Article(id=1322944011060773657, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200947, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1608566400000, receivedDateStr=2020-12-22, revisedDate=1609344000000, revisedDateStr=2020-12-31, acceptedDate=null, acceptedDateStr=null, onlineDate=1793344031345, onlineDateStr=2026-10-30, pubDate=1624118400000, pubDateStr=2021-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793344031345, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793344031345, creator=13701087609, updateTime=1793344031345, updator=13701087609, issue=Issue{id=1322942627649303277, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='6', pageStart='1033', pageEnd='1246', issueExtLink='null', onlineDate='null', pubDate='1624118400000', pubDateStr='2021-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343701517, creator='13701087609', updateTime=1793345989266, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322952223231181603, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322952223231181604, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1041, endPage=1047, ext={EN=ArticleExt(id=1322944012411339548, articleId=1322944011060773657, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Molten Salt-Assisted Synthesis of r-BN Nanosheets and Its Electrochemical Performance, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

The high-purity r-BN nanosheets were synthesized at 1 100℃ by using KBH4 and NH4Cl as raw materials, NaCl and KCl as molten salt medias. The effects of salt-free and molten-salt methods on the phase composition and crystal morphology of r-BN were studied. And the electrochemical performance of r-BN was tested. Compared with the salt-free method, the molten-salt method can be used to prepare high-crystallinity and good-shaped sheet r-BN at the same temperature. r-BN shows good cycle stability. The specific capacitance of r-BN at a current density of 1 A/g is 16.35 F/g, and r-BN shows a small charge-transfer resistance and internal resistance.

, authors=Xing WANG, Yang CHEN, Chengji DENG, Chao YU, Jun DING, Hongxi ZHU, authorsList=Xing WANG, Yang CHEN, Chengji DENG, Chao YU, Jun DING, Hongxi ZHU, authorCompany=null, correspAuthors=Jun DING, authorNote=

WANG Xing (1985-), female, Doctoral candidate E-mail:

, correspAuthorsNote=
DING Jun(1982-), male, Ph.D., Associate Professor. E-mail:
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以KBH4和NH4Cl为原料,NaCl和KCl为熔盐介质,在1 100℃合成了高纯度的r-BN纳米片。研究了无盐和熔盐两种方法对合成r-BN物相组成和晶体形貌的影响,并测试了r-BN的电化学性能。结果表明:与不添加熔盐方法相比,采用熔盐方法能够在相同温度下制备出结晶性高和形貌好的片状r-BN;r-BN表现出较好的循环稳定性;在1 A/g的电流密度下r-BN的比电容值为16.35 F/g,且r-BN显示出较小的电荷转移电阻和内部电阻。

, authors=王杏, 陈洋, 邓承继, 余超, 丁军, 祝洪喜, authorsList=王杏, 陈洋, 邓承继, 余超, 丁军, 祝洪喜, authorCompany=null, correspAuthors=丁军, authorNote=

王杏(1985—),女,博士研究生。

王杏,武汉科技大学材料科学与工程博士研究生,研究方向为非氧化物绿色合成及其在碳复合耐火材料中的应用。所在课题组研究项目包括:基于菱镁矿的氧化镁基耐高温复合材料的物相重构与转化机理及服役行为;精密加工用纳米B4C研磨陶瓷制备关键技术与应用;碳氮化钛的烧结机理和性能及应用。

丁军,武汉科技大学材料与冶金学院副教授,硕士生导师。湖北省“楚天学者计划”楚天学子。围绕耐火材料设计制备、耐火原料高值高效利用及材料性能表征等领域开展研究。先后主持和参与国家科技支撑计划、973计划前期专项和国家自然科学基金等15项,以第一及通信作者在国内外学术刊物上发表研究论文65篇,其中被SCI检索论文37篇,以第一完成人授权国家发明专利10项,合作制定行业标准1项,获省部级一等奖2项、二等奖2项。

, correspAuthorsNote=
丁军(1982—),男,博士,副教授。
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WANG Xing (1985-), female, Doctoral candidate E-mail:

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WANG Xing (1985-), female, Doctoral candidate E-mail:

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王杏,武汉科技大学材料科学与工程博士研究生,研究方向为非氧化物绿色合成及其在碳复合耐火材料中的应用。所在课题组研究项目包括:基于菱镁矿的氧化镁基耐高温复合材料的物相重构与转化机理及服役行为;精密加工用纳米B4C研磨陶瓷制备关键技术与应用;碳氮化钛的烧结机理和性能及应用。

