Article(id=1319232595267802025, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20211021, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1638028800000, receivedDateStr=2021-11-28, revisedDate=1640102400000, revisedDateStr=2021-12-22, acceptedDate=null, acceptedDateStr=null, onlineDate=1792459160867, onlineDateStr=2026-10-20, pubDate=1658246400000, pubDateStr=2022-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792459160867, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792459160867, creator=13701087609, updateTime=1792459160867, updator=13701087609, issue=Issue{id=1319232566922695375, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='7', pageStart='1775', pageEnd='2066', issueExtLink='null', onlineDate='null', pubDate='1658246400000', pubDateStr='2022-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792459154109, creator='13701087609', updateTime=1792460038980, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319236278420357264, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319236278420357265, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1838, endPage=1851, ext={EN=ArticleExt(id=1319232596291212202, articleId=1319232595267802025, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Functional Design of Hard Carbon and Its Application in Sodium-Ion Battery Anode, columnId=1321891832468976209, journalTitle=Journal of the Chinese Ceramic Society, columnName=New Carbon Materials—Review, runingTitle=null, highlight=null, articleAbstract=

Hard carbon (HC) materials are considered as promising anode materials for sodium-ion batteries (SIBs) due to their advantages of high capacity, low working potential, and low cost. The most important feature of HC materials is a rich microcrystalline structure that is conducive to the sorption and insertion/extraction of sodium ions, which in turn enables HC materials to exhibit a superior sodium ion storage performance. However, HC materials have some problems such as low initial Coulombic efficiency (ICE), insufficient long-cycle stability, and poor rate performance in the application. A functional design can be an effective strategy to improve these problems of HC. This review mainly summarized recent studies on the modification of HC anode for SIBs, and provided the related information on some typical optimization strategies and the latest research progress in the functional design of HC anodes. The advantages and disadvantages of functional design were also discussed, providing a theoretical basis and technical support for guiding the commercial application of HC anodes for SIBs.

, authors=Xin FENG1, Ying LI1, Mingquan LIU1, 2, Qiaojun LI1, Yang ZHAO1, Ying BAI1, Chuan WU1, 2, authorsList=Xin FENG, Ying LI, Mingquan LIU, Qiaojun LI, Yang ZHAO, Ying BAI, Chuan WU, authorCompany=null, correspAuthors=Ying BAI, Chuan WU, authorNote=

FENG Xin (1989-), male, Doctoral candidate. E-mail:

, correspAuthorsNote=
BAI Ying (1975-), female, Professor; E-mail:
WU Chuan (1974-), male, Professor.
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硬碳拥有容量高、工作电位低、成本低等优势,在钠离子电池负极中展现出潜在的应用前景。其最重要的特点是拥有丰富的微晶结构,这对钠离子的吸附及嵌入/脱出过程十分有益,使硬碳展现出优益的储钠性能。在实际应用中,硬碳存在首效低、稳定性不足以及倍率性能较差等问题,功能化设计是针对性改善硬碳上述缺陷的有效策略。结合目前硬碳功能化改性方面的研究工作,系统介绍了近年来关于硬碳负极在功能化设计方面的典型策略及最新研究进展,并探讨了功能化设计的优势与不足,为指导未来钠离子电池硬碳负极的商业化应用提供理论基础和技术支撑。

, authors=冯鑫1, 李莹1, 刘明权1, 2, 李巧君1, 赵洋1, 白莹1, 吴川1, 2, authorsList=冯鑫, 李莹, 刘明权, 李巧君, 赵洋, 白莹, 吴川, authorCompany=null, correspAuthors=白莹, 吴川, authorNote=

冯鑫(1989—),男,博士研究生。

, correspAuthorsNote=
白莹(1975—),女,教授。
吴川(1974—),男,教授。
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硬碳材料的功能化设计及其在钠离子电池负极中的应用
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冯鑫 1 , 李莹 1 , 刘明权 1, 2 , 李巧君 1 , 赵洋 1 , 白莹 1 , 吴川 1, 2
硅酸盐学报 | 新型炭材料专题—综合评述 2022,50(7): 1838-1851
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硅酸盐学报 |新型炭材料专题—综合评述 2022 , 50 (7) : 1838 -1851
硬碳材料的功能化设计及其在钠离子电池负极中的应用
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FENG Xin (1989-), male, Doctoral candidate. E-mail:

