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Oscillatory pressure sintering (OPS) technique was used to prepare silicon nitride ceramics with high quality. In comparison with hot pressure (HP) sintering process, the density, phase, grain size, aspect ratio and microstructure of silicon nitride ceramics by two methods were further investigated. The densification effect of oscillatory pressure on silicon nitride ceramics were studied. The results indicate that the silicon nitride ceramic has reached a complete phase transition from α phase to β phase under OPS process and its relative density has reached 99.82%. The grain sizes of OPS specimen are significantly increased compared with the specimen prepared by HP process. The average aspect ratio of the grains has increased from 3.79 to 4.86 when the fabricated process changed from HP to OPS. Bending strength, hardness and fracture toughness reached 1 333 MPa, 16.2 GPa, 12.1 MPa·m1/2, respectively. Fracture surface energy also increased with the introduction of oscillatory pressure. In addition, obvious deformation streaks and dislocation movement areas are observed through TEM analysis. Obviously, the application of oscillatory pressure improves the densification rate and the growth driving force of grains. The plastic deformation of silicon nitride during the densification process were also found. Thereby, the sintering densification process was accelerated.
, authors=Yao HAN
1, Haiyan LI
2, Zhipeng XIE
3, Huadong WANG
1, Heng DONG
1, Zhiqiang SUN
1, Bingqing ZHANG
1, Jian ZHANG
1, Yi LV
1, authorsList=Yao HAN, Haiyan LI, Zhipeng XIE, Huadong WANG, Heng DONG, Zhiqiang SUN, Bingqing ZHANG, Jian ZHANG, Yi LV, authorCompany=null, correspAuthors=null, authorNote=
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采用新型振荡压力烧结技术制备高性能氮化硅陶瓷,并对比热压烧结技术,研究了不同工艺下氮化硅陶瓷的致密度、物相、晶粒尺寸、微观形貌及力学性能变化规律,分析了振荡压力对氮化硅陶瓷的致密化作用。结果表明:振荡压力烧结工艺下氮化硅陶瓷实现了α相到β相的物相完全转变,相对密度达到了99.82%;对比热压烧结工艺,振荡压力作用下氮化硅陶瓷的晶粒尺寸明显增加,晶粒平均长径比由3.79增加到4.86,弯曲强度、硬度及断裂韧性分别提高到1333 MPa、16.2 GPa、12.1 MPa·m1/2,断裂表面能也明显提高。OPS试样晶粒表面观察到了明显的形变条纹和位错运动区域。振荡压力的引入提高了致密化速率和晶粒的生长驱动力,且能够促进氮化硅在致密化过程中塑性形变的产生,有效加快了烧结致密化进程。
, authors=韩耀
1, 李海燕
2, 谢志鹏
3, 王华栋
1, 董衡
1, 孙志强
1, 张冰清
1, 张剑
1, 吕毅
1, authorsList=韩耀, 李海燕, 谢志鹏, 王华栋, 董衡, 孙志强, 张冰清, 张剑, 吕毅, authorCompany=null, correspAuthors=null, authorNote=
 |
韩耀,航天特种材料及工艺技术研究所工程师,博士。先后参与和主持科技部“国家重点研发科技课题”、国家自然科学基金重大仪器科研仪器专项、面上项目、青年基金项目以及国防科工局等科研课题10余项。在国内外学术刊物发表研究论文20余篇,国内外会议宣读展示论文6篇,其中SCI收录论文18篇,申请专利10项,已授权专利3项。主要研究方向为新型烧结技术、高性能结构陶瓷、纤维增强陶瓷基透波材料、热结构陶瓷基复合材料、纳米粉体。研究项目包括:新型振荡压力烧结技术制备高性能结构陶瓷及其致密化机理研究、耐高温纤维增强陶瓷基透波材料的结构设计与一体化研究、高性能氮化铝粉体的合成制备技术研究、低密度高热导率多孔材料的结构设计优化研究。 |
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韩耀,航天特种材料及工艺技术研究所工程师,博士。先后参与和主持科技部“国家重点研发科技课题”、国家自然科学基金重大仪器科研仪器专项、面上项目、青年基金项目以及国防科工局等科研课题10余项。在国内外学术刊物发表研究论文20余篇,国内外会议宣读展示论文6篇,其中SCI收录论文18篇,申请专利10项,已授权专利3项。主要研究方向为新型烧结技术、高性能结构陶瓷、纤维增强陶瓷基透波材料、热结构陶瓷基复合材料、纳米粉体。研究项目包括:新型振荡压力烧结技术制备高性能结构陶瓷及其致密化机理研究、耐高温纤维增强陶瓷基透波材料的结构设计与一体化研究、高性能氮化铝粉体的合成制备技术研究、低密度高热导率多孔材料的结构设计优化研究。
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韩耀,航天特种材料及工艺技术研究所工程师,博士。先后参与和主持科技部“国家重点研发科技课题”、国家自然科学基金重大仪器科研仪器专项、面上项目、青年基金项目以及国防科工局等科研课题10余项。在国内外学术刊物发表研究论文20余篇,国内外会议宣读展示论文6篇,其中SCI收录论文18篇,申请专利10项,已授权专利3项。主要研究方向为新型烧结技术、高性能结构陶瓷、纤维增强陶瓷基透波材料、热结构陶瓷基复合材料、纳米粉体。研究项目包括:新型振荡压力烧结技术制备高性能结构陶瓷及其致密化机理研究、耐高温纤维增强陶瓷基透波材料的结构设计与一体化研究、高性能氮化铝粉体的合成制备技术研究、低密度高热导率多孔材料的结构设计优化研究。
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