Article(id=1319987106496229694, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210627, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1627833600000, receivedDateStr=2021-08-02, revisedDate=1632326400000, revisedDateStr=2021-09-23, acceptedDate=null, acceptedDateStr=null, onlineDate=1792639050363, onlineDateStr=2026-10-22, pubDate=1642608000000, pubDateStr=2022-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792639050363, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792639050363, creator=13701087609, updateTime=1792639050363, updator=13701087609, issue=Issue{id=1319987091220574321, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='1', pageStart='1', pageEnd='276', issueExtLink='null', onlineDate='null', pubDate='1642608000000', pubDateStr='2022-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792639046721, creator='13701087609', updateTime=1792639238958, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319987897588105574, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319987897588105575, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=148, endPage=157, ext={EN=ArticleExt(id=1319987106722722111, articleId=1319987106496229694, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Research Progress on Ordering Structure of Layered Oxide Cathode Materials for Sodium-Ion Batteries, columnId=1321891336266035533, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Electrochemical Energy Storage Materials—Review, runingTitle=null, highlight=null, articleAbstract=
Sodium-based layered oxides are a reasearch hotspot due to thier high specific capacity and high ionic conductivity. Different ordering superstructures in these materilas, including Na+/vacancy ordering in Na layer, charge ordering and transition metal ordering in transition metal layer, greatly affect the phase transition process, voltage profile and ion diffusion coefficient, etc.. The characteristics of three types of ordering superstructures were introduced, and the effects of ionic interaction, Fermi level and ionic radius on the ordering superstructures were also discussed. Meanwhile, this review summarized some work on the disordering structures and predicted the promising design directions to supress the ordering structures, for providing a guidance for the structural design of high-performance electrode materials.
, authors=Lu GAN
1, 2, Hurong YAO
1, 3, authorsList=Lu GAN, Hurong YAO, authorCompany=null, correspAuthors=Hurong YAO, authorNote=
, correspAuthorsNote=
YAO Hurong (1988-), female, Ph.D., Associate Professor. E-mail:
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钠基层状过渡金属氧化物正极材料具有比容量大,离子电导率高等优势,成为了电极材料研究热点之一。这类材料中存在的各类有序结构(钠层内的钠离子有序,电荷有序,过渡金属层内的离子有序)对材料的结构相变、电压平台、钠离子扩散系数等均会产生影响。详细介绍了层状氧化物中3种有序结构的特征,讨论了离子间相互作用、Fermi能级和离子半径对有序结构的影响,同时总结了结构的无序化研究,并展望了有无序结构的发展方向,旨在对高性能电极材料的结构设计提供指导。
, authors=甘露
1, 2, 姚胡蓉
1, 3, authorsList=甘露, 姚胡蓉, authorCompany=null, correspAuthors=姚胡蓉, authorNote=
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姚胡蓉(1988—),女,博士,副教授。
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甘露(1996—),女,硕士研究生。
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甘露(1996—),女,硕士研究生。
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