Article(id=1322943129510355823, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942545734546372, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200636, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1598112000000, receivedDateStr=2020-08-23, revisedDate=1605628800000, revisedDateStr=2020-11-18, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343821170, onlineDateStr=2026-10-30, pubDate=1618848000000, pubDateStr=2021-04-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343821170, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343821170, creator=13701087609, updateTime=1793343821170, updator=13701087609, issue=Issue{id=1322942545734546372, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='4', pageStart='605', pageEnd='806', issueExtLink='null', onlineDate='null', pubDate='1618848000000', pubDateStr='2021-04-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343681986, creator='13701087609', updateTime=1793345524324, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322950273110508350, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942545734546372, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322950273110508351, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942545734546372, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=673, endPage=680, ext={EN=ArticleExt(id=1322943131401986929, articleId=1322943129510355823, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of Oscillatory Pressure on Sintering Densification of High Quality Silicon Nitride Ceramics, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Oscillatory pressure sintering (OPS) technique was used to prepare silicon nitride ceramics with high quality. In comparison with hot pressure (HP) sintering process, the density, phase, grain size, aspect ratio and microstructure of silicon nitride ceramics by two methods were further investigated. The densification effect of oscillatory pressure on silicon nitride ceramics were studied. The results indicate that the silicon nitride ceramic has reached a complete phase transition from α phase to β phase under OPS process and its relative density has reached 99.82%. The grain sizes of OPS specimen are significantly increased compared with the specimen prepared by HP process. The average aspect ratio of the grains has increased from 3.79 to 4.86 when the fabricated process changed from HP to OPS. Bending strength, hardness and fracture toughness reached 1 333 MPa, 16.2 GPa, 12.1 MPa·m1/2, respectively. Fracture surface energy also increased with the introduction of oscillatory pressure. In addition, obvious deformation streaks and dislocation movement areas are observed through TEM analysis. Obviously, the application of oscillatory pressure improves the densification rate and the growth driving force of grains. The plastic deformation of silicon nitride during the densification process were also found. Thereby, the sintering densification process was accelerated.

, authors=Yao HAN1, Haiyan LI2, Zhipeng XIE3, Huadong WANG1, Heng DONG1, Zhiqiang SUN1, Bingqing ZHANG1, Jian ZHANG1, Yi LV1, authorsList=Yao HAN, Haiyan LI, Zhipeng XIE, Huadong WANG, Heng DONG, Zhiqiang SUN, Bingqing ZHANG, Jian ZHANG, Yi LV, authorCompany=null, correspAuthors=null, authorNote=

HAN Yao (1990-), male, Ph.D., Engineer. E-mail:

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采用新型振荡压力烧结技术制备高性能氮化硅陶瓷,并对比热压烧结技术,研究了不同工艺下氮化硅陶瓷的致密度、物相、晶粒尺寸、微观形貌及力学性能变化规律,分析了振荡压力对氮化硅陶瓷的致密化作用。结果表明:振荡压力烧结工艺下氮化硅陶瓷实现了α相到β相的物相完全转变,相对密度达到了99.82%;对比热压烧结工艺,振荡压力作用下氮化硅陶瓷的晶粒尺寸明显增加,晶粒平均长径比由3.79增加到4.86,弯曲强度、硬度及断裂韧性分别提高到1333 MPa、16.2 GPa、12.1 MPa·m1/2,断裂表面能也明显提高。OPS试样晶粒表面观察到了明显的形变条纹和位错运动区域。振荡压力的引入提高了致密化速率和晶粒的生长驱动力,且能够促进氮化硅在致密化过程中塑性形变的产生,有效加快了烧结致密化进程。

, authors=韩耀1, 李海燕2, 谢志鹏3, 王华栋1, 董衡1, 孙志强1, 张冰清1, 张剑1, 吕毅1, authorsList=韩耀, 李海燕, 谢志鹏, 王华栋, 董衡, 孙志强, 张冰清, 张剑, 吕毅, authorCompany=null, correspAuthors=null, authorNote=

韩耀(1990—),男,博士,工程师。

韩耀,航天特种材料及工艺技术研究所工程师,博士。先后参与和主持科技部“国家重点研发科技课题”、国家自然科学基金重大仪器科研仪器专项、面上项目、青年基金项目以及国防科工局等科研课题10余项。在国内外学术刊物发表研究论文20余篇,国内外会议宣读展示论文6篇,其中SCI收录论文18篇,申请专利10项,已授权专利3项。主要研究方向为新型烧结技术、高性能结构陶瓷、纤维增强陶瓷基透波材料、热结构陶瓷基复合材料、纳米粉体。研究项目包括:新型振荡压力烧结技术制备高性能结构陶瓷及其致密化机理研究、耐高温纤维增强陶瓷基透波材料的结构设计与一体化研究、高性能氮化铝粉体的合成制备技术研究、低密度高热导率多孔材料的结构设计优化研究。

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HAN Yao (1990-), male, Ph.D., Engineer. E-mail:

