Article(id=1319232623810039913, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210941, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1635955200000, receivedDateStr=2021-11-04, revisedDate=1640102400000, revisedDateStr=2021-12-22, acceptedDate=null, acceptedDateStr=null, onlineDate=1792459167672, onlineDateStr=2026-10-20, pubDate=1658246400000, pubDateStr=2022-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792459167672, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792459167672, creator=13701087609, updateTime=1792459167672, updator=13701087609, issue=Issue{id=1319232566922695375, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='7', pageStart='1775', pageEnd='2066', issueExtLink='null', onlineDate='null', pubDate='1658246400000', pubDateStr='2022-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792459154109, creator='13701087609', updateTime=1792460038980, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319236278420357264, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319236278420357265, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1994, endPage=2004, ext={EN=ArticleExt(id=1319232624015560810, articleId=1319232623810039913, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Synthesis and Mechanism of One-Dimensional SiC with Different Morphologies Catalyzed by Copper, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

To investigate the effect of CO gas partial pressure on the morphology and quantity of one-dimensional SiC catalyzed by copper, one-dimensional silicon carbide (SiC) with different morphologies was synthesized by a catalytic reaction method with silicon powder and phenolic resin as raw materials, and copper tartrate as a catalyst precursor. The samples were characterized by X-ray diffraction, field emission-scanning electron microscopy and transmission electron microscopy. The effects of catalyst, atmosphere and temperature on the morphology of SiC were investigated. The results indicate that the worm-like one-dimensional SiC is formed without a catalyst at 1 400 ℃. The Cu-catalyzed one-dimensional SiC with a chain-bead structure was synthesized under an argon atmosphere at 1 200 ℃, and the Cu-catalyzed one-dimensional SiC with a core-shell structures was synthesized under a CO atmosphere at 1 200 ℃. The growth mechanism of worm-like SiC is the reaction of gaseous phase CO and liquid phase Si to form a solid-phase SiC (i.e., V-L-S mechanism), and the growth mechanism of SiC with a chain-bead structure and a core-shell structure is the direct reaction of vapor phase SiO and CO to form solid-phase SiC (i.e., V-S mechanism). The results of this work can provide a theoretical basis for the in-situ formation of one-dimensional SiC ceramic reinforced phases with different morphologies in carbon-containing refractories.

, authors=Pengcheng JIANG, Zhoufu WANG, Hao LIU, Yan MA, Yunjie DONG, Yulong WANG, Jiwei NIU, Hongxing PANG, authorsList=Pengcheng JIANG, Zhoufu WANG, Hao LIU, Yan MA, Yunjie DONG, Yulong WANG, Jiwei NIU, Hongxing PANG, authorCompany=null, correspAuthors=Zhoufu WANG, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319232624309162091, articleId=1319232623810039913, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=铜催化合成不同形貌一维碳化硅及其机理, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

为了探究CO气体分压对Cu催化合成一维碳化硅（SiC）形貌和数量的影响，以酚醛树脂为碳源、单质硅粉为硅源、酒石酸铜为催化剂前驱体，采用催化反应合成法制备出不同形貌的一维SiC。利用X射线衍射、场发射扫描电子显微镜和透射电子显微镜对合成产物进行了表征分析，研究了催化剂、气氛和温度对合成一维SiC的影响。结果表明：酚醛树脂和硅粉在1400 ℃反应合成了蠕虫状的一维SiC。1200 ℃时，Cu催化酚醛树脂和硅粉分别在氩气气氛和CO气氛下合成了珠链结构和核壳结构的一维SiC。蠕虫状一维SiC的生长机理是气相CO与液相Si反应生成固相SiC的生长机制（V-L-S机制），珠链结构和核壳结构一维SiC的生长机理是气相SiO和CO直接反应生成固相SiC的生长机制（V-S机制）。研究结果为碳复合耐火材料中原位生成不同形貌一维SiC陶瓷增强相提供理论依据。

, authors=姜鹏程, 王周福, 刘浩, 马妍, 董云洁, 王玉龙, 牛记伟, 庞红星, authorsList=姜鹏程, 王周福, 刘浩, 马妍, 董云洁, 王玉龙, 牛记伟, 庞红星, authorCompany=null, correspAuthors=王周福, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=24t0IDKwjwy8qdnV8neWsg==, magXml=4aMz3TJM9n0QAtcR0vdk1A==, pdfUrl=null, pdf=GOC45cQ0mbh7roYNM65Rfg==, pdfFileSize=3855841, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=1Zt/OsGOpRF88LqH1UyTQQ==, mapNumber=null, fund=null)}, authors=[Author(id=1322507035611087165, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319232623810039913, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=wustjpc@163.com, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322507035699167551, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1319232623810039913, authorId=1322507035611087165, language=EN, stringName=Pengcheng JIANG, firstName=Pengcheng, middleName=null, lastName=JIANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=null, address=The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China, bio={"content":"

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JIANG Pengcheng (1993-), male, Doctorial candidate. E-mail: wustjpc@163.com

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姜鹏程（1993—），男，博士研究生。

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