Article(id=1322944276992230083, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942849381183980, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210092, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1612454400000, receivedDateStr=2021-02-05, revisedDate=1616774400000, revisedDateStr=2021-03-27, acceptedDate=null, acceptedDateStr=null, onlineDate=1793344094750, onlineDateStr=2026-10-30, pubDate=1634659200000, pubDateStr=2021-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793344094750, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793344094750, creator=13701087609, updateTime=1793344094750, updator=13701087609, issue=Issue{id=1322942849381183980, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='10', pageStart='2045', pageEnd='2312', issueExtLink='null', onlineDate='null', pubDate='1634659200000', pubDateStr='2021-10-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343754382, creator='13701087609', updateTime=1793345931656, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951981580562527, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942849381183980, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951981584756832, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942849381183980, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2123, endPage=2129, ext={EN=ArticleExt(id=1322944277160002244, articleId=1322944276992230083, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Performance of Silicon Nanoparticles Composite Anode Material Based on Surface Modification, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Si/C@graphene(GR)/graphite(G) composite anode materials were prepared by a simple and easy-to-operate wet coating method with silicon nanoparticles and graphite as main raw materials, fatty alcohol polyoxyethylene ether as a surfactant and graphene. The effect of allocation ratio on the composition, morphology and electrochemical performance of the composite materials was investigated. The results show that the prepared composite materials exhibit a superior cycling stability, and the volume expansion alleviates. When the silicon nanoparticles content is 10%, the initial discharge capacity is approximately 730 mA·h/g. After 100 cycles at a current density of 100 mA/g, the discharge capacity can stably maintain at 500 mA·h/g. The initial coulomb efficiency reaches 87.27%, revealing a great improvement in comparison with the efficiency of pure silicon material (i.e., less than 70%).

, authors=Wei ZHANG1, Xujia XIE2, Jiamin YE1, Xi KE1, Zhicong SHI1, authorsList=Wei ZHANG, Xujia XIE, Jiamin YE, Xi KE, Zhicong SHI, authorCompany=null, correspAuthors=Zhicong SHI, authorNote=

ZHANG Wei (1996-), female, Master candidate. E-mail:

, correspAuthorsNote=
SHI Zhicong (1975-), male, Ph.D., Professor. E-mail:
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基于简单易操作的湿法包覆制备了以纳米硅粉体和石墨(G)为主要原料,添加表面活性剂脂肪醇聚氧乙烯醚和石墨烯(GR)的Si/C@GR/G复合材料。研究了不同组分配比对复合材料的成分、形貌及电化学性能的影响。结果表明:制得的复合材料具有良好的循环稳定性,体积膨胀得到缓解。当复合材料中硅质量分数为10%,首次放电比容量约为730 mA·h/g,在电流密度为100 mA/g经100次循环后,其放电比容量稳定维持在500 mA·h/g左右,也展现了良好的倍率性能,首次Coulombic效率达到87.27%,相比纯硅不足70%的效率有了大幅度提高。

, authors=张炜1, 谢旭佳2, 叶嘉敏1, 柯曦1, 施志聪1, authorsList=张炜, 谢旭佳, 叶嘉敏, 柯曦, 施志聪, authorCompany=null, correspAuthors=施志聪, authorNote=

张炜(1996—),女,硕士研究生。

, correspAuthorsNote=
施志聪(1975—),男,博士,教授。
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基于表面改性纳米硅复合负极材料的制备及其性能
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张炜 1 , 谢旭佳 2 , 叶嘉敏 1 , 柯曦 1 , 施志聪 1
硅酸盐学报 | 2021,49(10): 2123-2129
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硅酸盐学报 | 2021 , 49 (10) : 2123 -2129
基于表面改性纳米硅复合负极材料的制备及其性能
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张炜1 , 谢旭佳2, 叶嘉敏1, 柯曦1, 施志聪1
作者信息
  • 1.广东工业大学材料与能源学院,广州 510006
  • 2.汕头比亚迪电子有限公司,广东 汕头 515073
通讯作者:
施志聪(1975—),男,博士,教授。
作者简介:

张炜(1996—),女,硕士研究生。

Preparation and Performance of Silicon Nanoparticles Composite Anode Material Based on Surface Modification
Wei ZHANG1 , Xujia XIE2, Jiamin YE1, Xi KE1, Zhicong SHI1
Affiliations
  • 1.School of Materials and Energy, Guangdong University of Technology, Guangzhou 510006, China
  • 2.Shantou Byd Electronics Co., Ltd., Shantou 515073, Guangdong, China
  • Corresponding Author:
    SHI Zhicong (1975-), male, Ph.D., Professor. E-mail:

    ZHANG Wei (1996-), female, Master candidate. E-mail:

出版时间: 2021-10-20 doi: 10.14062/j.issn.0454-5648.20210092
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基于简单易操作的湿法包覆制备了以纳米硅粉体和石墨(G)为主要原料,添加表面活性剂脂肪醇聚氧乙烯醚和石墨烯(GR)的Si/C@GR/G复合材料。研究了不同组分配比对复合材料的成分、形貌及电化学性能的影响。结果表明:制得的复合材料具有良好的循环稳定性,体积膨胀得到缓解。当复合材料中硅质量分数为10%,首次放电比容量约为730 mA·h/g,在电流密度为100 mA/g经100次循环后,其放电比容量稳定维持在500 mA·h/g左右,也展现了良好的倍率性能,首次Coulombic效率达到87.27%,相比纯硅不足70%的效率有了大幅度提高。

锂离子电池  /  硅-碳  /  复合负极  /  表面改性  /  湿法包覆

Si/C@graphene(GR)/graphite(G) composite anode materials were prepared by a simple and easy-to-operate wet coating method with silicon nanoparticles and graphite as main raw materials, fatty alcohol polyoxyethylene ether as a surfactant and graphene. The effect of allocation ratio on the composition, morphology and electrochemical performance of the composite materials was investigated. The results show that the prepared composite materials exhibit a superior cycling stability, and the volume expansion alleviates. When the silicon nanoparticles content is 10%, the initial discharge capacity is approximately 730 mA·h/g. After 100 cycles at a current density of 100 mA/g, the discharge capacity can stably maintain at 500 mA·h/g. The initial coulomb efficiency reaches 87.27%, revealing a great improvement in comparison with the efficiency of pure silicon material (i.e., less than 70%).

lithium-ion battery  /  silicon-carbon  /  composite anode material  /  surface modification  /  wet coating method
张炜, 谢旭佳, 叶嘉敏, 柯曦, 施志聪. 基于表面改性纳米硅复合负极材料的制备及其性能. 硅酸盐学报, 2021 , 49 (10) : 2123 -2129 . DOI: 10.14062/j.issn.0454-5648.20210092
Wei ZHANG, Xujia XIE, Jiamin YE, Xi KE, Zhicong SHI. Preparation and Performance of Silicon Nanoparticles Composite Anode Material Based on Surface Modification[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (10) : 2123 -2129 . DOI: 10.14062/j.issn.0454-5648.20210092
  • 国家自然科学基金面上项目(21673051)
  • 广东省科技厅国际合作项目(2019A050510043)
  • 广东省科技厅产学研重大专项(2017B010119003)
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2021年第49卷第10期
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doi: 10.14062/j.issn.0454-5648.20210092
  • 接收时间:2021-02-05
  • 首发时间:2026-10-30
  • 出版时间:2021-10-20
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  • 收稿日期:2021-02-05
  • 修回日期:2021-03-27
基金
国家自然科学基金面上项目(21673051)
广东省科技厅国际合作项目(2019A050510043)
广东省科技厅产学研重大专项(2017B010119003)
作者信息
    1.广东工业大学材料与能源学院,广州 510006
    2.汕头比亚迪电子有限公司,广东 汕头 515073

通讯作者:

施志聪(1975—),男,博士,教授。
参考文献
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20210092
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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