Article(id=1319232633104613697, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210930, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1636300800000, receivedDateStr=2021-11-08, revisedDate=1640361600000, revisedDateStr=2021-12-25, acceptedDate=null, acceptedDateStr=null, onlineDate=1792459169888, onlineDateStr=2026-10-20, pubDate=1658246400000, pubDateStr=2022-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792459169888, onlineIssueDateStr=2026-10-20, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792459169888, creator=13701087609, updateTime=1792459169888, updator=13701087609, issue=Issue{id=1319232566922695375, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='7', pageStart='1775', pageEnd='2066', issueExtLink='null', onlineDate='null', pubDate='1658246400000', pubDateStr='2022-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792459154109, creator='13701087609', updateTime=1792460038980, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319236278420357264, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319236278420357265, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319232566922695375, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2015, endPage=2023, ext={EN=ArticleExt(id=1319232633301745986, articleId=1319232633104613697, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Progress on Low-Temperature Solid Oxide Fuel Cell with Composite Electrolyte, columnId=1263922772401635899, journalTitle=Journal of the Chinese Ceramic Society, columnName=Review, runingTitle=null, highlight=null, articleAbstract=

Reducing the operational temperature for high-temperature solid oxide fuel cell (SOFC) is of great significance to improve the stability of materials, increase the operation life of the system and reduce the fabrication and operation cost of the cell. This aspect has therefore attracted recent research attention. So far, different research strategies were proposed to reduce the operational temperature. This review represented recent research progress on the composite electrolyte in low-temperature solid oxide fuel cell (LT-SOFC). The carbonate materials as the second phase for composite preparation of molten carbonate-like SOFCs and the transition metal oxide materials as the second phase for composite preparation were introduced. The single-component fuel cell for eliminating the interface resistance between electrode and electrolyte and improving the fuel cell performance and the stability of the peroxide composite electrolyte was elaborated. The semiconductor composites to enhance LT-SOFC's electrochemical performance were described. In addition, this review also represented the preparation of novel nanocomposites to further enhance the electrolyte ionic conductivity and the interfacial compatibility, and the explorations of the electrochemical performance of LT-SOFC with respect to the effect of novel electrode materials.

, authors=Xiaoliang ZHOU, Jiaqi QIAN, Limin LIU, Xueyan CUI, Chunyu CHEN, Rongchen TU, Luomeng ZHAO, Hanwen SHEN, Yuxin WU, authorsList=Xiaoliang ZHOU, Jiaqi QIAN, Limin LIU, Xueyan CUI, Chunyu CHEN, Rongchen TU, Luomeng ZHAO, Hanwen SHEN, Yuxin WU, authorCompany=null, correspAuthors=null, authorNote=

ZHOU Xiaoliang (1978-), male, Ph.D., Professor. E-mail:

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高温固体氧化物燃料电池(SOFC)的低温化对于解决材料的稳定性、提高系统运行寿命和降低电池成本具有重要的意义,已成为近几年的研发热点。在实现SOFC低温化方面,目前国内外研究学者提出了不同的解决策略。综述了低温固体氧化物燃料电池(LT-SOFC)中复合电解质的研究进展,其包括引入碳酸盐材料作为第二相进行复合,构建类熔融碳酸盐固体氧化物燃料电池;引入过渡金属氧化物材料作为第二相进行复合,制备单组分燃料电池消除电极与电解质界面电阻提高电池性能,尤其是全氧化物复合电解质提高电池稳定性策略;引入半导体材料复合进一步提升LT-SOFC的电化学性能等几个方面。最后阐述了通过制备新型纳米复合材料进一步提升电解质离子电导率,改善界面接触问题以及探索新的电极材料对LT-SOFC电化学性能的影响。

, authors=周晓亮, 钱佳琪, 刘立敏, 崔学严, 陈春玉, 涂容陈, 赵罗蒙, 沈翰文, 吴雨欣, authorsList=周晓亮, 钱佳琪, 刘立敏, 崔学严, 陈春玉, 涂容陈, 赵罗蒙, 沈翰文, 吴雨欣, authorCompany=null, correspAuthors=null, authorNote=

周晓亮(1978—),男,博士,研究员。

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ZHOU Xiaoliang (1978-), male, Ph.D., Professor. E-mail:

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周晓亮(1978—),男,博士,研究员。

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周晓亮(1978—),男,博士,研究员。

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具有复合电解质的低温固体氧化物燃料电池研究进展
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周晓亮 , 钱佳琪 , 刘立敏 , 崔学严 , 陈春玉 , 涂容陈 , 赵罗蒙 , 沈翰文 , 吴雨欣
硅酸盐学报 | 综合评述 2022,50(7): 2015-2023
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硅酸盐学报 |综合评述 2022 , 50 (7) : 2015 -2023
具有复合电解质的低温固体氧化物燃料电池研究进展
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周晓亮(1978—),男,博士,研究员。

