利于晶体生长，当加入0.9%（摩尔分数）Ta和0.1% Mn时，单晶表面更为规则和致密，所获晶体最大尺寸可达30.0 mm×9.2 mm×2.6 mm。当固定0.1% Mn掺杂并改变Ta的掺杂量时，Ta掺杂量较高的单晶具有相对高的压电性能；当Ta和Mn分别掺杂为0.9%和0.1%时，所得单晶具有较高的剩余极化强度P_r和压电常数d₃₃，分别为26.96 μC/cm²和227 pC/N。

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ZHANG Zhaowei (1996-), male, Master candidate. E-mail: zhaowei.maples@foxmail.com

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ZHANG Zhaowei (1996-), male, Master candidate. E-mail: zhaowei.maples@foxmail.com

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张钊伟（1996—），男，硕士研究生。

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