Article(id=1322942662482998208, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200986, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1609257600000, receivedDateStr=2020-12-30, revisedDate=1614873600000, revisedDateStr=2021-03-05, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343709822, onlineDateStr=2026-10-30, pubDate=1626710400000, pubDateStr=2021-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343709822, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343709822, creator=13701087609, updateTime=1793343709822, updator=13701087609, issue=Issue{id=1322942634976752425, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='7', pageStart='1249', pageEnd='1518', issueExtLink='null', onlineDate='null', pubDate='1626710400000', pubDateStr='2021-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343703264, creator='13701087609', updateTime=1793345819416, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951510828659213, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951510828659214, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1395, endPage=1402, ext={EN=ArticleExt(id=1322942662701102017, articleId=1322942662482998208, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of Calcination on Pore Structure and Fractal Characteristics of Diatomite, columnId=1322942641213682516, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Mineral Material, runingTitle=null, highlight=null, articleAbstract=

Diatomite samples were prepared at different calcination temperatures, with Linjiang diatomite as raw material. Pore structures of the diatomite and calcined samples were characterized by using the low-temperature nitrogen adsorption and the mercury intrusion technologies. With these experimental data, fractal characteristics of the diatomite and the calcined samples were analyzed with FHH model, Menger sponge model and thermodynamic relations model. It was found that the diatomite contained mainly mesoporous and macropores. With increasing calcination temperature, specific surface area and mesoporous volume of the diatomite samples were decreased, while the proportion of the macropores was increased. At the same time, the sample surface roughness was reduced or the surface became smoother and smoother. When the calcination temperature was lower than 600℃, fractal dimension of the mesopore volume and heterogeneity of the mesoporous structure were decreased with increasing calcination temperature. The deformation of the mesoporous structure and the mesoporous volume fractal dimension was seriously accelerated after calcining at 1000℃. When the calcination temperature was higher than 600℃, the fractal dimension of the macroporous pores was reduced, while the roughness and inhomogeneity of macropore surface of the samples were decreased.

, authors=Zhibo HU1, 2, 3, Shuilin ZHENG4, Yu LI1, Xingqing WEN1, Junxiang HUANG1, Teng HUANG1, 2, 3, authorsList=Zhibo HU, Shuilin ZHENG, Yu LI, Xingqing WEN, Junxiang HUANG, Teng HUANG, authorCompany=null, correspAuthors=null, authorNote=

HU Zhibo (1987-), male, Ph.D., Lecturer. E-mail:

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以临江硅藻土为原料,经不同煅烧温度处理制备煅烧硅藻土样品。采用低温氮吸附法和压汞法系统表征硅藻土及其煅烧样品的孔道结构特征,基于氮吸附和压汞实验数据,采用FHH模型、Menger海绵模型和热力学关系模型分析硅藻土及其煅烧样品的分形特征。结果表明:硅藻土的孔道主要为介孔和大孔;随着煅烧温度的升高,硅藻土的比表面积和介孔体积呈下降趋势,大孔比例增加,孔隙表面粗糙度降低,表面趋向光滑。煅烧温度低于600℃时,介孔体积分形维数随煅烧温度的升高而降低,介孔结构不均匀性降低,煅烧温度为1000℃时,介孔体积分形维数明显提高,介孔结构变形。煅烧温度高于600℃时,大孔孔隙的分形维数降低,硅藻土的大孔表面的粗糙度和不均匀性降低。

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胡志波(1987—),男,博士,讲师。

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煅烧处理硅藻土的孔道结构及分形特征
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胡志波 1, 2, 3 , 郑水林 4 , 李渝 1 , 文兴青 1 , 黄俊翔 1 , 黄腾 1, 2, 3
硅酸盐学报 | 矿物材料专题 2021,49(7): 1395-1402
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硅酸盐学报 |矿物材料专题 2021 , 49 (7) : 1395 -1402
煅烧处理硅藻土的孔道结构及分形特征
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胡志波1, 2, 3 , 郑水林4, 李渝1, 文兴青1, 黄俊翔1, 黄腾1, 2, 3
作者信息
  • 1.西南科技大学环境与资源学院,四川 绵阳 621010
  • 2.固体废物处理与资源化教育部重点实验室,四川 绵阳 621010
  • 3.四川省非金属矿粉体表面改性和高值化利用工程实验室,四川 绵阳 621010
  • 4.中国矿业大学(北京)化学与环境工程学院,北京 100083
作者简介:

胡志波(1987—),男,博士,讲师。

Effect of Calcination on Pore Structure and Fractal Characteristics of Diatomite
Zhibo HU1, 2, 3 , Shuilin ZHENG4, Yu LI1, Xingqing WEN1, Junxiang HUANG1, Teng HUANG1, 2, 3
Affiliations
  • 1.School of Environment and Resource, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China
  • 2.Key Laboratory of Waste Treatment and Resource Recycle, Southwest University of Science and Technology, Ministry of Education, Mianyang 621010, Sichuan, China
  • 3.Sichuan Provincial Engineering Lab of Non-Metallic Mineral Powder Modification and High-Value Utilization, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China
  • 4.School of Chemical and Environmental Engineering, China University of Mining & Technology (Beijing), Beijing 100083, China
  • HU Zhibo (1987-), male, Ph.D., Lecturer. E-mail:

出版时间: 2021-07-20 doi: 10.14062/j.issn.0454-5648.20200986
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以临江硅藻土为原料,经不同煅烧温度处理制备煅烧硅藻土样品。采用低温氮吸附法和压汞法系统表征硅藻土及其煅烧样品的孔道结构特征,基于氮吸附和压汞实验数据,采用FHH模型、Menger海绵模型和热力学关系模型分析硅藻土及其煅烧样品的分形特征。结果表明:硅藻土的孔道主要为介孔和大孔;随着煅烧温度的升高,硅藻土的比表面积和介孔体积呈下降趋势,大孔比例增加,孔隙表面粗糙度降低,表面趋向光滑。煅烧温度低于600℃时,介孔体积分形维数随煅烧温度的升高而降低,介孔结构不均匀性降低,煅烧温度为1000℃时,介孔体积分形维数明显提高,介孔结构变形。煅烧温度高于600℃时,大孔孔隙的分形维数降低,硅藻土的大孔表面的粗糙度和不均匀性降低。

硅藻土  /  孔结构  /  分形

Diatomite samples were prepared at different calcination temperatures, with Linjiang diatomite as raw material. Pore structures of the diatomite and calcined samples were characterized by using the low-temperature nitrogen adsorption and the mercury intrusion technologies. With these experimental data, fractal characteristics of the diatomite and the calcined samples were analyzed with FHH model, Menger sponge model and thermodynamic relations model. It was found that the diatomite contained mainly mesoporous and macropores. With increasing calcination temperature, specific surface area and mesoporous volume of the diatomite samples were decreased, while the proportion of the macropores was increased. At the same time, the sample surface roughness was reduced or the surface became smoother and smoother. When the calcination temperature was lower than 600℃, fractal dimension of the mesopore volume and heterogeneity of the mesoporous structure were decreased with increasing calcination temperature. The deformation of the mesoporous structure and the mesoporous volume fractal dimension was seriously accelerated after calcining at 1000℃. When the calcination temperature was higher than 600℃, the fractal dimension of the macroporous pores was reduced, while the roughness and inhomogeneity of macropore surface of the samples were decreased.

diatomite  /  pore structure  /  fractal
胡志波, 郑水林, 李渝, 文兴青, 黄俊翔, 黄腾. 煅烧处理硅藻土的孔道结构及分形特征. 硅酸盐学报, 2021 , 49 (7) : 1395 -1402 . DOI: 10.14062/j.issn.0454-5648.20200986
Zhibo HU, Shuilin ZHENG, Yu LI, Xingqing WEN, Junxiang HUANG, Teng HUANG. Effect of Calcination on Pore Structure and Fractal Characteristics of Diatomite[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (7) : 1395 -1402 . DOI: 10.14062/j.issn.0454-5648.20200986
  • 国家自然基金项目(51804262)
  • 浙江省非金属矿工程技术研究中心国土资源部粘土矿物重点实验室开放课题(ZD2018k01)
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doi: 10.14062/j.issn.0454-5648.20200986
  • 接收时间:2020-12-30
  • 首发时间:2026-10-30
  • 出版时间:2021-07-20
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出版历史
  • 收稿日期:2020-12-30
  • 修回日期:2021-03-05
基金
国家自然基金项目(51804262)
浙江省非金属矿工程技术研究中心国土资源部粘土矿物重点实验室开放课题(ZD2018k01)
作者信息
    1.西南科技大学环境与资源学院,四川 绵阳 621010
    2.固体废物处理与资源化教育部重点实验室,四川 绵阳 621010
    3.四川省非金属矿粉体表面改性和高值化利用工程实验室,四川 绵阳 621010
    4.中国矿业大学(北京)化学与环境工程学院,北京 100083
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分享链接
https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20200986
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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