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Article(id=1319987126767308978, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210572, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1626710400000, receivedDateStr=2021-07-20, revisedDate=1628611200000, revisedDateStr=2021-08-11, acceptedDate=null, acceptedDateStr=null, onlineDate=1792639055196, onlineDateStr=2026-10-22, pubDate=1642608000000, pubDateStr=2022-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792639055196, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792639055196, creator=13701087609, updateTime=1792639055196, updator=13701087609, issue=Issue{id=1319987091220574321, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='1', pageStart='1', pageEnd='276', issueExtLink='null', onlineDate='null', pubDate='1642608000000', pubDateStr='2022-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792639046721, creator='13701087609', updateTime=1792639238958, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319987897588105574, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319987897588105575, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=9, endPage=15, ext={EN=ArticleExt(id=1319987127031550131, articleId=1319987126767308978, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Lithium/Sodium Storage of Sulfur Doped V2O3/C Nanowires, columnId=1321891465115062324, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Electrochemical Energy Storage Materials—Research Articles, runingTitle=null, highlight=null, articleAbstract=

To solve the problems of low electrical conductivity and poor stability of V2O3 as an anode electrode of secondary batteries, sulfur (S) doped V2O3/C nanowires were prepared via electrostatic spinning and sulfuration treatment technology. The structure, chemical composition, and energy storage properties were characterized. The results show that the S doped V2O3/C nanowire as an anode electrode for lithium ion batteries has a discharge specific capacity of 538 mA·h/g at a current density of 0.1 A/g after 50 cycles, and the discharge specific capacity at 2 A/g after 600 cycles can still maintain 288 mA·h/g. The specific capacity of sodium ion batteries with S-doped V2O3/C nanofiber as an anode electrode is 233 mA·h/g at 0.1 A/g after 100 cycles.

, authors=Zhixin RAO1, Zhi CHEN1, Danni LIANG1, Zhijun FENG1, Huiyong YANG1, Xibao LI1, Tong XIANG1, Shanzhi FENG1, Juntong HUANG1, Ming ZHANG2, authorsList=Zhixin RAO, Zhi CHEN, Danni LIANG, Zhijun FENG, Huiyong YANG, Xibao LI, Tong XIANG, Shanzhi FENG, Juntong HUANG, Ming ZHANG, authorCompany=null, correspAuthors=Zhi CHEN, Juntong HUANG, authorNote=

RAO Zhixin (1995-), male, Master candidate. E-mail:

, correspAuthorsNote=
CHEN Zhi (1990-), male, Lecturer; E-mail: (CHEN Zhi)
HUANG Juntong (1983-), male, Professor. (HUANG Juntong)
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319987127299985589, articleId=1319987126767308978, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=硫掺杂V2O3/C纳米纤维的制备及其储锂/钠性能, columnId=1321891465291223093, journalTitle=硅酸盐学报, columnName=电化学储能材料专题—研究论文, runingTitle=null, highlight=null, articleAbstract=

针对V2O3作为二次电池负极存在电导率低、稳定性差等问题，提出了采用静电纺丝并结合硫化处理技术制备了硫（S）掺杂的V2O3/C纳米纤维以提高其储能性能，并对其结构特征、化学组成、储能特性进行了系统表征。结果表明：在作为锂离子电池负极时，S掺杂的V2O3/C纳米纤维电极在0.1 A/g的电流密度下经过50个循环具有538 mA·h/g的放电比容量，且在2 A/g的电流密度下在第600个循环的放电比容量仍能维持288 mA·h/g。作为钠离子电池负极，S掺杂的V2O3/C纳米纤维电极在0.1 A/g的电流密度下经过100个循环比容量还具有233 mA·h/g。

, authors=饶志欣1, 陈智1, 梁丹妮1, 冯志军1, 杨会永1, 李喜宝1, 向彤1, 冯善志1, 黄军同1, 张明2, authorsList=饶志欣, 陈智, 梁丹妮, 冯志军, 杨会永, 李喜宝, 向彤, 冯善志, 黄军同, 张明, authorCompany=null, correspAuthors=陈智, 黄军同, authorNote=

饶志欣（1995—），男，硕士研究生。

, correspAuthorsNote=
陈智（1990—），男，博士，讲师；
黄军同（1983—），男，博士，教授。
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RAO Zhixin (1995-), male, Master candidate. E-mail:

