Article(id=1322943165224858570, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322943149844345666, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210053, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1610899200000, receivedDateStr=2021-01-18, revisedDate=1618243200000, revisedDateStr=2021-04-13, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343829684, onlineDateStr=2026-10-30, pubDate=1639929600000, pubDateStr=2021-12-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343829684, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343829684, creator=13701087609, updateTime=1793343829684, updator=13701087609, issue=Issue{id=1322943149844345666, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='12', pageStart='2549', pageEnd='2816', issueExtLink='null', onlineDate='null', pubDate='1639929600000', pubDateStr='2021-12-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343826018, creator='13701087609', updateTime=1793345974749, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322952162350859029, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322943149844345666, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322952162350859030, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322943149844345666, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2751, endPage=2759, ext={EN=ArticleExt(id=1322943167229735884, articleId=1322943165224858570, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Influence of Glass Ceramic Coating on Alkali Resistance of Lightweight Mullite-SiC Composites, columnId=1319726165087077079, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Article, runingTitle=null, highlight=null, articleAbstract=

Three kinds of mullite-SiC materials were prepared with homogenized bauxite aggregate, porous mullite aggregate and glass ceramic coated porous mullite aggregate, respectively. The physical properties of the mullite-SiC materials sintered at 1 500℃ were investigated. The structure and properties of the materials after alkali vapor attack at 1 000℃ were analyzed. The influence of glass ceramic coating on the alkali vapor attack resistance of material was revealed by thermodynamics analysis. The results show that the strength of the lightweight mullite-SiC material is similar to that of the conventional mullite-SiC materials. However, the lightweight mullite-SiC material has a poor alkali vapor attack resistance. A liquid phase formed in glass ceramic coating at a high temperature promotes sintering, leading to a stronger bonding between aggregates and matrix and an increase in the strength for coated lightweight mullite-SiC materials. Moreover, the glass ceramic coating can absorb a part of K vapor and generate a liquid phase, thus protecting the porous aggregate from alkali vapor. The alkali vapor attack resistance of the lightweight mullite-SiC material is better than that of the conventional mullite-silicon carbide material.

, authors=Yan LIU, Shaobai SANG, Qi WU, Yuzhou MA, Yawei LI, Tianbin ZHU, authorsList=Yan LIU, Shaobai SANG, Qi WU, Yuzhou MA, Yawei LI, Tianbin ZHU, authorCompany=null, correspAuthors=Shaobai SANG, authorNote=

LIU Yan (1995-), female, Master candidate. E-mail:

, correspAuthorsNote=
SANG Shaobai (1979-), male, Ph.D., Porfessor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322943167699497933, articleId=1322943165224858570, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=玻璃陶瓷涂层对轻量莫来石-碳化硅材料抗碱侵蚀性能的影响, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

分别以均化矾土、多孔莫来石和涂覆玻璃陶瓷涂层的多孔莫来石作为骨料制备3种不同的莫来石-碳化硅材料,研究了莫来石-碳化硅材料1 500℃热处理后常温物理性能及1 000℃模拟钾蒸气侵蚀条件下的结构与性能变化,并借助热力学分析了玻璃陶瓷涂层影响材料抗碱侵蚀性能的机制。结果表明:相比于以均化矾土为骨料制备的传统莫来石-碳化硅材料,通过直接引入多孔莫来石骨料方式得到的轻量莫来石-碳化硅材料耐压强度变化不大,但其抗碱侵蚀性能明显下降;当多孔莫来石骨料表面涂覆玻璃陶瓷涂层后,玻璃陶瓷涂层在高温下形成的液相促进材料烧结,使骨料与基质结合更为紧密,所制得的具有玻璃陶瓷涂层的轻量莫来石-碳化硅材料强度明显增加;并且玻璃陶瓷涂层可以吸收部分钾蒸气并产生液相,进一步保护多孔莫来石骨料免受碱侵蚀,从而使具有玻璃陶瓷涂层的轻量莫来石-碳化硅材料的抗碱侵蚀性能优于传统莫来石-碳化硅材料。

, authors=刘燕, 桑绍柏, 武奇, 马宇洲, 李亚伟, 朱天彬, authorsList=刘燕, 桑绍柏, 武奇, 马宇洲, 李亚伟, 朱天彬, authorCompany=null, correspAuthors=桑绍柏, authorNote=

刘燕(1995—),女,硕士研究生。

, correspAuthorsNote=
桑绍柏(1979—),男,博士,教授。
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玻璃陶瓷涂层对轻量莫来石-碳化硅材料抗碱侵蚀性能的影响
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刘燕 , 桑绍柏 , 武奇 , 马宇洲 , 李亚伟 , 朱天彬
硅酸盐学报 | 研究论文 2021,49(12): 2751-2759
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硅酸盐学报 |研究论文 2021 , 49 (12) : 2751 -2759
玻璃陶瓷涂层对轻量莫来石-碳化硅材料抗碱侵蚀性能的影响
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刘燕 , 桑绍柏 , 武奇, 马宇洲, 李亚伟, 朱天彬
作者信息
  • 武汉科技大学,省部共建耐火材料与冶金国家重点实验室,高温材料与炉衬技术国家地方联合工程研究中心,武汉 430081
通讯作者:
桑绍柏(1979—),男,博士,教授。
作者简介:

