Article(id=1322942635563954985, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200906, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1607184000000, receivedDateStr=2020-12-06, revisedDate=1611504000000, revisedDateStr=2021-01-25, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343703403, onlineDateStr=2026-10-30, pubDate=1626710400000, pubDateStr=2021-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343703403, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343703403, creator=13701087609, updateTime=1793343703403, updator=13701087609, issue=Issue{id=1322942634976752425, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='7', pageStart='1249', pageEnd='1518', issueExtLink='null', onlineDate='null', pubDate='1626710400000', pubDateStr='2021-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343703264, creator='13701087609', updateTime=1793345819416, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951510828659213, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951510828659214, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1263, endPage=1277, ext={EN=ArticleExt(id=1322942635958219563, articleId=1322942635563954985, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Research Progress of Composite Solid Electrolytes and Their Interface for Lithium Metal Batteries, columnId=1322942635891110698, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Energy Material, runingTitle=null, highlight=null, articleAbstract=

Solid state lithium metal batteries have extremely high safety, due to the non-flammable and non-volatile characteristics, which makes it possible to use high energy density lithium metal as negative electrode. However, there are still several challenges in the industrialization of solid state lithium metal batteries, such as high interface impedance, poor solid electrolyte/electrode compatibility, low electrolyte ionic conductivity and narrow electrochemical window. Therefore, the development of flexible solid electrolytes with high performance has become an important research topic, in terms of accelerating the development of solid state lithium metal batteries. Here, the latest research progress of composite solid electrolytes in solid state lithium metal batteries and the interface problems and solutions of composite solid electrolyte matching electrode materials will be comprehensively described.

, authors=Guoxu WANG, Hong LIU, Yuhao LIANG, Bingyao WANG, Lizhen FAN, authorsList=Guoxu WANG, Hong LIU, Yuhao LIANG, Bingyao WANG, Lizhen FAN, authorCompany=null, correspAuthors=Lizhen FAN, authorNote=

WANG Guoxu (1987-), male, Doctoral candidate. E-mail:

, correspAuthorsNote=
FAN Lizhen (1975-), female, Ph.D., Professor. E-mail:
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相比于液态锂电池,固态锂金属电池由于电解质不易燃、不挥发而具有更高的安全性。此外,固态电解质能够有效抑制锂枝晶的生长,使基于高能量密度的锂金属作为负极材料成为可能。但是,固态锂金属电池存在着界面阻抗大、固体电解质/电极兼容性差、电解质离子电导率低及电化学窗口较窄等问题。因此,开发高性能的柔性固体电解质对推动固态锂金属电池的发展起着重要作用。本工作总结了固态锂金属电池中聚合物与不同类型填料复合最新研究进展及复合固体电解质匹配电极材料时存在的界面阻抗大问题与解决策略。

, authors=王国需, 刘洪, 梁宇皓, 王秉尧, 范丽珍, authorsList=王国需, 刘洪, 梁宇皓, 王秉尧, 范丽珍, authorCompany=null, correspAuthors=范丽珍, authorNote=

王国需(1987—),男,博士研究生。

, correspAuthorsNote=
范丽珍(1975—),女,教授。
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王国需(1987—),男,博士研究生。

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王国需(1987—),男,博士研究生。

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锂金属电池用复合固体电解质及其界面研究进展
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王国需 , 刘洪 , 梁宇皓 , 王秉尧 , 范丽珍
硅酸盐学报 | 能源材料专题 2021,49(7): 1263-1277
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硅酸盐学报 |能源材料专题 2021 , 49 (7) : 1263 -1277
锂金属电池用复合固体电解质及其界面研究进展
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王国需 , 刘洪, 梁宇皓, 王秉尧, 范丽珍
作者信息
  • 北京科技大学新材料技术研究院,北京 100083
通讯作者:
范丽珍(1975—),女,教授。
作者简介:

王国需(1987—),男,博士研究生。

Research Progress of Composite Solid Electrolytes and Their Interface for Lithium Metal Batteries
Guoxu WANG , Hong LIU, Yuhao LIANG, Bingyao WANG, Lizhen FAN
Affiliations
  • Institute of Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China
  • Corresponding Author:
    FAN Lizhen (1975-), female, Ph.D., Professor. E-mail:

    WANG Guoxu (1987-), male, Doctoral candidate. E-mail:

出版时间: 2021-07-20 doi: 10.14062/j.issn.0454-5648.20200906
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相比于液态锂电池,固态锂金属电池由于电解质不易燃、不挥发而具有更高的安全性。此外,固态电解质能够有效抑制锂枝晶的生长,使基于高能量密度的锂金属作为负极材料成为可能。但是,固态锂金属电池存在着界面阻抗大、固体电解质/电极兼容性差、电解质离子电导率低及电化学窗口较窄等问题。因此,开发高性能的柔性固体电解质对推动固态锂金属电池的发展起着重要作用。本工作总结了固态锂金属电池中聚合物与不同类型填料复合最新研究进展及复合固体电解质匹配电极材料时存在的界面阻抗大问题与解决策略。

固态锂金属电池  /  复合固体电解质  /  填料  /  界面

Solid state lithium metal batteries have extremely high safety, due to the non-flammable and non-volatile characteristics, which makes it possible to use high energy density lithium metal as negative electrode. However, there are still several challenges in the industrialization of solid state lithium metal batteries, such as high interface impedance, poor solid electrolyte/electrode compatibility, low electrolyte ionic conductivity and narrow electrochemical window. Therefore, the development of flexible solid electrolytes with high performance has become an important research topic, in terms of accelerating the development of solid state lithium metal batteries. Here, the latest research progress of composite solid electrolytes in solid state lithium metal batteries and the interface problems and solutions of composite solid electrolyte matching electrode materials will be comprehensively described.

solid state lithium metal batteries  /  composite solid electrolytes  /  fillers  /  interface
王国需, 刘洪, 梁宇皓, 王秉尧, 范丽珍. 锂金属电池用复合固体电解质及其界面研究进展. 硅酸盐学报, 2021 , 49 (7) : 1263 -1277 . DOI: 10.14062/j.issn.0454-5648.20200906
Guoxu WANG, Hong LIU, Yuhao LIANG, Bingyao WANG, Lizhen FAN. Research Progress of Composite Solid Electrolytes and Their Interface for Lithium Metal Batteries[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (7) : 1263 -1277 . DOI: 10.14062/j.issn.0454-5648.20200906
  • 国家自然科学基金(51872027)
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doi: 10.14062/j.issn.0454-5648.20200906
  • 接收时间:2020-12-06
  • 首发时间:2026-10-30
  • 出版时间:2021-07-20
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  • 收稿日期:2020-12-06
  • 修回日期:2021-01-25
基金
国家自然科学基金(51872027)
作者信息
    北京科技大学新材料技术研究院,北京 100083

通讯作者:

范丽珍(1975—),女,教授。
参考文献
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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