Article(id=1319986585886642537, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20211140, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1640361600000, receivedDateStr=2021-12-25, revisedDate=1643817600000, revisedDateStr=2022-02-03, acceptedDate=null, acceptedDateStr=null, onlineDate=1792638926239, onlineDateStr=2026-10-22, pubDate=1655654400000, pubDateStr=2022-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792638926239, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792638926239, creator=13701087609, updateTime=1792638926239, updator=13701087609, issue=Issue{id=1319986532933555119, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='6', pageStart='1455', pageEnd='1774', issueExtLink='null', onlineDate='null', pubDate='1655654400000', pubDateStr='2022-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792638913615, creator='13701087609', updateTime=1792639299444, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319988151507075566, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319988151507075567, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1634, endPage=1641, ext={EN=ArticleExt(id=1319986586083774826, articleId=1319986585886642537, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Thermal Properties of Na2SO4·10H2O/Na2HPO4·12H2O Composite Phase Transition Materials Supported by Porous Carbon Sponge, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

Carbon sponge can be used as a carrier for phase-change materials due to its advantages of low density, large pore volume, and high thermal conductivity. A carbon sponge with certain graphitization characteristics and a porosity of 96.30% was synthesized as a carrier with absorbent cotton and MgO as raw materials, and a composite phase-change material encapsulated by a porous carbon sponge was prepared with Na2SO4·10H2O/Na2HPO4·12H2O as a phase-change medium. The results show that the adsorption amount of carbon sponges prepared at 700, 800 ℃ and 900 ℃ to the phase-change materials is 60, 75 and 102 times greater than their weights, respectively. Also, the solid-liquid phase-change cycle performance of the carbon sponge-encapsulated materials prepared at different temperatures was discussed at 5-60 ℃. After 5 000 cycles, the latent heat of the phase-change material is still > 200 J·g-1, which is reduced by 13%, and the thermal conductivity increasing rate is > 50%. The composite phase-change material encapsulated by porous carbon sponge has promising application prospects in the field of solar energy storage.

, authors=Liang WANG1, Chang'an WANG1, 2, Xin LIU1, Shengnian TIE1, authorsList=Liang WANG, Chang'an WANG, Xin LIU, Shengnian TIE, authorCompany=null, correspAuthors=Shengnian TIE, authorNote=

WANG Liang (1998-), male, Master candidate. E-mail:

, correspAuthorsNote=
TIE Shengnian (1965-), male, Professor. E-mail:
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碳海绵具有低密度、大孔体积、高导热系数等优点,可作为相变材料的良好载体。采用脱脂棉及MgO为原料,合成了具有一定石墨化特性、孔隙率达到96.3%的碳海绵为载体,以Na2SO4·10H2O/Na2HPO4·12H2O为相变介质,制备出多孔碳海绵封装的复合相变材料。结果表明:在700、800 ℃和900 ℃制得的碳海绵对相变材料的吸附量分别达到了自身质量的60、75倍和102倍。同时探讨了在不同温度下制得碳海绵封装的材料在5~60 ℃之间固液相变循环性能,经5000次循环后,该相变材料的潜热仍在200 J·g-1以上,下降值均在13%以内,导热系数提升率均大于50%。该多孔碳海绵封装的复合相变材料在太阳能储能等领域具有很好的应用前景。

, authors=王亮1, 汪长安1, 2, 柳馨1, 铁生年1, authorsList=王亮, 汪长安, 柳馨, 铁生年, authorCompany=null, correspAuthors=铁生年, authorNote=

王亮(1998—),男,硕士研究生。

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铁生年(1965—),男,教授。
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多孔碳海绵封装Na2SO4·10H2O/Na2HPO4·12H2O复合相变材料及其热性能
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王亮 1 , 汪长安 1, 2 , 柳馨 1 , 铁生年 1
硅酸盐学报 | 研究论文 2022,50(6): 1634-1641
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硅酸盐学报 |研究论文 2022 , 50 (6) : 1634 -1641
多孔碳海绵封装Na2SO4·10H2O/Na2HPO4·12H2O复合相变材料及其热性能
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王亮1 , 汪长安1, 2, 柳馨1, 铁生年1
作者信息
  • 1.青海大学,新能源光伏产业研究中心,西宁 810016
  • 2.清华大学材料学院,北京 100084
通讯作者:
铁生年(1965—),男,教授。
作者简介:

