Article(id=1319986613191561728, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210702, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1629302400000, receivedDateStr=2021-08-19, revisedDate=1634832000000, revisedDateStr=2021-10-22, acceptedDate=null, acceptedDateStr=null, onlineDate=1792638932750, onlineDateStr=2026-10-22, pubDate=1655654400000, pubDateStr=2022-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792638932750, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792638932750, creator=13701087609, updateTime=1792638932750, updator=13701087609, issue=Issue{id=1319986532933555119, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='6', pageStart='1455', pageEnd='1774', issueExtLink='null', onlineDate='null', pubDate='1655654400000', pubDateStr='2022-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792638913615, creator='13701087609', updateTime=1792639299444, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319988151507075566, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319988151507075567, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1669, endPage=1676, ext={EN=ArticleExt(id=1319986613405471233, articleId=1319986613191561728, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Photo-Fenton Catalytic Properties of High-Purity Hercynite, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

To develop novel environmental-friendly photo-Fenton catalysts, hercynite (FeAl2O4) was prepared via reaction sintering. The catalytic performance in photo-Fenton and the degradation of hercynite for rhodamine B dye was investigated. The results show that the phase composition in the samples is a high-purity hercynite with Fe2+ and Fe3+ complex valence states. The optimal degradation efficiency and TOC removal efficiency are 90.71% and 76.46%, respectively at pH value of 3.14, FeAl2O4 of 1.0 g/L and H2O2 of 2% (in volume fraction). After four cycles, hercynite still maintains a good stability. The synthesized hercynite as an optical photo-Fenton catalyst can be recycled and reused for times, The synthesized hercynite which has a potential application prospect in dye wastewater treatment.

, authors=Jiayu ZHANG1, 2, Mingwei YAN1, Guangchao SUN1, 2, Xiang LI1, 2, Kaiqi LIU1, 2, authorsList=Jiayu ZHANG, Mingwei YAN, Guangchao SUN, Xiang LI, Kaiqi LIU, authorCompany=null, correspAuthors=Kaiqi LIU, authorNote=

ZHANG Jiayu (1995-), female, Doctorial candidate. E-mail:

, correspAuthorsNote=
LIU Kaiqi (1969-), male, Professor. E-mail:
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为进一步开发新型环境友好型光芬顿催化剂,基于反应烧结法制备了铁铝尖晶石,探究了铁铝尖晶石对罗丹明B染料的光芬顿催化性能和降解机理。结果表明:试样中物相组成为具有Fe2+和Fe3+复合价态的高纯铁铝尖晶石。通过调整pH值、催化剂质量浓度和H2O2剂量,铁铝尖晶石催化罗丹明B呈现不同的降解效率。当工艺条件为pH=3.14、1.0 g/L FeAl2O4和2% H2O2时,降解效率达到90.71%,TOC去除率达76.46%。经过4次循环使用后,铁铝尖晶石仍然保持良好的稳定性。反应烧结法合成的铁铝尖晶石是一种具有潜在价值的光芬顿催化剂,在染料废水处理中具有应用前景。

, authors=张佳钰1, 2, 闫明伟1, 孙广超1, 2, 李想1, 2, 刘开琪1, 2, authorsList=张佳钰, 闫明伟, 孙广超, 李想, 刘开琪, authorCompany=null, correspAuthors=刘开琪, authorNote=

张佳钰(1995—),女,博士研究生。

, correspAuthorsNote=
刘开琪(1969—),男,博士,研究员。
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高纯铁铝尖晶石制备及其光芬顿催化性能
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张佳钰 1, 2 , 闫明伟 1 , 孙广超 1, 2 , 李想 1, 2 , 刘开琪 1, 2
硅酸盐学报 | 研究论文 2022,50(6): 1669-1676
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硅酸盐学报 |研究论文 2022 , 50 (6) : 1669 -1676
高纯铁铝尖晶石制备及其光芬顿催化性能
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ZHANG Jiayu (1995-), female, Doctorial candidate. E-mail:

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张佳钰(1995—),女,博士研究生。

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张佳钰1, 2 , 闫明伟1, 孙广超1, 2, 李想1, 2, 刘开琪1, 2
作者信息
  • 1.中国科学院过程工程研究所,多相复杂系统国家重点研究室,北京 100190
  • 2.中国科学院大学,北京 100086
通讯作者:
刘开琪(1969—),男,博士,研究员。
作者简介:

