Article(id=1322943160116196250, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322943149844345666, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210290, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1618761600000, receivedDateStr=2021-04-19, revisedDate=1625068800000, revisedDateStr=2021-07-01, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343828467, onlineDateStr=2026-10-30, pubDate=1639929600000, pubDateStr=2021-12-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343828467, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343828467, creator=13701087609, updateTime=1793343828467, updator=13701087609, issue=Issue{id=1322943149844345666, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='12', pageStart='2549', pageEnd='2816', issueExtLink='null', onlineDate='null', pubDate='1639929600000', pubDateStr='2021-12-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343826018, creator='13701087609', updateTime=1793345974749, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322952162350859029, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322943149844345666, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322952162350859030, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322943149844345666, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2710, endPage=2716, ext={EN=ArticleExt(id=1322943160346882971, articleId=1322943160116196250, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effects of Composition on Crystallization and Properties of Cordierite Glass-Ceramics, columnId=1319726165087077079, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Article, runingTitle=null, highlight=null, articleAbstract=

According to MgO-A12O3-SiO2 ternary system phase diagram, 22 kinds of compositions were designed by using triangular rule, and cordierite was synthesized by melting sintering method. The crystal evolution and phase transition of cordierite glass-ceramics was studied by means of differential thermal analysis, X-ray diffraction and scanning electron microscope. The apparent porosity and thermal expansion properties were tested. The results show that there are two kinds of exothermic peaks in the differential thermal curve with the change of composition. Near the theoretical composition, a double crystallization exothermic peak occurs, and MgAl2Si3O10 and α-cordierite crystal phase is precipitated. The thermal expansion coefficient of cordierite under the theoretical composition is the lowest, which is 1.27×10-6/℃. However, when the MgO content in the composition increases to more than 16.6%, the exothermic peak of crystallization is unimodal, and only α-cordierite crystal phase is precipitated under the single peak. At this time, the apparent porosity of cordierite sample is on the decrease significantly, with a minimum value of 0.32%.

, authors=Yanzhao ZHAO1, Cuiyue YANG1, Yunpeng HE1, Zhiming HU2, Hao HU1, Hairong YIN1, authorsList=Yanzhao ZHAO, Cuiyue YANG, Yunpeng HE, Zhiming HU, Hao HU, Hairong YIN, authorCompany=null, correspAuthors=null, authorNote=

ZHAO Yanzhao(1964-), male, Ph.D., Professor. E-mail:

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根据MgO-A12O3-SiO2三元系统相图,利用三角型规则设计出22种组成,并用熔融烧结法合成堇青石。采用差热分析、X射线衍射分析及扫描电子显微镜研究了堇青石微晶玻璃的析晶和晶相转变过程,并对其显气孔率以及热膨胀性能进行测试。结果表明:随着组成变化,差热曲线出现2种类型的晶化放热峰。在理论组成附近,为双晶化放热峰,析出MgAl2Si3O10和α-堇青石晶相,且理论组成下的堇青石热膨胀系数最低,为1.27×10-6/℃;而当组成中MgO的含量增加到16.6%以上时,晶化放热峰为单峰,单峰下析出α-堇青石晶相,此时堇青石样品显气孔率显著降低,最低为0.32%。

, authors=赵彦钊1, 杨崔月1, 贺云鹏1, 胡智敏2, 呼浩1, 殷海荣1, authorsList=赵彦钊, 杨崔月, 贺云鹏, 胡智敏, 呼浩, 殷海荣, authorCompany=null, correspAuthors=null, authorNote=

赵彦钊(1964—),男,博士,教授。

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ZHAO Yanzhao(1964-), male, Ph.D., Professor. E-mail:

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赵彦钊(1964—),男,博士,教授。

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赵彦钊(1964—),男,博士,教授。

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组成对堇青石微晶玻璃析晶和性能的影响
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赵彦钊 1 , 杨崔月 1 , 贺云鹏 1 , 胡智敏 2 , 呼浩 1 , 殷海荣 1
硅酸盐学报 | 研究论文 2021,49(12): 2710-2716
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硅酸盐学报 |研究论文 2021 , 49 (12) : 2710 -2716
组成对堇青石微晶玻璃析晶和性能的影响
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赵彦钊1 , 杨崔月1, 贺云鹏1, 胡智敏2, 呼浩1, 殷海荣1
作者信息
  • 1.陕西科技大学材料科学与工程学院,西安 710021
  • 2.大禾陶瓷原料有限公司,四川 威远 642450
作者简介:

