Article(id=1322942815877083302, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942780003201932, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200933, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1608307200000, receivedDateStr=2020-12-19, revisedDate=1612281600000, revisedDateStr=2021-02-03, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343746393, onlineDateStr=2026-10-30, pubDate=1632067200000, pubDateStr=2021-09-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343746393, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343746393, creator=13701087609, updateTime=1793343746393, updator=13701087609, issue=Issue{id=1322942780003201932, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='9', pageStart='1785', pageEnd='2044', issueExtLink='null', onlineDate='null', pubDate='1632067200000', pubDateStr='2021-09-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343737841, creator='13701087609', updateTime=1793345873558, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951737916665918, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942780003201932, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951737916665919, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942780003201932, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1976, endPage=1984, ext={EN=ArticleExt(id=1322942816095187112, articleId=1322942815877083302, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Fe-Doped TiO2 for Visible Light-Driven Nitrogen Fixation, columnId=1319726165087077079, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Article, runingTitle=null, highlight=null, articleAbstract=

Fe-doped TiO2 with rich surface oxygen vacancies was prepared by a facile solvothermal method combined with HF etching. The doping of Fe extends the light absorption range of TiO2 from ultraviolet to visible light. The abundant oxygen vacancies on the TiO2 surface cooperate with the d orbital of Fe3+ to provide a large number of active sites for activating nitrogen molecules, and inhibit the recombination of electrons and holes. In ambient condition, without any sacrificial agent, the ammonia production of 6% Fe-TiO2 reaches 94.3 µmol·g-1·h-1, compared to that of pure TiO2. In visible light illumination, the ammonia production of 6% Fe-TiO2 reaches 45.6 µmol·g-1·h-1.

, authors=Yu ZHOU, Pu YUAN, Yujing XIANG, Wenfeng HAN, Haodong TANG, Rongbin HUANG, Aimin Chen, authorsList=Yu ZHOU, Pu YUAN, Yujing XIANG, Wenfeng HAN, Haodong TANG, Rongbin HUANG, Aimin Chen, authorCompany=null, correspAuthors=Rongbin HUANG, Aimin Chen, authorNote=

ZHOU Yu (1996-), female, Master candidate. E-mail:

, correspAuthorsNote=
CHEN Aimin (1975-), male, Associate Professor. E-mail:
HUANG Rongbin (1965-), male, Associate Professor.
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通过溶剂热法协同氢氟酸刻蚀,制备得到富表面氧空位的Fe-TiO2光催化剂。Fe掺杂到TiO2晶格中,拓宽了TiO2对可见光的吸收;TiO2表面丰富的氧空位协同Fe3+的d轨道为活化氮分子提供大量活性位点,同时抑制了电子-空穴的复合。在温和无牺牲剂条件下,6% Fe-TiO2的光催化固氮率达到94.3 µmol·g-1·h-1;在可见光光照下,6% Fe-TiO2的氨产量达到45.6 µmol·g-1·h-1。

, authors=周煜, 袁普, 相钰婧, 韩文锋, 唐浩东, 黄荣斌, 陈爱民, authorsList=周煜, 袁普, 相钰婧, 韩文锋, 唐浩东, 黄荣斌, 陈爱民, authorCompany=null, correspAuthors=黄荣斌, 陈爱民, authorNote=

周煜(1996—),女,硕士研究生。

, correspAuthorsNote=
陈爱民(1975—),男,博士,副教授。
黄荣斌(1965—),男,博士,副教授。
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周煜(1996—),女,硕士研究生。