张佳钰(1995—),女,博士研究生。

Preparation and Photo-Fenton Catalytic Properties of High-Purity Hercynite
Jiayu ZHANG1, 2 , Mingwei YAN1, Guangchao SUN1, 2, Xiang LI1, 2, Kaiqi LIU1, 2
Affiliations
  • 1.State Key Laboratory of Multi-phase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
  • 2.University of Chinese Academy of Sciences, Beijing 100049, China
  • Corresponding Author:
    LIU Kaiqi (1969-), male, Professor. E-mail:

    ZHANG Jiayu (1995-), female, Doctorial candidate. E-mail:

出版时间: 2022-06-20 doi: 10.14062/j.issn.0454-5648.20210702
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为进一步开发新型环境友好型光芬顿催化剂,基于反应烧结法制备了铁铝尖晶石,探究了铁铝尖晶石对罗丹明B染料的光芬顿催化性能和降解机理。结果表明:试样中物相组成为具有Fe2+和Fe3+复合价态的高纯铁铝尖晶石。通过调整pH值、催化剂质量浓度和H2O2剂量,铁铝尖晶石催化罗丹明B呈现不同的降解效率。当工艺条件为pH=3.14、1.0 g/L FeAl2O4和2% H2O2时,降解效率达到90.71%,TOC去除率达76.46%。经过4次循环使用后,铁铝尖晶石仍然保持良好的稳定性。反应烧结法合成的铁铝尖晶石是一种具有潜在价值的光芬顿催化剂,在染料废水处理中具有应用前景。

铁铝尖晶石  /  光芬顿催化  /  反应烧结  /  染料降解

To develop novel environmental-friendly photo-Fenton catalysts, hercynite (FeAl2O4) was prepared via reaction sintering. The catalytic performance in photo-Fenton and the degradation of hercynite for rhodamine B dye was investigated. The results show that the phase composition in the samples is a high-purity hercynite with Fe2+ and Fe3+ complex valence states. The optimal degradation efficiency and TOC removal efficiency are 90.71% and 76.46%, respectively at pH value of 3.14, FeAl2O4 of 1.0 g/L and H2O2 of 2% (in volume fraction). After four cycles, hercynite still maintains a good stability. The synthesized hercynite as an optical photo-Fenton catalyst can be recycled and reused for times, The synthesized hercynite which has a potential application prospect in dye wastewater treatment.

hercynite  /  photo-Fenton  /  reaction sintering  /  dye degradation
张佳钰, 闫明伟, 孙广超, 李想, 刘开琪. 高纯铁铝尖晶石制备及其光芬顿催化性能. 硅酸盐学报, 2022 , 50 (6) : 1669 -1676 . DOI: 10.14062/j.issn.0454-5648.20210702
Jiayu ZHANG, Mingwei YAN, Guangchao SUN, Xiang LI, Kaiqi LIU. Preparation and Photo-Fenton Catalytic Properties of High-Purity Hercynite[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (6) : 1669 -1676 . DOI: 10.14062/j.issn.0454-5648.20210702
  • 国家自然科学基金(22005309)
  • 多相复杂系统国家重点实验室自主研究课题(MPCS-2021-C-01)
  • 中科南京绿色制造产业创新研究院关键研究项目(E0010717)
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2022年第50卷第6期
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doi: 10.14062/j.issn.0454-5648.20210702
  • 接收时间:2021-08-19
  • 首发时间:2026-10-22
  • 出版时间:2022-06-20
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出版历史
  • 收稿日期:2021-08-19
  • 修回日期:2021-10-22
基金
国家自然科学基金(22005309)
多相复杂系统国家重点实验室自主研究课题(MPCS-2021-C-01)
中科南京绿色制造产业创新研究院关键研究项目(E0010717)
作者信息
    1.中国科学院过程工程研究所,多相复杂系统国家重点研究室,北京 100190
    2.中国科学院大学,北京 100086

通讯作者:

刘开琪(1969—),男,博士,研究员。
参考文献
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2种不同金属材料的力学参数
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属数
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genus
种数
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species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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