Article(id=1319986893811470610, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986871980118160, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210537, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1625155200000, receivedDateStr=2021-07-02, revisedDate=1629820800000, revisedDateStr=2021-08-25, acceptedDate=null, acceptedDateStr=null, onlineDate=1792638999654, onlineDateStr=2026-10-22, pubDate=1652976000000, pubDateStr=2022-05-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792638999654, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792638999654, creator=13701087609, updateTime=1792638999654, updator=13701087609, issue=Issue{id=1319986871980118160, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='5', pageStart='1201', pageEnd='1454', issueExtLink='null', onlineDate='null', pubDate='1652976000000', pubDateStr='2022-05-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792638994450, creator='13701087609', updateTime=1792639285419, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319988092451275233, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986871980118160, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319988092451275234, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986871980118160, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1257, endPage=1262, ext={EN=ArticleExt(id=1319986894025380115, articleId=1319986893811470610, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation of Cu₂ZnSnS₄ Thin Films Solar Cells Based on Magnetron Sputtering, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

In order to solve a problem of Sn-loss and reduce the thickness of MoS₂ during the sulfurization process, the oxygen containing Cu-Zn-Sn precursor thin films were prepared on Mo-coated soda lime glasses via magnetron sputtering ZnO/SnO₂/Cu. The results show that the Sn-loss and the formation of MoS₂ are well inhibited by the utilization of SnO₂ and ZnO. The single-phase CZTS absorbed thin films with the smooth surface, dense grains and good crystal structure can be prepared at 590 ℃. Also, the CZTS solar cells from oxygen containing precursors annealed at 590 ℃ have an optimum power conversion efficiency (PCE) of 5.12% with an open circuit voltage of 590 mV, a short circuit current density of 22.09 mA/cm² and a fill factor of 39.28%.

, authors=Xinyu LI, Daoyong ZHANG, Xiang LI, Qiulian LI, Xin LIU, Shurong WANG, authorsList=Xinyu LI, Daoyong ZHANG, Xiang LI, Qiulian LI, Xin LIU, Shurong WANG, authorCompany=null, correspAuthors=Shurong WANG, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319986894449004820, articleId=1319986893811470610, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=磁控溅射制备Cu₂ZnSnS₄薄膜太阳电池, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

为解决硫化过程中Sn元素损失的问题以及减少MoS₂的厚度，采用磁控溅射技术，在基于钼的钠钙玻璃衬底上采用双周期溅射的方法，以ZnO/SnO₂/Cu的顺序制备了含氧的Cu-Zn-Sn预制层。结果表明：SnO₂以及ZnO的使用很好的抑制了Sn元素的损失以及MoS₂层的形成，而且在590 ℃的硫化温度下能制备出表面平整、晶粒致密、晶体结构较好的单相Cu₂ZnSnS₄（CZTS）吸收层薄膜。最后，制备出结构完整的CZTS薄膜太阳电池，在590 ℃硫化制备的CZTS薄膜太阳电池效率最高，其开路电压为590 mV，短路电流密度为22.09 mA/cm²，填充因子为39.28%，光电转换效率达到5.12%，为今后制备高效CZTS薄膜太阳电池起到了推动作用。

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LI Xinyu (1995-), fermale, Master candidate. E-mail: Lixinyu@aliyun.com

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李新毓（1995—），女，硕士研究生。

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李新毓（1995—），女，硕士研究生。

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