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可见光响应的Fe-TiO2增强光催化合成氨活性
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周煜 , 袁普 , 相钰婧 , 韩文锋 , 唐浩东 , 黄荣斌 , 陈爱民
硅酸盐学报 | 研究论文 2021,49(9): 1976-1984
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硅酸盐学报 |研究论文 2021 , 49 (9) : 1976 -1984
可见光响应的Fe-TiO2增强光催化合成氨活性
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周煜 , 袁普, 相钰婧, 韩文锋, 唐浩东, 黄荣斌 , 陈爱民
作者信息
  • 浙江工业大学化学工程学院,杭州 310014
通讯作者:
陈爱民(1975—),男,博士,副教授。
黄荣斌(1965—),男,博士,副教授。
作者简介:

周煜(1996—),女,硕士研究生。

Fe-Doped TiO2 for Visible Light-Driven Nitrogen Fixation
Yu ZHOU , Pu YUAN, Yujing XIANG, Wenfeng HAN, Haodong TANG, Rongbin HUANG , Aimin Chen
Affiliations
  • College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China
  • Corresponding Author:
    CHEN Aimin (1975-), male, Associate Professor. E-mail:
    HUANG Rongbin (1965-), male, Associate Professor.

    ZHOU Yu (1996-), female, Master candidate. E-mail:

出版时间: 2021-09-20 doi: 10.14062/j.issn.0454-5648.20200933
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通过溶剂热法协同氢氟酸刻蚀,制备得到富表面氧空位的Fe-TiO2光催化剂。Fe掺杂到TiO2晶格中,拓宽了TiO2对可见光的吸收;TiO2表面丰富的氧空位协同Fe3+的d轨道为活化氮分子提供大量活性位点,同时抑制了电子-空穴的复合。在温和无牺牲剂条件下,6% Fe-TiO2的光催化固氮率达到94.3 µmol·g-1·h-1;在可见光光照下,6% Fe-TiO2的氨产量达到45.6 µmol·g-1·h-1。

二氧化钛  /  掺杂  /  氧空位  /  光催化合成氨

Fe-doped TiO2 with rich surface oxygen vacancies was prepared by a facile solvothermal method combined with HF etching. The doping of Fe extends the light absorption range of TiO2 from ultraviolet to visible light. The abundant oxygen vacancies on the TiO2 surface cooperate with the d orbital of Fe3+ to provide a large number of active sites for activating nitrogen molecules, and inhibit the recombination of electrons and holes. In ambient condition, without any sacrificial agent, the ammonia production of 6% Fe-TiO2 reaches 94.3 µmol·g-1·h-1, compared to that of pure TiO2. In visible light illumination, the ammonia production of 6% Fe-TiO2 reaches 45.6 µmol·g-1·h-1.

titanium dioxide  /  doping  /  oxygen vacancy  /  photocatalytic synthesis of ammonia
周煜, 袁普, 相钰婧, 韩文锋, 唐浩东, 黄荣斌, 陈爱民. 可见光响应的Fe-TiO2增强光催化合成氨活性. 硅酸盐学报, 2021 , 49 (9) : 1976 -1984 . DOI: 10.14062/j.issn.0454-5648.20200933
Yu ZHOU, Pu YUAN, Yujing XIANG, Wenfeng HAN, Haodong TANG, Rongbin HUANG, Aimin Chen. Fe-Doped TiO2 for Visible Light-Driven Nitrogen Fixation[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (9) : 1976 -1984 . DOI: 10.14062/j.issn.0454-5648.20200933
  • 国家自然科学基金(21776257)
  • 浙江省自然科学基金(LY19B 050004; LY19B060009)
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2021年第49卷第9期
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doi: 10.14062/j.issn.0454-5648.20200933
  • 接收时间:2020-12-19
  • 首发时间:2026-10-30
  • 出版时间:2021-09-20
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  • 收稿日期:2020-12-19
  • 修回日期:2021-02-03
基金
国家自然科学基金(21776257)
浙江省自然科学基金(LY19B 050004; LY19B060009)
作者信息
    浙江工业大学化学工程学院,杭州 310014

通讯作者:

陈爱民(1975—),男,博士,副教授。
黄荣斌(1965—),男,博士,副教授。
参考文献
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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