Article(id=1319986952582050808, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986924727677753, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20211013, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1637769600000, receivedDateStr=2021-11-25, revisedDate=1640275200000, revisedDateStr=2021-12-24, acceptedDate=null, acceptedDateStr=null, onlineDate=1792639013667, onlineDateStr=2026-10-22, pubDate=1650384000000, pubDateStr=2022-04-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792639013667, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792639013667, creator=13701087609, updateTime=1792639013667, updator=13701087609, issue=Issue{id=1319986924727677753, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='4', pageStart='877', pageEnd='1200', issueExtLink='null', onlineDate='null', pubDate='1650384000000', pubDateStr='2022-04-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792639007026, creator='13701087609', updateTime=1792639269665, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319988026600702366, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986924727677753, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319988026600702367, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986924727677753, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1182, endPage=1192, ext={EN=ArticleExt(id=1319986953399940089, articleId=1319986952582050808, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Research Progress on Glass Materials for Low-Temperature Co-Fired Ceramics, columnId=1321891933815943235, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on United Nations International Year of Glass—Review, runingTitle=null, highlight=null, articleAbstract=

The glass material of low-temperature co-fired ceramics (LTCC) has an important influence on the performance of the substrate. In this paper, the properties of the co-fired glass materials used in LTCC were introduced, the influences of component and preparation process on the material properties were summarized, and the existing mature systems were analyzed. The superior dielectric properties of CaO-B2O3-SiO2 glass-ceramic system are due to the presence of the massive crystal phases. However, the components and preparation process fluctuations have a great influence on the properties due to its sensitive sintering and crystallization behavior. The structure of PbO-B2O3-SiO2 glass/ceramic composite system is compact and the glass phase is not easy to crystallize. The material has a table properties and superior mechanical properties. However, its application in a high frequency field is restricted because of the massive leaded glass phases. The crystalline glass and ceramic filler composite can be used in La2O3-B2O3 glass/ceramic composite system for the performance and stability requirements. The sintering mechanism and performance adjustment laws of LTCC materials still need to be further investigated to support the expansion of existing systems and the development of new systems.

, authors=Yu CAO, Yun HAI, Baojing ZHU, Xianyin YIN, Bo XU, Bin HAN, Yanhang WANG, Chengkui ZU, authorsList=Yu CAO, Yun HAI, Baojing ZHU, Xianyin YIN, Bo XU, Bin HAN, Yanhang WANG, Chengkui ZU, authorCompany=null, correspAuthors=Chengkui ZU, authorNote=

CAO Yu (1997-), male, Master candidate. E-mail:

, correspAuthorsNote=
ZU Chengkui (1964-), male, Ph.D., Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319986955010552827, articleId=1319986952582050808, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=低温共烧陶瓷用玻璃材料研究进展, columnId=1321891934151487556, journalTitle=硅酸盐学报, columnName=“联合国国际玻璃年”特刊—综合评述, runingTitle=null, highlight=null, articleAbstract=

低温共烧陶瓷(LTCC)的玻璃材料对基板性能有重要影响。本文介绍了LTCC用玻璃材料的体系分类与性能特点,梳理了组分、工艺等对材料性能的影响规律,对现有较成熟体系进行了重点分析。CaO-B2O3-SiO2微晶玻璃体系基板含大量晶相,介电性能优异,但烧结析晶行为敏感,组分和工艺波动对性能影响较大。PbO-B2O3-SiO2玻璃/陶瓷复合体系结构致密,玻璃不易析晶,性能稳定,力学性能优异,但大量含铅玻璃相限制了其在高频领域的应用。La2O3-B2O3玻璃/陶瓷复合体系使用结晶型玻璃与陶瓷填料复合,结合了二者优点,兼顾了性能与稳定。LTCC材料的烧结机理与性能调节规律仍需深入研究,以支撑拓展已有体系,开发新体系。

, authors=曹禹, 海韵, 朱宝京, 殷先印, 徐博, 韩滨, 王衍行, 祖成奎, authorsList=曹禹, 海韵, 朱宝京, 殷先印, 徐博, 韩滨, 王衍行, 祖成奎, authorCompany=null, correspAuthors=祖成奎, authorNote=

曹禹(1997—),硕士研究生。

, correspAuthorsNote=
祖成奎(1964—),博士,教授。
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曹禹(1997—),硕士研究生。