刘燕(1995—),女,硕士研究生。

Influence of Glass Ceramic Coating on Alkali Resistance of Lightweight Mullite-SiC Composites
Yan LIU , Shaobai SANG , Qi WU, Yuzhou MA, Yawei LI, Tianbin ZHU
Affiliations
  • Wuhan University of Science and Technology, The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, National-provincial Joint Engineering Research Center of High Temperature Materials and Lining Technology, Wuhan 430081, China
  • Corresponding Author:
    SANG Shaobai (1979-), male, Ph.D., Porfessor. E-mail:

    LIU Yan (1995-), female, Master candidate. E-mail:

出版时间: 2021-12-20 doi: 10.14062/j.issn.0454-5648.20210053
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分别以均化矾土、多孔莫来石和涂覆玻璃陶瓷涂层的多孔莫来石作为骨料制备3种不同的莫来石-碳化硅材料,研究了莫来石-碳化硅材料1 500℃热处理后常温物理性能及1 000℃模拟钾蒸气侵蚀条件下的结构与性能变化,并借助热力学分析了玻璃陶瓷涂层影响材料抗碱侵蚀性能的机制。结果表明:相比于以均化矾土为骨料制备的传统莫来石-碳化硅材料,通过直接引入多孔莫来石骨料方式得到的轻量莫来石-碳化硅材料耐压强度变化不大,但其抗碱侵蚀性能明显下降;当多孔莫来石骨料表面涂覆玻璃陶瓷涂层后,玻璃陶瓷涂层在高温下形成的液相促进材料烧结,使骨料与基质结合更为紧密,所制得的具有玻璃陶瓷涂层的轻量莫来石-碳化硅材料强度明显增加;并且玻璃陶瓷涂层可以吸收部分钾蒸气并产生液相,进一步保护多孔莫来石骨料免受碱侵蚀,从而使具有玻璃陶瓷涂层的轻量莫来石-碳化硅材料的抗碱侵蚀性能优于传统莫来石-碳化硅材料。

玻璃陶瓷涂层  /  多孔莫来石骨料  /  碱侵蚀  /  莫来石碳化硅

Three kinds of mullite-SiC materials were prepared with homogenized bauxite aggregate, porous mullite aggregate and glass ceramic coated porous mullite aggregate, respectively. The physical properties of the mullite-SiC materials sintered at 1 500℃ were investigated. The structure and properties of the materials after alkali vapor attack at 1 000℃ were analyzed. The influence of glass ceramic coating on the alkali vapor attack resistance of material was revealed by thermodynamics analysis. The results show that the strength of the lightweight mullite-SiC material is similar to that of the conventional mullite-SiC materials. However, the lightweight mullite-SiC material has a poor alkali vapor attack resistance. A liquid phase formed in glass ceramic coating at a high temperature promotes sintering, leading to a stronger bonding between aggregates and matrix and an increase in the strength for coated lightweight mullite-SiC materials. Moreover, the glass ceramic coating can absorb a part of K vapor and generate a liquid phase, thus protecting the porous aggregate from alkali vapor. The alkali vapor attack resistance of the lightweight mullite-SiC material is better than that of the conventional mullite-silicon carbide material.

glass ceramic coating  /  porous mullite aggregate  /  alkali resistance  /  mullite-silicon carbide matrial
刘燕, 桑绍柏, 武奇, 马宇洲, 李亚伟, 朱天彬. 玻璃陶瓷涂层对轻量莫来石-碳化硅材料抗碱侵蚀性能的影响. 硅酸盐学报, 2021 , 49 (12) : 2751 -2759 . DOI: 10.14062/j.issn.0454-5648.20210053
Yan LIU, Shaobai SANG, Qi WU, Yuzhou MA, Yawei LI, Tianbin ZHU. Influence of Glass Ceramic Coating on Alkali Resistance of Lightweight Mullite-SiC Composites[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (12) : 2751 -2759 . DOI: 10.14062/j.issn.0454-5648.20210053
  • 国家重点研发计划项目(2019YFC1904900)
  • 湖北省自然科学基金杰出青年人才项目(2019CFA050)
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doi: 10.14062/j.issn.0454-5648.20210053
  • 接收时间:2021-01-18
  • 首发时间:2026-10-30
  • 出版时间:2021-12-20
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  • 收稿日期:2021-01-18
  • 修回日期:2021-04-13
基金
国家重点研发计划项目(2019YFC1904900)
湖北省自然科学基金杰出青年人才项目(2019CFA050)
作者信息
    武汉科技大学,省部共建耐火材料与冶金国家重点实验室,高温材料与炉衬技术国家地方联合工程研究中心,武汉 430081

通讯作者:

桑绍柏(1979—),男,博士,教授。
参考文献
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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