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冯鑫(1989—),男,博士研究生。

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冯鑫(1989—),男,博士研究生。

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冯鑫1 , 李莹1, 刘明权1, 2, 李巧君1, 赵洋1, 白莹1 , 吴川1, 2
作者信息
  • 1.北京理工大学材料学院 环境科学与工程北京市重点实验室 北京 100081
  • 2.北京理工大学长三角研究院,浙江 嘉兴 314019
通讯作者:
白莹(1975—),女,教授。
吴川(1974—),男,教授。
作者简介:

冯鑫(1989—),男,博士研究生。

Functional Design of Hard Carbon and Its Application in Sodium-Ion Battery Anode
Xin FENG1 , Ying LI1, Mingquan LIU1, 2, Qiaojun LI1, Yang ZHAO1, Ying BAI1 , Chuan WU1, 2
Affiliations
  • 1.School of Materials Science and Engineering, Beijing Key Laboratory of Environmental Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
  • 2.Yangtze Delta Region Academy of Beijing Institute of Technology, Jiaxing 314019, Zhejiang China
  • Corresponding Author:
    BAI Ying (1975-), female, Professor; E-mail:
    WU Chuan (1974-), male, Professor.

    FENG Xin (1989-), male, Doctoral candidate. E-mail:

出版时间: 2022-07-20 doi: 10.14062/j.issn.0454-5648.20211021
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硬碳拥有容量高、工作电位低、成本低等优势,在钠离子电池负极中展现出潜在的应用前景。其最重要的特点是拥有丰富的微晶结构,这对钠离子的吸附及嵌入/脱出过程十分有益,使硬碳展现出优益的储钠性能。在实际应用中,硬碳存在首效低、稳定性不足以及倍率性能较差等问题,功能化设计是针对性改善硬碳上述缺陷的有效策略。结合目前硬碳功能化改性方面的研究工作,系统介绍了近年来关于硬碳负极在功能化设计方面的典型策略及最新研究进展,并探讨了功能化设计的优势与不足,为指导未来钠离子电池硬碳负极的商业化应用提供理论基础和技术支撑。

硬碳  /  微晶结构  /  功能化设计  /  钠离子电池  /  负极材料

Hard carbon (HC) materials are considered as promising anode materials for sodium-ion batteries (SIBs) due to their advantages of high capacity, low working potential, and low cost. The most important feature of HC materials is a rich microcrystalline structure that is conducive to the sorption and insertion/extraction of sodium ions, which in turn enables HC materials to exhibit a superior sodium ion storage performance. However, HC materials have some problems such as low initial Coulombic efficiency (ICE), insufficient long-cycle stability, and poor rate performance in the application. A functional design can be an effective strategy to improve these problems of HC. This review mainly summarized recent studies on the modification of HC anode for SIBs, and provided the related information on some typical optimization strategies and the latest research progress in the functional design of HC anodes. The advantages and disadvantages of functional design were also discussed, providing a theoretical basis and technical support for guiding the commercial application of HC anodes for SIBs.

hard carbon  /  microcrystalline structure  /  functional design  /  sodium-ion batteries  /  anode materials
冯鑫, 李莹, 刘明权, 李巧君, 赵洋, 白莹, 吴川. 硬碳材料的功能化设计及其在钠离子电池负极中的应用. 硅酸盐学报, 2022 , 50 (7) : 1838 -1851 . DOI: 10.14062/j.issn.0454-5648.20211021
Xin FENG, Ying LI, Mingquan LIU, Qiaojun LI, Yang ZHAO, Ying BAI, Chuan WU. Functional Design of Hard Carbon and Its Application in Sodium-Ion Battery Anode[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (7) : 1838 -1851 . DOI: 10.14062/j.issn.0454-5648.20211021
  • 国家自然科学基金(21975026)
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doi: 10.14062/j.issn.0454-5648.20211021
  • 接收时间:2021-11-28
  • 首发时间:2026-10-20
  • 出版时间:2022-07-20
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  • 收稿日期:2021-11-28
  • 修回日期:2021-12-22
基金
国家自然科学基金(21975026)
作者信息
    1.北京理工大学材料学院 环境科学与工程北京市重点实验室 北京 100081
    2.北京理工大学长三角研究院,浙江 嘉兴 314019

通讯作者:

白莹(1975—),女,教授。
吴川(1974—),男,教授。
参考文献
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20211021
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Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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