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低温共烧陶瓷用玻璃材料研究进展
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曹禹 , 海韵 , 朱宝京 , 殷先印 , 徐博 , 韩滨 , 王衍行 , 祖成奎
硅酸盐学报 | “联合国国际玻璃年”特刊—综合评述 2022,50(4): 1182-1192
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硅酸盐学报 |“联合国国际玻璃年”特刊—综合评述 2022 , 50 (4) : 1182 -1192
低温共烧陶瓷用玻璃材料研究进展
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曹禹 , 海韵, 朱宝京, 殷先印, 徐博, 韩滨, 王衍行, 祖成奎
作者信息
  • 中国建筑材料科学研究总院有限公司,北京 100024
通讯作者:
祖成奎(1964—),博士,教授。
作者简介:

曹禹(1997—),硕士研究生。

Research Progress on Glass Materials for Low-Temperature Co-Fired Ceramics
Yu CAO , Yun HAI, Baojing ZHU, Xianyin YIN, Bo XU, Bin HAN, Yanhang WANG, Chengkui ZU
Affiliations
  • China Building Materials Academy, Beijing 100024, China
  • Corresponding Author:
    ZU Chengkui (1964-), male, Ph.D., Professor. E-mail:

    CAO Yu (1997-), male, Master candidate. E-mail:

出版时间: 2022-04-20 doi: 10.14062/j.issn.0454-5648.20211013
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低温共烧陶瓷(LTCC)的玻璃材料对基板性能有重要影响。本文介绍了LTCC用玻璃材料的体系分类与性能特点,梳理了组分、工艺等对材料性能的影响规律,对现有较成熟体系进行了重点分析。CaO-B2O3-SiO2微晶玻璃体系基板含大量晶相,介电性能优异,但烧结析晶行为敏感,组分和工艺波动对性能影响较大。PbO-B2O3-SiO2玻璃/陶瓷复合体系结构致密,玻璃不易析晶,性能稳定,力学性能优异,但大量含铅玻璃相限制了其在高频领域的应用。La2O3-B2O3玻璃/陶瓷复合体系使用结晶型玻璃与陶瓷填料复合,结合了二者优点,兼顾了性能与稳定。LTCC材料的烧结机理与性能调节规律仍需深入研究,以支撑拓展已有体系,开发新体系。

低温共烧陶瓷  /  微晶玻璃  /  复合材料  /  烧结

The glass material of low-temperature co-fired ceramics (LTCC) has an important influence on the performance of the substrate. In this paper, the properties of the co-fired glass materials used in LTCC were introduced, the influences of component and preparation process on the material properties were summarized, and the existing mature systems were analyzed. The superior dielectric properties of CaO-B2O3-SiO2 glass-ceramic system are due to the presence of the massive crystal phases. However, the components and preparation process fluctuations have a great influence on the properties due to its sensitive sintering and crystallization behavior. The structure of PbO-B2O3-SiO2 glass/ceramic composite system is compact and the glass phase is not easy to crystallize. The material has a table properties and superior mechanical properties. However, its application in a high frequency field is restricted because of the massive leaded glass phases. The crystalline glass and ceramic filler composite can be used in La2O3-B2O3 glass/ceramic composite system for the performance and stability requirements. The sintering mechanism and performance adjustment laws of LTCC materials still need to be further investigated to support the expansion of existing systems and the development of new systems.

low-temperature co-fired ceramics  /  glass-ceramic  /  composite  /  sintering
曹禹, 海韵, 朱宝京, 殷先印, 徐博, 韩滨, 王衍行, 祖成奎. 低温共烧陶瓷用玻璃材料研究进展. 硅酸盐学报, 2022 , 50 (4) : 1182 -1192 . DOI: 10.14062/j.issn.0454-5648.20211013
Yu CAO, Yun HAI, Baojing ZHU, Xianyin YIN, Bo XU, Bin HAN, Yanhang WANG, Chengkui ZU. Research Progress on Glass Materials for Low-Temperature Co-Fired Ceramics[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (4) : 1182 -1192 . DOI: 10.14062/j.issn.0454-5648.20211013

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doi: 10.14062/j.issn.0454-5648.20211013
  • 接收时间:2021-11-25
  • 首发时间:2026-10-22
  • 出版时间:2022-04-20
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  • 收稿日期:2021-11-25
  • 修回日期:2021-12-24
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    中国建筑材料科学研究总院有限公司,北京 100024

通讯作者:

祖成奎(1964—),博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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