Article(id=1322942739825963579, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942707957641522, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200825, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1604246400000, receivedDateStr=2020-11-02, revisedDate=1606147200000, revisedDateStr=2020-11-24, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343728262, onlineDateStr=2026-10-30, pubDate=1629388800000, pubDateStr=2021-08-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343728262, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343728262, creator=13701087609, updateTime=1793343728262, updator=13701087609, issue=Issue{id=1322942707957641522, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='8', pageStart='1519', pageEnd='1784', issueExtLink='null', onlineDate='null', pubDate='1629388800000', pubDateStr='2021-08-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343720664, creator='13701087609', updateTime=1793345848275, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951631859494962, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942707957641522, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951631859494963, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942707957641522, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1699, endPage=1705, ext={EN=ArticleExt(id=1322942740459303484, articleId=1322942739825963579, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=In-situ Study on Micro-Nano Structure of Portland Cement Hydration Products, columnId=1319726165087077079, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Article, runingTitle=null, highlight=null, articleAbstract=

BSE-Raman was used to investigate in-situ Raman spectra of hydration products and their spatial distribution profiles. It was found that the in-situ structural information of the silicon-oxygen tetrahedral Q1, Q2 and Q3 chains of C-S-H could be readily obtained, while the hydration products could be accurately identified. All the hydration products with different morphologies exhibited multiple characteristic peaks of chemical bonds of the hydration products. Therefore, it was concluded that the cement hydration products were mixed at nanometer scale. The pom-shaped hydration product had a skeleton consisting of C-S-H and ettringite. Due to its ability of quick and accurate in-situ identification of different phases, BSE-Raman has broad prospects in the microstructural characterization of cement-based materials.

, authors=Zheyu ZHU, Zhongping WANG, Yue ZHOU, Yuting CHEN, Kai WU, authorsList=Zheyu ZHU, Zhongping WANG, Yue ZHOU, Yuting CHEN, Kai WU, authorCompany=null, correspAuthors=Kai WU, authorNote=

ZHU Zheyu (1991-), male, Doctor candidate. E-mail:

, correspAuthorsNote=
WU Kai (1987-), male, Ph. D., Associate Professor. E-mail:
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采用BSE-Raman原位表征了硅酸盐水泥水化产物的Raman光谱和空间分布。结果表明:BSE-Raman能够原位获取水化硅酸钙(C-S-H)中硅氧四面体链Q1、Q2、Q3的结构信息。不同形貌组分的原位Raman光谱均由多种水化产物的Raman特征峰组成,即水泥水化产物在纳米尺寸存在混合现象。其中,占比最大的绒球状骨架主要由C-S-H和钙矾石(AFt)组成。BSE-Raman可快速、原位、精确识别不同的物相,在水泥基材料微结构表征方面具有广阔前景。

, authors=朱哲誉, 王中平, 周玥, 陈钰婷, 吴凯, authorsList=朱哲誉, 王中平, 周玥, 陈钰婷, 吴凯, authorCompany=null, correspAuthors=吴凯, authorNote=

朱哲誉(1991—);男,博士研究生。

, correspAuthorsNote=
吴凯(1987—);男,博士,副教授。
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硅酸盐水泥水化产物微纳结构的原位研究
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朱哲誉 , 王中平 , 周玥 , 陈钰婷 , 吴凯
硅酸盐学报 | 研究论文 2021,49(8): 1699-1705
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硅酸盐学报 |研究论文 2021 , 49 (8) : 1699 -1705
硅酸盐水泥水化产物微纳结构的原位研究
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朱哲誉 , 王中平, 周玥, 陈钰婷, 吴凯
作者信息
  • 先进土木工程材料教育部重点实验室,同济大学材料科学与工程学院,上海 201804
通讯作者:
吴凯(1987—);男,博士,副教授。
作者简介:

朱哲誉(1991—);男,博士研究生。

In-situ Study on Micro-Nano Structure of Portland Cement Hydration Products
Zheyu ZHU , Zhongping WANG, Yue ZHOU, Yuting CHEN, Kai WU
Affiliations
  • School of Materials Science and Engineering, Tongji University, Shanghai 201804, China
  • Corresponding Author:
    WU Kai (1987-), male, Ph. D., Associate Professor. E-mail:

    ZHU Zheyu (1991-), male, Doctor candidate. E-mail:

出版时间: 2021-08-20 doi: 10.14062/j.issn.0454-5648.20200825
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采用BSE-Raman原位表征了硅酸盐水泥水化产物的Raman光谱和空间分布。结果表明:BSE-Raman能够原位获取水化硅酸钙(C-S-H)中硅氧四面体链Q1、Q2、Q3的结构信息。不同形貌组分的原位Raman光谱均由多种水化产物的Raman特征峰组成,即水泥水化产物在纳米尺寸存在混合现象。其中,占比最大的绒球状骨架主要由C-S-H和钙矾石(AFt)组成。BSE-Raman可快速、原位、精确识别不同的物相,在水泥基材料微结构表征方面具有广阔前景。

硅酸盐水泥  /  Raman光谱  /  原位  /  水化硅酸钙  /  钙矾石

BSE-Raman was used to investigate in-situ Raman spectra of hydration products and their spatial distribution profiles. It was found that the in-situ structural information of the silicon-oxygen tetrahedral Q1, Q2 and Q3 chains of C-S-H could be readily obtained, while the hydration products could be accurately identified. All the hydration products with different morphologies exhibited multiple characteristic peaks of chemical bonds of the hydration products. Therefore, it was concluded that the cement hydration products were mixed at nanometer scale. The pom-shaped hydration product had a skeleton consisting of C-S-H and ettringite. Due to its ability of quick and accurate in-situ identification of different phases, BSE-Raman has broad prospects in the microstructural characterization of cement-based materials.

Portland cement  /  Raman spectra  /  in-situ  /  calcium silicate hydrates  /  ettringite
朱哲誉, 王中平, 周玥, 陈钰婷, 吴凯. 硅酸盐水泥水化产物微纳结构的原位研究. 硅酸盐学报, 2021 , 49 (8) : 1699 -1705 . DOI: 10.14062/j.issn.0454-5648.20200825
Zheyu ZHU, Zhongping WANG, Yue ZHOU, Yuting CHEN, Kai WU. In-situ Study on Micro-Nano Structure of Portland Cement Hydration Products[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (8) : 1699 -1705 . DOI: 10.14062/j.issn.0454-5648.20200825
  • 国家自然科学基金项目(51772212; 51978505)
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doi: 10.14062/j.issn.0454-5648.20200825
  • 接收时间:2020-11-02
  • 首发时间:2026-10-30
  • 出版时间:2021-08-20
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  • 收稿日期:2020-11-02
  • 修回日期:2020-11-24
基金
国家自然科学基金项目(51772212; 51978505)
作者信息
    先进土木工程材料教育部重点实验室,同济大学材料科学与工程学院,上海 201804

通讯作者:

吴凯(1987—);男,博士,副教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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