Article(id=1319232621306036434, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20211015, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1637856000000, receivedDateStr=2021-11-26, revisedDate=1639670400000, revisedDateStr=2021-12-17, acceptedDate=null, acceptedDateStr=null, onlineDate=1792459167075, onlineDateStr=2026-10-20, pubDate=1658246400000, pubDateStr=2022-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792459167075, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792459167075, creator=13701087609, updateTime=1792459167075, updator=13701087609, issue=Issue{id=1319232566922695375, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='7', pageStart='1775', pageEnd='2066', issueExtLink='null', onlineDate='null', pubDate='1658246400000', pubDateStr='2022-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792459154109, creator='13701087609', updateTime=1792460038980, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319236278420357264, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319236278420357265, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1972, endPage=1977, ext={EN=ArticleExt(id=1319232622698545363, articleId=1319232621306036434, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Evolution and Formation Kinetics of Gehlenite Phase in Ordinary Sulfoaluminate Cement Clinker with Low Al₂O₃/SiO₂ Ratio, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

To reveal the mechanism of the inert gehlenite (C₂AS) phase in sulfoaluminate cement clinker at a low Al₂O₃/SiO₂ ratio, a series of clinkers were prepared at different calcination temperatures and holding time as well as a fixed Al₂O₃/SiO₂ ratio of 2. The evolution of C₂AS was investigated by X-ray diffraction combined with the Rietveld method and thermogravimetry-differential scanning calorimetry. The results show that C₂AS is produced by the reaction of CaO, SiO₂ and Al₂O₃ at 950-1 200 ℃. C₂AS is mainly produced by the reaction of CA and CaO decomposed from C₄A₃$ with the residual SiO₂ when the temperature exceeds 1 200 ℃. It is indicated that the kinetics of the C₂AS formation above 1 200 ℃ is mainly controlled by the diffusion of Ca²⁺, and the activation energy of the reaction is (305±20) kJ/mol. This study provides a a guidance for the use of low-grade bauxite in the calcination of sulfoaluminate cement clinker.

, authors=Qingchun YANG, Jiaming WU, Changqing HU, Teng NIU, Xiangyu HAN, Xueyan FENG, Zhengmao YE, authorsList=Qingchun YANG, Jiaming WU, Changqing HU, Teng NIU, Xiangyu HAN, Xueyan FENG, Zhengmao YE, authorCompany=null, correspAuthors=Jiaming WU, Zhengmao YE, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319232623097004244, articleId=1319232621306036434, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=低铝硅比条件下硫铝酸盐水泥熟料中钙铝黄长石相的演变及形成动力学, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

为揭示低铝硅比（质量比）条件下硫铝酸盐水泥熟料中低水化活性钙铝黄长石相（C₂AS）降低熟料质量的作用机制，固定铝硅质量比为2，通过改变煅烧温度及保温时间制备了一系列熟料。采用X射线衍射结合Rietveld方法和热重-差示扫描量热法，研究了C₂AS的演变过程。结果表明：950~1200 ℃范围内C₂AS主要由CaO、SiO₂以及Al₂O₃反应而来；当温度超过1200 ℃时，C₂AS主要由C₄A₃$分解出的CA及CaO与残留的SiO₂反应形成。反应动力学分析表明：超过1200 ℃时C₂AS的形成主要由Ca²⁺的扩散过程控制，其反应活化能为（305±20） kJ/mol。本研究为硫铝酸盐水泥熟料煅烧过程中低品位铝矾土的使用提供了理论指导。

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YANG Qingchun (1997-), male, Doctoral candidate. E-mail: yangqigchun@163.com

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杨庆春（1997—），男，博士研究生。

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杨庆春（1997—），男，博士研究生。

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