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王杏,武汉科技大学材料科学与工程博士研究生,研究方向为非氧化物绿色合成及其在碳复合耐火材料中的应用。所在课题组研究项目包括:基于菱镁矿的氧化镁基耐高温复合材料的物相重构与转化机理及服役行为;精密加工用纳米B4C研磨陶瓷制备关键技术与应用;碳氮化钛的烧结机理和性能及应用。

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丁军,武汉科技大学材料与冶金学院副教授,硕士生导师。湖北省“楚天学者计划”楚天学子。围绕耐火材料设计制备、耐火原料高值高效利用及材料性能表征等领域开展研究。先后主持和参与国家科技支撑计划、973计划前期专项和国家自然科学基金等15项,以第一及通信作者在国内外学术刊物上发表研究论文65篇,其中被SCI检索论文37篇,以第一完成人授权国家发明专利10项,合作制定行业标准1项,获省部级一等奖2项、二等奖2项。

"}, bioImg=null, bioContent=

丁军,武汉科技大学材料与冶金学院副教授,硕士生导师。湖北省“楚天学者计划”楚天学子。围绕耐火材料设计制备、耐火原料高值高效利用及材料性能表征等领域开展研究。先后主持和参与国家科技支撑计划、973计划前期专项和国家自然科学基金等15项,以第一及通信作者在国内外学术刊物上发表研究论文65篇,其中被SCI检索论文37篇,以第一完成人授权国家发明专利10项,合作制定行业标准1项,获省部级一等奖2项、二等奖2项。

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熔盐辅助合成r-BN纳米片及其电化学性能
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王杏 , 陈洋 , 邓承继 , 余超 , 丁军 , 祝洪喜
硅酸盐学报 | 2021,49(6): 1041-1047
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硅酸盐学报 | 2021 , 49 (6) : 1041 -1047
熔盐辅助合成r-BN纳米片及其电化学性能
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王杏,武汉科技大学材料科学与工程博士研究生,研究方向为非氧化物绿色合成及其在碳复合耐火材料中的应用。所在课题组研究项目包括:基于菱镁矿的氧化镁基耐高温复合材料的物相重构与转化机理及服役行为;精密加工用纳米B4C研磨陶瓷制备关键技术与应用;碳氮化钛的烧结机理和性能及应用。

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王杏,武汉科技大学材料科学与工程博士研究生,研究方向为非氧化物绿色合成及其在碳复合耐火材料中的应用。所在课题组研究项目包括:基于菱镁矿的氧化镁基耐高温复合材料的物相重构与转化机理及服役行为;精密加工用纳米B4C研磨陶瓷制备关键技术与应用;碳氮化钛的烧结机理和性能及应用。

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丁军,武汉科技大学材料与冶金学院副教授,硕士生导师。湖北省“楚天学者计划”楚天学子。围绕耐火材料设计制备、耐火原料高值高效利用及材料性能表征等领域开展研究。先后主持和参与国家科技支撑计划、973计划前期专项和国家自然科学基金等15项,以第一及通信作者在国内外学术刊物上发表研究论文65篇,其中被SCI检索论文37篇,以第一完成人授权国家发明专利10项,合作制定行业标准1项,获省部级一等奖2项、二等奖2项。

"}, bioImg=null, bioContent=

丁军,武汉科技大学材料与冶金学院副教授,硕士生导师。湖北省“楚天学者计划”楚天学子。围绕耐火材料设计制备、耐火原料高值高效利用及材料性能表征等领域开展研究。先后主持和参与国家科技支撑计划、973计划前期专项和国家自然科学基金等15项,以第一及通信作者在国内外学术刊物上发表研究论文65篇,其中被SCI检索论文37篇,以第一完成人授权国家发明专利10项,合作制定行业标准1项,获省部级一等奖2项、二等奖2项。

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王杏 , 陈洋, 邓承继, 余超, 丁军 , 祝洪喜
作者信息
  • 武汉科技大学,省部共建耐火材料与冶金国家重点实验室,武汉 430081
通讯作者:
丁军(1982—),男,博士,副教授。
作者简介:

王杏(1985—),女,博士研究生。

王杏,武汉科技大学材料科学与工程博士研究生,研究方向为非氧化物绿色合成及其在碳复合耐火材料中的应用。所在课题组研究项目包括:基于菱镁矿的氧化镁基耐高温复合材料的物相重构与转化机理及服役行为;精密加工用纳米B4C研磨陶瓷制备关键技术与应用;碳氮化钛的烧结机理和性能及应用。

丁军,武汉科技大学材料与冶金学院副教授,硕士生导师。湖北省“楚天学者计划”楚天学子。围绕耐火材料设计制备、耐火原料高值高效利用及材料性能表征等领域开展研究。先后主持和参与国家科技支撑计划、973计划前期专项和国家自然科学基金等15项,以第一及通信作者在国内外学术刊物上发表研究论文65篇,其中被SCI检索论文37篇,以第一完成人授权国家发明专利10项,合作制定行业标准1项,获省部级一等奖2项、二等奖2项。

Molten Salt-Assisted Synthesis of r-BN Nanosheets and Its Electrochemical Performance
Xing WANG , Yang CHEN, Chengji DENG, Chao YU, Jun DING , Hongxi ZHU
Affiliations
  • The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
  • Corresponding Author:
    DING Jun(1982-), male, Ph.D., Associate Professor. E-mail:

    WANG Xing (1985-), female, Doctoral candidate E-mail:

出版时间: 2021-06-20 doi: 10.14062/j.issn.0454-5648.20200947
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以KBH4和NH4Cl为原料,NaCl和KCl为熔盐介质,在1 100℃合成了高纯度的r-BN纳米片。研究了无盐和熔盐两种方法对合成r-BN物相组成和晶体形貌的影响,并测试了r-BN的电化学性能。结果表明:与不添加熔盐方法相比,采用熔盐方法能够在相同温度下制备出结晶性高和形貌好的片状r-BN;r-BN表现出较好的循环稳定性;在1 A/g的电流密度下r-BN的比电容值为16.35 F/g,且r-BN显示出较小的电荷转移电阻和内部电阻。

熔盐  /  菱形氮化硼  /  物相  /  显微结构  /  电化学性能

The high-purity r-BN nanosheets were synthesized at 1 100℃ by using KBH4 and NH4Cl as raw materials, NaCl and KCl as molten salt medias. The effects of salt-free and molten-salt methods on the phase composition and crystal morphology of r-BN were studied. And the electrochemical performance of r-BN was tested. Compared with the salt-free method, the molten-salt method can be used to prepare high-crystallinity and good-shaped sheet r-BN at the same temperature. r-BN shows good cycle stability. The specific capacitance of r-BN at a current density of 1 A/g is 16.35 F/g, and r-BN shows a small charge-transfer resistance and internal resistance.

molten salt  /  rhombohedral boron nitride  /  phase  /  microstructure  /  electrochemical performance
王杏, 陈洋, 邓承继, 余超, 丁军, 祝洪喜. 熔盐辅助合成r-BN纳米片及其电化学性能. 硅酸盐学报, 2021 , 49 (6) : 1041 -1047 . DOI: 10.14062/j.issn.0454-5648.20200947
Xing WANG, Yang CHEN, Chengji DENG, Chao YU, Jun DING, Hongxi ZHU. Molten Salt-Assisted Synthesis of r-BN Nanosheets and Its Electrochemical Performance[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (6) : 1041 -1047 . DOI: 10.14062/j.issn.0454-5648.20200947
  • 国家自然科学基金(51574187; 51502215; 51602232)
  • 湖北省自然科学基金创新群体项目(2018CFA022)
  • 武汉科技大学研究生创新创业基金(JCX201904)
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2021年第49卷第6期
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doi: 10.14062/j.issn.0454-5648.20200947
  • 接收时间:2020-12-22
  • 首发时间:2026-10-30
  • 出版时间:2021-06-20
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  • 收稿日期:2020-12-22
  • 修回日期:2020-12-31
基金
国家自然科学基金(51574187; 51502215; 51602232)
湖北省自然科学基金创新群体项目(2018CFA022)
武汉科技大学研究生创新创业基金(JCX201904)
作者信息
    武汉科技大学,省部共建耐火材料与冶金国家重点实验室,武汉 430081

通讯作者:

丁军(1982—),男,博士,副教授。
参考文献
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20200947
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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