Article(id=1319232605313160162, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20211138, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1640275200000, receivedDateStr=2021-12-24, revisedDate=1642003200000, revisedDateStr=2022-01-13, acceptedDate=null, acceptedDateStr=null, onlineDate=1792459163262, onlineDateStr=2026-10-20, pubDate=1658246400000, pubDateStr=2022-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792459163262, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792459163262, creator=13701087609, updateTime=1792459163262, updator=13701087609, issue=Issue{id=1319232566922695375, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='7', pageStart='1775', pageEnd='2066', issueExtLink='null', onlineDate='null', pubDate='1658246400000', pubDateStr='2022-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792459154109, creator='13701087609', updateTime=1792460038980, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319236278420357264, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319236278420357265, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1883, endPage=1889, ext={EN=ArticleExt(id=1319232605598372835, articleId=1319232605313160162, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Electrochemical Properties of Polymer Electrolyte Reinforced by SiO2 Nanofibers, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

Composite polymer electrolyte is one of the most promising electrolyte candidates for future solid state lithium batteries, but inorganic fillers used are prone to an agglomeration, thus being difficult to form a continuous ion transport pathway. Flexible SiO2 nanofiber porous membranes were fabricated by an electrospinning technique and a heating treatment process. The samples were characterized by scanning electron microscope, fourier transform infrared spectrometer, X-ray diffractometer, and thermogravimetry analyzer. The effects of TEOS proportion and polymer concentration in electrospinning precursor on the morphology and flexibility of the nanofiber porous membranes were investigated. Moreover, the electrochemical properties of PEO based composite polymer electrolyte (CPE-SiO2) were analyzed. The ionic conductivity of this composite electrolyte can reach 2.52×10-5 S/cm at 30 ℃. LiFePO4|CPE-SiO2|Li can be steadily charged/discharged for 50 times at 1 C rate and 60 ℃. Li|CPE-SiO2|Li symmetric cell can keep a stable overpotential profile for 300 h with a low hysteresis at 60 ℃. This work provides an effective approach for the commercialization of next generation high-performance all-solid-state batteries.

, authors=Jiawei ZHONG1, Zhichuan SHEN1, Kun YANG1, Shiyong JIANG2, Shiying ZHAN3, Hailing HU3, Zhicong SHI1, authorsList=Jiawei ZHONG, Zhichuan SHEN, Kun YANG, Shiyong JIANG, Shiying ZHAN, Hailing HU, Zhicong SHI, authorCompany=null, correspAuthors=Zhicong SHI, authorNote=

ZHONG Jiawei (1996-), male, Master candidate. E-mail:

, correspAuthorsNote=
SHI Zhicong (1975-), male, Ph.D., Professor. E-mail:
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复合聚合物电解质是未来固态锂电池最重要的候选电解质之一,但其中无机填料易团聚,难以形成连续的离子传输通路。通过静电纺丝和高温热处理手段得到柔性SiO2纳米纤维多孔薄膜,采用扫描电子显微镜、Fourier变换红外光谱、X射线衍射和热重-微分热重法对样品进行了表征,系统研究了电纺前驱体溶液中正硅酸乙酯的占比和聚合物浓度对纳米纤维多孔薄膜形貌及柔性的影响。并以该多孔薄膜作为支撑体,制备了聚氧化乙烯(PEO)基复合聚合物电解质(CPE-SiO2)。对其电化学性能进行了测试,30 ℃时离子电导率达到2.52×10-5 S/cm,60 ℃时LiFePO4|CPE-SiO2|Li半电池可以在1 C倍率下充放电稳定循环50次,Li|CPE-SiO2|Li对称电池可在60 ℃下充放电稳定循环300 h,为下一代高性能全固态电池的商业化提供了一种行之有效的思路。

, authors=钟嘉炜1, 沈之川1, 杨坤1, 蒋世用2, 詹世英3, 胡海玲3, 施志聪1, authorsList=钟嘉炜, 沈之川, 杨坤, 蒋世用, 詹世英, 胡海玲, 施志聪, authorCompany=null, correspAuthors=施志聪, authorNote=

钟嘉炜(1996—),男,硕士研究生。

, correspAuthorsNote=
施志聪(1975—),男,博士,教授。
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SiO2纳米纤维增强聚合物电解质的电化学性能
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钟嘉炜 1 , 沈之川 1 , 杨坤 1 , 蒋世用 2 , 詹世英 3 , 胡海玲 3 , 施志聪 1
硅酸盐学报 | 研究论文 2022,50(7): 1883-1889
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硅酸盐学报 |研究论文 2022 , 50 (7) : 1883 -1889
SiO2纳米纤维增强聚合物电解质的电化学性能
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钟嘉炜1 , 沈之川1, 杨坤1, 蒋世用2, 詹世英3, 胡海玲3, 施志聪1
作者信息
  • 1.广东工业大学材料与能源学院,广州 510006
  • 2.重庆大学电气工程学院,重庆 400044
  • 3.格力钛新能源股份有限公司,珠海 519090
通讯作者:
施志聪(1975—),男,博士,教授。
作者简介:

钟嘉炜(1996—),男,硕士研究生。

Electrochemical Properties of Polymer Electrolyte Reinforced by SiO2 Nanofibers
Jiawei ZHONG1 , Zhichuan SHEN1, Kun YANG1, Shiyong JIANG2, Shiying ZHAN3, Hailing HU3, Zhicong SHI1
Affiliations
  • 1.Guangdong University of Technology, School of Materials and Energy, Guangzhou 510006, China
  • 2.Chongqing University, School of Electrical Engineering, Chongqing 400044, China
  • 3.Gree Altairnano New Energy Co., Ltd, Zhuhai 519090, China
  • Corresponding Author:
    SHI Zhicong (1975-), male, Ph.D., Professor. E-mail:

    ZHONG Jiawei (1996-), male, Master candidate. E-mail:

出版时间: 2022-07-20 doi: 10.14062/j.issn.0454-5648.20211138
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复合聚合物电解质是未来固态锂电池最重要的候选电解质之一,但其中无机填料易团聚,难以形成连续的离子传输通路。通过静电纺丝和高温热处理手段得到柔性SiO2纳米纤维多孔薄膜,采用扫描电子显微镜、Fourier变换红外光谱、X射线衍射和热重-微分热重法对样品进行了表征,系统研究了电纺前驱体溶液中正硅酸乙酯的占比和聚合物浓度对纳米纤维多孔薄膜形貌及柔性的影响。并以该多孔薄膜作为支撑体,制备了聚氧化乙烯(PEO)基复合聚合物电解质(CPE-SiO2)。对其电化学性能进行了测试,30 ℃时离子电导率达到2.52×10-5 S/cm,60 ℃时LiFePO4|CPE-SiO2|Li半电池可以在1 C倍率下充放电稳定循环50次,Li|CPE-SiO2|Li对称电池可在60 ℃下充放电稳定循环300 h,为下一代高性能全固态电池的商业化提供了一种行之有效的思路。

固态锂电池  /  纳米纤维多孔薄膜  /  二氧化硅  /  复合聚合物电解质  /  电化学性能

Composite polymer electrolyte is one of the most promising electrolyte candidates for future solid state lithium batteries, but inorganic fillers used are prone to an agglomeration, thus being difficult to form a continuous ion transport pathway. Flexible SiO2 nanofiber porous membranes were fabricated by an electrospinning technique and a heating treatment process. The samples were characterized by scanning electron microscope, fourier transform infrared spectrometer, X-ray diffractometer, and thermogravimetry analyzer. The effects of TEOS proportion and polymer concentration in electrospinning precursor on the morphology and flexibility of the nanofiber porous membranes were investigated. Moreover, the electrochemical properties of PEO based composite polymer electrolyte (CPE-SiO2) were analyzed. The ionic conductivity of this composite electrolyte can reach 2.52×10-5 S/cm at 30 ℃. LiFePO4|CPE-SiO2|Li can be steadily charged/discharged for 50 times at 1 C rate and 60 ℃. Li|CPE-SiO2|Li symmetric cell can keep a stable overpotential profile for 300 h with a low hysteresis at 60 ℃. This work provides an effective approach for the commercialization of next generation high-performance all-solid-state batteries.

solid state lithium batteries  /  nanofiber porous membranes  /  silicon dioxide  /  composite polymer electrolyte  /  electrochemical properties
钟嘉炜, 沈之川, 杨坤, 蒋世用, 詹世英, 胡海玲, 施志聪. SiO2纳米纤维增强聚合物电解质的电化学性能. 硅酸盐学报, 2022 , 50 (7) : 1883 -1889 . DOI: 10.14062/j.issn.0454-5648.20211138
Jiawei ZHONG, Zhichuan SHEN, Kun YANG, Shiyong JIANG, Shiying ZHAN, Hailing HU, Zhicong SHI. Electrochemical Properties of Polymer Electrolyte Reinforced by SiO2 Nanofibers[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (7) : 1883 -1889 . DOI: 10.14062/j.issn.0454-5648.20211138
  • 珠海市产学研合作项目(ZH22017001200059PWC)
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2022年第50卷第7期
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doi: 10.14062/j.issn.0454-5648.20211138
  • 接收时间:2021-12-24
  • 首发时间:2026-10-20
  • 出版时间:2022-07-20
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  • 收稿日期:2021-12-24
  • 修回日期:2022-01-13
基金
珠海市产学研合作项目(ZH22017001200059PWC)
作者信息
    1.广东工业大学材料与能源学院,广州 510006
    2.重庆大学电气工程学院,重庆 400044
    3.格力钛新能源股份有限公司,珠海 519090

通讯作者:

施志聪(1975—),男,博士,教授。
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2种不同金属材料的力学参数
科
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属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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