王亮(1998—),男,硕士研究生。

Preparation and Thermal Properties of Na2SO4·10H2O/Na2HPO4·12H2O Composite Phase Transition Materials Supported by Porous Carbon Sponge
Liang WANG1 , Chang'an WANG1, 2, Xin LIU1, Shengnian TIE1
Affiliations
  • 1.New Energy Photovoltaic Industry Research Institute, Qinghai University, Xining 810016, China
  • 2.School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
  • Corresponding Author:
    TIE Shengnian (1965-), male, Professor. E-mail:

    WANG Liang (1998-), male, Master candidate. E-mail:

出版时间: 2022-06-20 doi: 10.14062/j.issn.0454-5648.20211140
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碳海绵具有低密度、大孔体积、高导热系数等优点,可作为相变材料的良好载体。采用脱脂棉及MgO为原料,合成了具有一定石墨化特性、孔隙率达到96.3%的碳海绵为载体,以Na2SO4·10H2O/Na2HPO4·12H2O为相变介质,制备出多孔碳海绵封装的复合相变材料。结果表明:在700、800 ℃和900 ℃制得的碳海绵对相变材料的吸附量分别达到了自身质量的60、75倍和102倍。同时探讨了在不同温度下制得碳海绵封装的材料在5~60 ℃之间固液相变循环性能,经5000次循环后,该相变材料的潜热仍在200 J·g-1以上,下降值均在13%以内,导热系数提升率均大于50%。该多孔碳海绵封装的复合相变材料在太阳能储能等领域具有很好的应用前景。

多孔碳海绵  /  封装  /  十水硫酸钠  /  十二水合磷酸氢二钠  /  复合相变材料  /  热性能

Carbon sponge can be used as a carrier for phase-change materials due to its advantages of low density, large pore volume, and high thermal conductivity. A carbon sponge with certain graphitization characteristics and a porosity of 96.30% was synthesized as a carrier with absorbent cotton and MgO as raw materials, and a composite phase-change material encapsulated by a porous carbon sponge was prepared with Na2SO4·10H2O/Na2HPO4·12H2O as a phase-change medium. The results show that the adsorption amount of carbon sponges prepared at 700, 800 ℃ and 900 ℃ to the phase-change materials is 60, 75 and 102 times greater than their weights, respectively. Also, the solid-liquid phase-change cycle performance of the carbon sponge-encapsulated materials prepared at different temperatures was discussed at 5-60 ℃. After 5 000 cycles, the latent heat of the phase-change material is still > 200 J·g-1, which is reduced by 13%, and the thermal conductivity increasing rate is > 50%. The composite phase-change material encapsulated by porous carbon sponge has promising application prospects in the field of solar energy storage.

porous carbon sponge  /  encapsulation  /  sodium sulfate decahydrate  /  disodium hydrogen phosphate dodecahydrate  /  composite phase change material  /  thermal performance
王亮, 汪长安, 柳馨, 铁生年. 多孔碳海绵封装Na2SO4·10H2O/Na2HPO4·12H2O复合相变材料及其热性能. 硅酸盐学报, 2022 , 50 (6) : 1634 -1641 . DOI: 10.14062/j.issn.0454-5648.20211140
Liang WANG, Chang'an WANG, Xin LIU, Shengnian TIE. Preparation and Thermal Properties of Na2SO4·10H2O/Na2HPO4·12H2O Composite Phase Transition Materials Supported by Porous Carbon Sponge[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (6) : 1634 -1641 . DOI: 10.14062/j.issn.0454-5648.20211140
  • 青海省自然基金(2020-ZJ-909; 2021-ZJ-906)
  • 材料复合新技术国家重点实验室(武汉理工大学)开放基金(2020-KF-1)
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2022年第50卷第6期
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doi: 10.14062/j.issn.0454-5648.20211140
  • 接收时间:2021-12-25
  • 首发时间:2026-10-22
  • 出版时间:2022-06-20
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  • 收稿日期:2021-12-25
  • 修回日期:2022-02-03
基金
青海省自然基金(2020-ZJ-909; 2021-ZJ-906)
材料复合新技术国家重点实验室(武汉理工大学)开放基金(2020-KF-1)
作者信息
    1.青海大学,新能源光伏产业研究中心,西宁 810016
    2.清华大学材料学院,北京 100084

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铁生年(1965—),男,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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