Article(id=1319987138947567901, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210759, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1630339200000, receivedDateStr=2021-08-31, revisedDate=1633276800000, revisedDateStr=2021-10-04, acceptedDate=null, acceptedDateStr=null, onlineDate=1792639058100, onlineDateStr=2026-10-22, pubDate=1642608000000, pubDateStr=2022-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792639058100, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792639058100, creator=13701087609, updateTime=1792639058100, updator=13701087609, issue=Issue{id=1319987091220574321, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='1', pageStart='1', pageEnd='276', issueExtLink='null', onlineDate='null', pubDate='1642608000000', pubDateStr='2022-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792639046721, creator='13701087609', updateTime=1792639238958, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319987897588105574, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319987897588105575, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=158, endPage=173, ext={EN=ArticleExt(id=1319987139266335006, articleId=1319987138947567901, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Recent Progress on Na3V2(PO4)2F3 Cathodes for Na-Ion Batteries, columnId=1321891336266035533, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Electrochemical Energy Storage Materials—Review, runingTitle=null, highlight=null, articleAbstract=

Sodium vanadium fluorophosphate (Na3V2(PO4)2F3) is considered as one of the most promising candidates for high-voltage Na-ion batteries cathodes due to the merits of high theoretical specific capacity, high energy density, high output voltage and rapid ion diffusion. However, the sluggish electron transfer kinetics and tremendous structural stress during repeated electrochemical processes restrict the further development and application. In this review, we presented recent progress on the development of Na3V2(PO4)2F3, i.e., the synthetic methods and modification strategies (micro-nano structure fabrication, carbon coating, element doping and battery composition optimization), and also gave the corresponding future outlook.

, authors=Chao ZHU1, Jian TU2, Yuanli DING1, authorsList=Chao ZHU, Jian TU, Yuanli DING, authorCompany=null, correspAuthors=Yuanli DING, authorNote=

ZHU Chao (1996-), male, Master, Research assistant. E-mail:

, correspAuthorsNote=
DING Yuanli (1981-), male, Ph.D., Professor. E-mail:
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氟磷酸钒钠[Na3V2(PO4)2F3]凭借其高理论比容量、高能量密度、高输出电压和快速离子扩散能力,被认为是最具发展前景的高电压型钠离子电池正极材料之一。然而,其缓慢的电子传输动力学和电化学反应过程中易遭受较大的结构应力等不足,严重制约了其进一步发展。基于此,从合成方法、修饰改性策略(微纳结构构建、碳包覆、元素掺杂、电池组分优化)等方面系统综述了Na3V2(PO4)2F3最新研究进展并对其未来发展作了展望。

, authors=朱超1, 涂健2, 丁元力1, authorsList=朱超, 涂健, 丁元力, authorCompany=null, correspAuthors=丁元力, authorNote=

朱超(1996—),男,硕士,助理研究员。

, correspAuthorsNote=
丁元力(1981—),男,博士,教授。
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ZHU Chao (1996-), male, Master, Research assistant. E-mail:

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钠离子电池正极材料氟磷酸钒钠的研究现状与展望
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朱超 1 , 涂健 2 , 丁元力 1
硅酸盐学报 | 电化学储能材料专题—综合评述 2022,50(1): 158-173
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硅酸盐学报 |电化学储能材料专题—综合评述 2022 , 50 (1) : 158 -173
钠离子电池正极材料氟磷酸钒钠的研究现状与展望
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朱超1 , 涂健2, 丁元力1
作者信息
  • 1.湖南大学材料科学与工程学院,长沙 410082
  • 2.湖南立方新能源科技有限责任公司,湖南 株洲 412007
通讯作者:
丁元力(1981—),男,博士,教授。
作者简介:

朱超(1996—),男,硕士,助理研究员。

Recent Progress on Na3V2(PO4)2F3 Cathodes for Na-Ion Batteries
Chao ZHU1 , Jian TU2, Yuanli DING1
Affiliations
  • 1.College of Materials Science and Engineering, Hunan University, Changsha 410082, China
  • 2.Li-FUN Technology Corporation Limited, Zhuzhou 412007, Hunan, China
  • Corresponding Author:
    DING Yuanli (1981-), male, Ph.D., Professor. E-mail:

    ZHU Chao (1996-), male, Master, Research assistant. E-mail:

出版时间: 2022-01-20 doi: 10.14062/j.issn.0454-5648.20210759
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氟磷酸钒钠[Na3V2(PO4)2F3]凭借其高理论比容量、高能量密度、高输出电压和快速离子扩散能力,被认为是最具发展前景的高电压型钠离子电池正极材料之一。然而,其缓慢的电子传输动力学和电化学反应过程中易遭受较大的结构应力等不足,严重制约了其进一步发展。基于此,从合成方法、修饰改性策略(微纳结构构建、碳包覆、元素掺杂、电池组分优化)等方面系统综述了Na3V2(PO4)2F3最新研究进展并对其未来发展作了展望。

氟磷酸钒钠  /  合成方法  /  微纳结构设计  /  碳包覆  /  元素掺杂  /  电池组分优化

Sodium vanadium fluorophosphate (Na3V2(PO4)2F3) is considered as one of the most promising candidates for high-voltage Na-ion batteries cathodes due to the merits of high theoretical specific capacity, high energy density, high output voltage and rapid ion diffusion. However, the sluggish electron transfer kinetics and tremendous structural stress during repeated electrochemical processes restrict the further development and application. In this review, we presented recent progress on the development of Na3V2(PO4)2F3, i.e., the synthetic methods and modification strategies (micro-nano structure fabrication, carbon coating, element doping and battery composition optimization), and also gave the corresponding future outlook.

sodium vanadium fluorophosphate  /  synthetic methods  /  micro-nano structures fabrication  /  carbon coating  /  element doping  /  battery composition optimization
朱超, 涂健, 丁元力. 钠离子电池正极材料氟磷酸钒钠的研究现状与展望. 硅酸盐学报, 2022 , 50 (1) : 158 -173 . DOI: 10.14062/j.issn.0454-5648.20210759
Chao ZHU, Jian TU, Yuanli DING. Recent Progress on Na3V2(PO4)2F3 Cathodes for Na-Ion Batteries[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (1) : 158 -173 . DOI: 10.14062/j.issn.0454-5648.20210759
  • 国家自然科学基金面上项目(52072119)
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doi: 10.14062/j.issn.0454-5648.20210759
  • 接收时间:2021-08-31
  • 首发时间:2026-10-22
  • 出版时间:2022-01-20
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  • 收稿日期:2021-08-31
  • 修回日期:2021-10-04
基金
国家自然科学基金面上项目(52072119)
作者信息
    1.湖南大学材料科学与工程学院,长沙 410082
    2.湖南立方新能源科技有限责任公司,湖南 株洲 412007

通讯作者:

丁元力(1981—),男,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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