Article(id=1322942832301977944, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942780003201932, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200983, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1609257600000, receivedDateStr=2020-12-30, revisedDate=1614787200000, revisedDateStr=2021-03-04, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343750309, onlineDateStr=2026-10-30, pubDate=1632067200000, pubDateStr=2021-09-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343750309, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343750309, creator=13701087609, updateTime=1793343750309, updator=13701087609, issue=Issue{id=1322942780003201932, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='9', pageStart='1785', pageEnd='2044', issueExtLink='null', onlineDate='null', pubDate='1632067200000', pubDateStr='2021-09-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343737841, creator='13701087609', updateTime=1793345873558, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951737916665918, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942780003201932, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951737916665919, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942780003201932, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1916, endPage=1927, ext={EN=ArticleExt(id=1322942832503304537, articleId=1322942832301977944, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Microstructure and Wave Absorption Properties of SiC
nf-C
f/Si
3N
4 Composites, columnId=1319726165087077079, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Article, runingTitle=null, highlight=null, articleAbstract=
To improve the microwave absorption properties of high-temperature resistance of Si3N4 based composites, four kinds of composites of Si3N4, Cf/Si3N4, SiCnf/Si3N4 and SiCnf-Cf/Si3N4 were prepared by a gel-casting and pressure less sintering process using Si3N4 ceramic as a substrate, and carbon fiber (Cf), SiC nanofibers (SiCnf) or SiC nanofibers coated carbon fiber (SiCnf-Cf), respectively, as an absorber. A comparative study on the microstructure, dielectric properties and microwave absorbing performance at room temperature and 800℃ of as-prepared Si3N4 based composites was conducted. The results show that the high-temperature chemical compatibility of Cf and Si3N4 is effectively improved by coating SiCnf on Cf , and Cf is well preserved in Si3N4 matrix and connected to each other into a conductive network, thus leading to the enhanced electron conduction and multiple relaxation phenomena in SiCn-Cf/Si3N4 composite. The SiCnf-Cf/Si3N4 composite exhibits the maximum dielectric loss value and the optimal microwave absorption performance both at room temperature and 800℃. At room temperature, the minimum reflection loss (RL) of SiCnf-Cf/Si3N4 composite is -15.2 dB at a thickness of 2.57 mm, and the effective absorption bandwidth (RL<-10 dB) is 1.9 GHz at a thickness of 2.30 mm. At 800℃, the minimum RL reaches -20.4 dB at a thickness of 2.0 mm, and the effective absorption bandwidth increases to 3 GHz at a thickness of 2.25 mm. The main absorbing mechanism of SiCnf-Cf/Si3N4 composite is multiple reflections and scattering, electrical conduction loss, electron polarization and multiple relaxations. At 800℃, the polarization and conduction of electrons are enhanced by the accelerated thermal motion of electrons, leading to a further enhancement in the microwave absorption performance. SiCnf-Cf/Si3N4 composite could be used as a high-performance microwave absorbing material for microwave absorption at a high temperature.
, authors=Wei Zhou
1, Yuting Zhang
1, Jingjing Wang
2, Liang Pang
2, Yang Li
2, authorsList=Wei Zhou, Yuting Zhang, Jingjing Wang, Liang Pang, Yang Li, authorCompany=null, correspAuthors=Yang Li, authorNote=
ZHOU Wei (1986-), male, Ph.D.,Associate Professor.
, correspAuthorsNote=
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322942832742379866, articleId=1322942832301977944, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=SiC
nf-C
f/Si
3N
4复合材料的微观结构与吸波性能, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=
以Si3N4陶瓷为基体,分别添加碳纤维(Cf)、SiC纳米纤维(SiCnf)和SiC纳米纤维包覆碳纤维(SiCnf-Cf)作为吸波剂,采用凝胶注模和无压烧结工艺制备Si3N4、Cf/Si3N4、SiCnf/Si3N4和SiCnf-Cf/Si3N4 4种Si3N4基复合材料,并对其微观结构、室温和800℃的介电性能和吸波性能进行了对比研究。结果表明:SiCnf有效改善了Cf与Si3N4的高温化学相容性,使得Cf在基体中保存完好并相互连接成导电网络,导致SiCnf-Cf/Si3N4复合材料中电子传导增强和存在多重弛豫现象,在室温和800℃高温下均展现出最高的介电损耗值和最优的吸波性能。室温时,SiCnf-Cf/Si3N4复合材料的最小反射损耗值为-15.2 dB(厚度为2.57 mm),有效吸收带宽(反射率<-10 dB)为1.9 GHz(厚度为2.3 mm);800℃时,最小反射损耗值达到-20.4 dB(厚度为2.0 mm),有效吸收带宽增大到3 GHz(厚度为2.25 mm)。SiCnf-Cf/Si3N4复合材料的主要吸波机制为多重反射和散射、电传导损耗、电子极化和多重弛豫;800℃时,电子热运动加剧使电子极化和传导增强,吸波性能进一步提高。进一步优化SiCnf-Cf/Si3N4复合材料的吸波性能,其有望作为优异的吸波材料应用于高温吸波领域。
, authors=周伟
1, 张玉婷
1, 王晶晶
2, 庞亮
2, 李杨
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, correspAuthorsNote=
李杨(1987—),男,副教授。
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ZHOU Wei (1986-), male, Ph.D.,Associate Professor.
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