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饶志欣（1995—），男，硕士研究生。

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饶志欣（1995—），男，硕士研究生。

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硫掺杂V2O3/C纳米纤维的制备及其储锂/钠性能
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饶志欣 1 , 陈智 1 , 梁丹妮 1 , 冯志军 1 , 杨会永 1 , 李喜宝 1 , 向彤 1 , 冯善志 1 , 黄军同 1 , 张明 2
硅酸盐学报 | 电化学储能材料专题—研究论文 2022,50(1): 9-15
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硅酸盐学报 |电化学储能材料专题—研究论文 2022 , 50 (1) : 9 -15
硫掺杂V2O3/C纳米纤维的制备及其储锂/钠性能
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饶志欣1 , 陈智1 , 梁丹妮1, 冯志军1, 杨会永1, 李喜宝1, 向彤1, 冯善志1, 黄军同1 , 张明2
作者信息
  • 1．南昌航空大学材料科学与工程学院，南昌 330063
  • 2．湖南大学物理与微电子科学学院，长沙 410082
通讯作者:
陈智（1990—），男，博士，讲师；
黄军同（1983—），男，博士，教授。
作者简介:

饶志欣（1995—），男，硕士研究生。

Preparation and Lithium/Sodium Storage of Sulfur Doped V2O3/C Nanowires
Zhixin RAO1 , Zhi CHEN1 , Danni LIANG1, Zhijun FENG1, Huiyong YANG1, Xibao LI1, Tong XIANG1, Shanzhi FENG1, Juntong HUANG1 , Ming ZHANG2
Affiliations
  • 1.School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China
  • 2.School of Physics and Electronics, Hunan University, Changsha 410082, China
    • Corresponding Author:
    CHEN Zhi (1990-), male, Lecturer; E-mail: (CHEN Zhi)
    HUANG Juntong (1983-), male, Professor. (HUANG Juntong)

    RAO Zhixin (1995-), male, Master candidate. E-mail:

出版时间: 2022-01-20 doi: 10.14062/j.issn.0454-5648.20210572
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针对V2O3作为二次电池负极存在电导率低、稳定性差等问题，提出了采用静电纺丝并结合硫化处理技术制备了硫（S）掺杂的V2O3/C纳米纤维以提高其储能性能，并对其结构特征、化学组成、储能特性进行了系统表征。结果表明：在作为锂离子电池负极时，S掺杂的V2O3/C纳米纤维电极在0.1 A/g的电流密度下经过50个循环具有538 mA·h/g的放电比容量，且在2 A/g的电流密度下在第600个循环的放电比容量仍能维持288 mA·h/g。作为钠离子电池负极，S掺杂的V2O3/C纳米纤维电极在0.1 A/g的电流密度下经过100个循环比容量还具有233 mA·h/g。

三氧化二钒  /  硫掺杂  /  静电纺丝  /  锂离子电池  /  钠离子电池

To solve the problems of low electrical conductivity and poor stability of V2O3 as an anode electrode of secondary batteries, sulfur (S) doped V2O3/C nanowires were prepared via electrostatic spinning and sulfuration treatment technology. The structure, chemical composition, and energy storage properties were characterized. The results show that the S doped V2O3/C nanowire as an anode electrode for lithium ion batteries has a discharge specific capacity of 538 mA·h/g at a current density of 0.1 A/g after 50 cycles, and the discharge specific capacity at 2 A/g after 600 cycles can still maintain 288 mA·h/g. The specific capacity of sodium ion batteries with S-doped V2O3/C nanofiber as an anode electrode is 233 mA·h/g at 0.1 A/g after 100 cycles.

vanadium trioxide  /  sulfur doped  /  electrospinning  /  lithium ion battery  /  sodium ion battery
饶志欣, 陈智, 梁丹妮, 冯志军, 杨会永, 李喜宝, 向彤, 冯善志, 黄军同, 张明. 硫掺杂V2O3/C纳米纤维的制备及其储锂/钠性能. 硅酸盐学报, 2022 , 50 (1) : 9 -15 . DOI: 10.14062/j.issn.0454-5648.20210572
Zhixin RAO, Zhi CHEN, Danni LIANG, Zhijun FENG, Huiyong YANG, Xibao LI, Tong XIANG, Shanzhi FENG, Juntong HUANG, Ming ZHANG. Preparation and Lithium/Sodium Storage of Sulfur Doped V2O3/C Nanowires[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (1) : 9 -15 . DOI: 10.14062/j.issn.0454-5648.20210572
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  • 国家自然科学基金地区基金项目(51862024)
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doi: 10.14062/j.issn.0454-5648.20210572
  • 接收时间：2021-07-20
  • 首发时间：2026-10-22
  • 出版时间：2022-01-20
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  • 收稿日期：2021-07-20
  • 修回日期：2021-08-11
基金
国家自然科学基金地区基金项目(51862024)
作者信息
    1．南昌航空大学材料科学与工程学院，南昌 330063
    2．湖南大学物理与微电子科学学院，长沙 410082

通讯作者:

陈智（1990—），男，博士，讲师；
黄军同（1983—），男，博士，教授。
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20210572
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
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