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韩耀,航天特种材料及工艺技术研究所工程师,博士。先后参与和主持科技部“国家重点研发科技课题”、国家自然科学基金重大仪器科研仪器专项、面上项目、青年基金项目以及国防科工局等科研课题10余项。在国内外学术刊物发表研究论文20余篇,国内外会议宣读展示论文6篇,其中SCI收录论文18篇,申请专利10项,已授权专利3项。主要研究方向为新型烧结技术、高性能结构陶瓷、纤维增强陶瓷基透波材料、热结构陶瓷基复合材料、纳米粉体。研究项目包括:新型振荡压力烧结技术制备高性能结构陶瓷及其致密化机理研究、耐高温纤维增强陶瓷基透波材料的结构设计与一体化研究、高性能氮化铝粉体的合成制备技术研究、低密度高热导率多孔材料的结构设计优化研究。

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韩耀,航天特种材料及工艺技术研究所工程师,博士。先后参与和主持科技部“国家重点研发科技课题”、国家自然科学基金重大仪器科研仪器专项、面上项目、青年基金项目以及国防科工局等科研课题10余项。在国内外学术刊物发表研究论文20余篇,国内外会议宣读展示论文6篇,其中SCI收录论文18篇,申请专利10项,已授权专利3项。主要研究方向为新型烧结技术、高性能结构陶瓷、纤维增强陶瓷基透波材料、热结构陶瓷基复合材料、纳米粉体。研究项目包括:新型振荡压力烧结技术制备高性能结构陶瓷及其致密化机理研究、耐高温纤维增强陶瓷基透波材料的结构设计与一体化研究、高性能氮化铝粉体的合成制备技术研究、低密度高热导率多孔材料的结构设计优化研究。

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振荡压力对高性能氮化硅陶瓷烧结致密化的影响
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韩耀 1 , 李海燕 2 , 谢志鹏 3 , 王华栋 1 , 董衡 1 , 孙志强 1 , 张冰清 1 , 张剑 1 , 吕毅 1
硅酸盐学报 | 2021,49(4): 673-680
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硅酸盐学报 | 2021 , 49 (4) : 673 -680
振荡压力对高性能氮化硅陶瓷烧结致密化的影响
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HAN Yao (1990-), male, Ph.D., Engineer. E-mail:

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HAN Yao (1990-), male, Ph.D., Engineer. E-mail:

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韩耀,航天特种材料及工艺技术研究所工程师,博士。先后参与和主持科技部“国家重点研发科技课题”、国家自然科学基金重大仪器科研仪器专项、面上项目、青年基金项目以及国防科工局等科研课题10余项。在国内外学术刊物发表研究论文20余篇,国内外会议宣读展示论文6篇,其中SCI收录论文18篇,申请专利10项,已授权专利3项。主要研究方向为新型烧结技术、高性能结构陶瓷、纤维增强陶瓷基透波材料、热结构陶瓷基复合材料、纳米粉体。研究项目包括:新型振荡压力烧结技术制备高性能结构陶瓷及其致密化机理研究、耐高温纤维增强陶瓷基透波材料的结构设计与一体化研究、高性能氮化铝粉体的合成制备技术研究、低密度高热导率多孔材料的结构设计优化研究。

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韩耀,航天特种材料及工艺技术研究所工程师,博士。先后参与和主持科技部“国家重点研发科技课题”、国家自然科学基金重大仪器科研仪器专项、面上项目、青年基金项目以及国防科工局等科研课题10余项。在国内外学术刊物发表研究论文20余篇,国内外会议宣读展示论文6篇,其中SCI收录论文18篇,申请专利10项,已授权专利3项。主要研究方向为新型烧结技术、高性能结构陶瓷、纤维增强陶瓷基透波材料、热结构陶瓷基复合材料、纳米粉体。研究项目包括:新型振荡压力烧结技术制备高性能结构陶瓷及其致密化机理研究、耐高温纤维增强陶瓷基透波材料的结构设计与一体化研究、高性能氮化铝粉体的合成制备技术研究、低密度高热导率多孔材料的结构设计优化研究。

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韩耀1 , 李海燕2, 谢志鹏3, 王华栋1, 董衡1, 孙志强1, 张冰清1, 张剑1, 吕毅1
作者信息
  • 1.航天特种材料及工艺技术研究所,北京 100074
  • 2.中国建材检验认证集团股份有限公司,北京 100024
  • 3.清华大学,新型陶瓷与精细工艺国家重点实验室,北京 100084
作者简介:

韩耀(1990—),男,博士,工程师。

韩耀,航天特种材料及工艺技术研究所工程师,博士。先后参与和主持科技部“国家重点研发科技课题”、国家自然科学基金重大仪器科研仪器专项、面上项目、青年基金项目以及国防科工局等科研课题10余项。在国内外学术刊物发表研究论文20余篇,国内外会议宣读展示论文6篇,其中SCI收录论文18篇,申请专利10项,已授权专利3项。主要研究方向为新型烧结技术、高性能结构陶瓷、纤维增强陶瓷基透波材料、热结构陶瓷基复合材料、纳米粉体。研究项目包括:新型振荡压力烧结技术制备高性能结构陶瓷及其致密化机理研究、耐高温纤维增强陶瓷基透波材料的结构设计与一体化研究、高性能氮化铝粉体的合成制备技术研究、低密度高热导率多孔材料的结构设计优化研究。

Effect of Oscillatory Pressure on Sintering Densification of High Quality Silicon Nitride Ceramics
Yao HAN1 , Haiyan LI2, Zhipeng XIE3, Huadong WANG1, Heng DONG1, Zhiqiang SUN1, Bingqing ZHANG1, Jian ZHANG1, Yi LV1
Affiliations
  • 1.Aerospace Institute of Advanced Materials & Processing Technology, Beijing 100074, China
  • 2.China Building Material Test & Certification Group Co., Ltd, Beijing 100024, China
  • 3.State Key Laboratory of New Ceramics and Fine Processing, Tsinghua University, Beijing 100084, China
  • HAN Yao (1990-), male, Ph.D., Engineer. E-mail:

出版时间: 2021-04-20 doi: 10.14062/j.issn.0454-5648.20200636
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采用新型振荡压力烧结技术制备高性能氮化硅陶瓷,并对比热压烧结技术,研究了不同工艺下氮化硅陶瓷的致密度、物相、晶粒尺寸、微观形貌及力学性能变化规律,分析了振荡压力对氮化硅陶瓷的致密化作用。结果表明:振荡压力烧结工艺下氮化硅陶瓷实现了α相到β相的物相完全转变,相对密度达到了99.82%;对比热压烧结工艺,振荡压力作用下氮化硅陶瓷的晶粒尺寸明显增加,晶粒平均长径比由3.79增加到4.86,弯曲强度、硬度及断裂韧性分别提高到1333 MPa、16.2 GPa、12.1 MPa·m1/2,断裂表面能也明显提高。OPS试样晶粒表面观察到了明显的形变条纹和位错运动区域。振荡压力的引入提高了致密化速率和晶粒的生长驱动力,且能够促进氮化硅在致密化过程中塑性形变的产生,有效加快了烧结致密化进程。

氮化硅  /  致密化  /  振荡压力  /  烧结  /  晶粒尺寸  /  微观结构

Oscillatory pressure sintering (OPS) technique was used to prepare silicon nitride ceramics with high quality. In comparison with hot pressure (HP) sintering process, the density, phase, grain size, aspect ratio and microstructure of silicon nitride ceramics by two methods were further investigated. The densification effect of oscillatory pressure on silicon nitride ceramics were studied. The results indicate that the silicon nitride ceramic has reached a complete phase transition from α phase to β phase under OPS process and its relative density has reached 99.82%. The grain sizes of OPS specimen are significantly increased compared with the specimen prepared by HP process. The average aspect ratio of the grains has increased from 3.79 to 4.86 when the fabricated process changed from HP to OPS. Bending strength, hardness and fracture toughness reached 1 333 MPa, 16.2 GPa, 12.1 MPa·m1/2, respectively. Fracture surface energy also increased with the introduction of oscillatory pressure. In addition, obvious deformation streaks and dislocation movement areas are observed through TEM analysis. Obviously, the application of oscillatory pressure improves the densification rate and the growth driving force of grains. The plastic deformation of silicon nitride during the densification process were also found. Thereby, the sintering densification process was accelerated.

silicon nitride  /  densification  /  oscillatory pressure  /  sintering  /  grain size  /  microstructure
韩耀, 李海燕, 谢志鹏, 王华栋, 董衡, 孙志强, 张冰清, 张剑, 吕毅. 振荡压力对高性能氮化硅陶瓷烧结致密化的影响. 硅酸盐学报, 2021 , 49 (4) : 673 -680 . DOI: 10.14062/j.issn.0454-5648.20200636
Yao HAN, Haiyan LI, Zhipeng XIE, Huadong WANG, Heng DONG, Zhiqiang SUN, Bingqing ZHANG, Jian ZHANG, Yi LV. Effect of Oscillatory Pressure on Sintering Densification of High Quality Silicon Nitride Ceramics[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (4) : 673 -680 . DOI: 10.14062/j.issn.0454-5648.20200636
  • 国家自然科学基金(5167020125)
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doi: 10.14062/j.issn.0454-5648.20200636
  • 接收时间:2020-08-23
  • 首发时间:2026-10-30
  • 出版时间:2021-04-20
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  • 收稿日期:2020-08-23
  • 修回日期:2020-11-18
基金
国家自然科学基金(5167020125)
作者信息
    1.航天特种材料及工艺技术研究所,北京 100074
    2.中国建材检验认证集团股份有限公司,北京 100024
    3.清华大学,新型陶瓷与精细工艺国家重点实验室,北京 100084
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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