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周晓亮 , 钱佳琪, 刘立敏, 崔学严, 陈春玉, 涂容陈, 赵罗蒙, 沈翰文, 吴雨欣
作者信息
  • 西南石油大学化学化工学院,成都 610500
作者简介:

周晓亮(1978—),男,博士,研究员。

Progress on Low-Temperature Solid Oxide Fuel Cell with Composite Electrolyte
Xiaoliang ZHOU , Jiaqi QIAN, Limin LIU, Xueyan CUI, Chunyu CHEN, Rongchen TU, Luomeng ZHAO, Hanwen SHEN, Yuxin WU
Affiliations
  • College of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, China
  • ZHOU Xiaoliang (1978-), male, Ph.D., Professor. E-mail:

出版时间: 2022-07-20 doi: 10.14062/j.issn.0454-5648.20210930
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高温固体氧化物燃料电池(SOFC)的低温化对于解决材料的稳定性、提高系统运行寿命和降低电池成本具有重要的意义,已成为近几年的研发热点。在实现SOFC低温化方面,目前国内外研究学者提出了不同的解决策略。综述了低温固体氧化物燃料电池(LT-SOFC)中复合电解质的研究进展,其包括引入碳酸盐材料作为第二相进行复合,构建类熔融碳酸盐固体氧化物燃料电池;引入过渡金属氧化物材料作为第二相进行复合,制备单组分燃料电池消除电极与电解质界面电阻提高电池性能,尤其是全氧化物复合电解质提高电池稳定性策略;引入半导体材料复合进一步提升LT-SOFC的电化学性能等几个方面。最后阐述了通过制备新型纳米复合材料进一步提升电解质离子电导率,改善界面接触问题以及探索新的电极材料对LT-SOFC电化学性能的影响。

固体氧化物燃料电池  /  低温化  /  复合电解质  /  纳米材料

Reducing the operational temperature for high-temperature solid oxide fuel cell (SOFC) is of great significance to improve the stability of materials, increase the operation life of the system and reduce the fabrication and operation cost of the cell. This aspect has therefore attracted recent research attention. So far, different research strategies were proposed to reduce the operational temperature. This review represented recent research progress on the composite electrolyte in low-temperature solid oxide fuel cell (LT-SOFC). The carbonate materials as the second phase for composite preparation of molten carbonate-like SOFCs and the transition metal oxide materials as the second phase for composite preparation were introduced. The single-component fuel cell for eliminating the interface resistance between electrode and electrolyte and improving the fuel cell performance and the stability of the peroxide composite electrolyte was elaborated. The semiconductor composites to enhance LT-SOFC's electrochemical performance were described. In addition, this review also represented the preparation of novel nanocomposites to further enhance the electrolyte ionic conductivity and the interfacial compatibility, and the explorations of the electrochemical performance of LT-SOFC with respect to the effect of novel electrode materials.

solid oxide fuel cell  /  low temperature  /  composite electrolyte  /  nanomaterials
周晓亮, 钱佳琪, 刘立敏, 崔学严, 陈春玉, 涂容陈, 赵罗蒙, 沈翰文, 吴雨欣. 具有复合电解质的低温固体氧化物燃料电池研究进展. 硅酸盐学报, 2022 , 50 (7) : 2015 -2023 . DOI: 10.14062/j.issn.0454-5648.20210930
Xiaoliang ZHOU, Jiaqi QIAN, Limin LIU, Xueyan CUI, Chunyu CHEN, Rongchen TU, Luomeng ZHAO, Hanwen SHEN, Yuxin WU. Progress on Low-Temperature Solid Oxide Fuel Cell with Composite Electrolyte[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (7) : 2015 -2023 . DOI: 10.14062/j.issn.0454-5648.20210930
  • 国家自然科学基金(21875056; 22075231)
  • 四川省重点研发项目(省院省校科技合作)(2020YFSY0026; 2021YFSY0022)
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doi: 10.14062/j.issn.0454-5648.20210930
  • 接收时间:2021-11-08
  • 首发时间:2026-10-20
  • 出版时间:2022-07-20
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作者
出版历史
  • 收稿日期:2021-11-08
  • 修回日期:2021-12-25
基金
国家自然科学基金(21875056; 22075231)
四川省重点研发项目(省院省校科技合作)(2020YFSY0026; 2021YFSY0022)
作者信息
    西南石油大学化学化工学院,成都 610500
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20210930
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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