赵彦钊(1964—),男,博士,教授。

Effects of Composition on Crystallization and Properties of Cordierite Glass-Ceramics
Yanzhao ZHAO1 , Cuiyue YANG1, Yunpeng HE1, Zhiming HU2, Hao HU1, Hairong YIN1
Affiliations
  • 1.School of Materials Science & Engineering, Shaanxi University of Science & Technology, Xi'an, 710021, China
  • 2.Dahe Ceramic Materials Co., Ltd., Weiyuan 642450, Sichuan, China
  • ZHAO Yanzhao(1964-), male, Ph.D., Professor. E-mail:

出版时间: 2021-12-20 doi: 10.14062/j.issn.0454-5648.20210290
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根据MgO-A12O3-SiO2三元系统相图,利用三角型规则设计出22种组成,并用熔融烧结法合成堇青石。采用差热分析、X射线衍射分析及扫描电子显微镜研究了堇青石微晶玻璃的析晶和晶相转变过程,并对其显气孔率以及热膨胀性能进行测试。结果表明:随着组成变化,差热曲线出现2种类型的晶化放热峰。在理论组成附近,为双晶化放热峰,析出MgAl2Si3O10和α-堇青石晶相,且理论组成下的堇青石热膨胀系数最低,为1.27×10-6/℃;而当组成中MgO的含量增加到16.6%以上时,晶化放热峰为单峰,单峰下析出α-堇青石晶相,此时堇青石样品显气孔率显著降低,最低为0.32%。

堇青石  /  微晶玻璃  /  组成  /  晶相转变

According to MgO-A12O3-SiO2 ternary system phase diagram, 22 kinds of compositions were designed by using triangular rule, and cordierite was synthesized by melting sintering method. The crystal evolution and phase transition of cordierite glass-ceramics was studied by means of differential thermal analysis, X-ray diffraction and scanning electron microscope. The apparent porosity and thermal expansion properties were tested. The results show that there are two kinds of exothermic peaks in the differential thermal curve with the change of composition. Near the theoretical composition, a double crystallization exothermic peak occurs, and MgAl2Si3O10 and α-cordierite crystal phase is precipitated. The thermal expansion coefficient of cordierite under the theoretical composition is the lowest, which is 1.27×10-6/℃. However, when the MgO content in the composition increases to more than 16.6%, the exothermic peak of crystallization is unimodal, and only α-cordierite crystal phase is precipitated under the single peak. At this time, the apparent porosity of cordierite sample is on the decrease significantly, with a minimum value of 0.32%.

cordierite  /  glass-ceramics  /  composition  /  crystal phase transition
赵彦钊, 杨崔月, 贺云鹏, 胡智敏, 呼浩, 殷海荣. 组成对堇青石微晶玻璃析晶和性能的影响. 硅酸盐学报, 2021 , 49 (12) : 2710 -2716 . DOI: 10.14062/j.issn.0454-5648.20210290
Yanzhao ZHAO, Cuiyue YANG, Yunpeng HE, Zhiming HU, Hao HU, Hairong YIN. Effects of Composition on Crystallization and Properties of Cordierite Glass-Ceramics[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (12) : 2710 -2716 . DOI: 10.14062/j.issn.0454-5648.20210290
  • 国家自然科学基金重点项目(51472151)
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doi: 10.14062/j.issn.0454-5648.20210290
  • 接收时间:2021-04-19
  • 首发时间:2026-10-30
  • 出版时间:2021-12-20
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  • 收稿日期:2021-04-19
  • 修回日期:2021-07-01
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国家自然科学基金重点项目(51472151)
作者信息
    1.陕西科技大学材料科学与工程学院,西安 710021
    2.大禾陶瓷原料有限公司,四川 威远 642450
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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