Article(id=1322943498613301855, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942780003201932, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200977, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1609171200000, receivedDateStr=2020-12-29, revisedDate=1618416000000, revisedDateStr=2021-04-15, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343909171, onlineDateStr=2026-10-30, pubDate=1632067200000, pubDateStr=2021-09-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343909171, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343909171, creator=13701087609, updateTime=1793343909171, updator=13701087609, issue=Issue{id=1322942780003201932, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='9', pageStart='1785', pageEnd='2044', issueExtLink='null', onlineDate='null', pubDate='1632067200000', pubDateStr='2021-09-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343737841, creator='13701087609', updateTime=1793345873558, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951737916665918, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942780003201932, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951737916665919, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942780003201932, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1935, endPage=1942, ext={EN=ArticleExt(id=1322943498856571488, articleId=1322943498613301855, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Crystalline Structure, Vibrational Spectra and Intrinsic Dielectric Properties of MgO·1.15Ga₂O₃ Ceramic, columnId=1319726165087077079, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Article, runingTitle=null, highlight=null, articleAbstract=

Magnesium gallate spinel ceramic is a promising candidate material for communication system devices due to its unique microwave dielectric properties. In this work, a pure phase MgO·1.15Ga₂O₃ ceramic powder with the uniform and fine particle size was synthesized via solid-state reaction. The crystal structure of synthesized powder was determined by X-ray diffraction, showing that the structure is (Mg_0.118Ga_0.882)^IV[Mg_0.781Ga_1.185□_0.033]^VIO₄. The ceramic was fabricated by pressureless sintering and subsequent hot isostatic pressing sintering with the powder. Furthermore, the correlations among crystal structure, phonon mode parameters and intrinsic dielectric properties were investigated by Raman scattering spectroscopy and Fourier transform far-infrared reflection spectroscopy. The results show that MgO·1.15Ga₂O₃ ceramic has good microwave dielectric properties (i.e., dielectric constant ε_r of 13.21 and quality factor Q_u×f of 166 THz). Besides, the [Mg—O] polyhedra vibrational group yields a larger contribution to infrared active intensity and dielectric loss rather than other vibration modes. The lattice vibration modes at low frequencies also provide a considerable contribution to intrinsic dielectric loss.

, authors=Shiqiao LI, Bin WANG, Pengyu XU, Bingtian TU, Hao WANG, authorsList=Shiqiao LI, Bin WANG, Pengyu XU, Bingtian TU, Hao WANG, authorCompany=null, correspAuthors=Hao WANG, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322943499129201250, articleId=1322943498613301855, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=MgO·1.15Ga₂O₃陶瓷的晶体结构、振动谱及本征介电性能, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

合成了颗粒均匀细小的单相MgO·1.15Ga₂O₃尖晶石粉体，通过无压预烧结合热等静压烧结制备出致密陶瓷。采用X射线Rietveld全谱拟合法确定其晶体结构为（Mg_0.118Ga_0.882）^IV[Mg_0.781Ga_1.185□_0.033]^VIO₄（□为空位），用Raman光谱与红外反射光谱研究了晶体结构、声子振动模与本征介电性能的关系。结果表明：MgO·1.15Ga₂O₃陶瓷的介电常数ε_r=13.21，品质因子Q_u×f=166 THz，且[Mg—O]多面体振动基团的声子振动模对振子强度和本征介电损耗影响较大。晶格声子振动模对本征介电损耗也有不容忽视的影响。

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LI Shiqiao (1995-), male, Master candidate. E-mail: 18829347511@163.com

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LI Shiqiao (1995-), male, Master candidate. E-mail: 18829347511@163.com

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李石峤（1995—），男，硕士研究生。

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李石峤（1995—），男，硕士研究生。

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