Article(id=1322943270153757664, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200608, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1597507200000, receivedDateStr=2020-08-16, revisedDate=1600099200000, revisedDateStr=2020-09-15, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343854701, onlineDateStr=2026-10-30, pubDate=1624118400000, pubDateStr=2021-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343854701, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343854701, creator=13701087609, updateTime=1793343854701, updator=13701087609, issue=Issue{id=1322942627649303277, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='6', pageStart='1033', pageEnd='1246', issueExtLink='null', onlineDate='null', pubDate='1624118400000', pubDateStr='2021-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343701517, creator='13701087609', updateTime=1793345989266, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322952223231181603, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322952223231181604, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1151, endPage=1156, ext={EN=ArticleExt(id=1322943270321529825, articleId=1322943270153757664, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Structure and Optical-Electric Properties of VO2 Films Prepared by Annealing V Films, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Metal V films were prepared on quartz substrates via magnetron sputtering, and then converted to VO2 films via vacuum annealing. The effect of annealing temperature on the surface morphologies, crystalline structures, optical properties and electric properties of VO2 films was investigated. The results show that the crystallinity of the films increases with the increase of annealing temperature from 300℃ to 450℃. The films annealed at 400℃ and 450℃ are a pure monoclinic phase. The grains grow better and the grain boundaries are clear. The valent states of V element for different samples include +4 and +5 states. The presence of V5+ in the films is due to the oxidation in atmosphere. The annealing temperature has little effect on the visible transmittance, but the solar modulation efficiency increases. The metal-insulator transition (MIT) temperature and the resistance of semiconductor phase increase with increasing the annealing temperature. The resistance change amplitude across the MIT for the films annealed at 400℃ and 450℃ is more than 2 orders of magnitude. The hysteresis width and the MIT temperature of the film annealed at 450℃ are 14.6℃ and 61.0℃, respectively.

, authors=Wenhui YUAN1, Baoshun LIU2, authorsList=Wenhui YUAN, Baoshun LIU, authorCompany=null, correspAuthors=Baoshun LIU, authorNote=

YUAN Wenhui(1984-), male, Master, Senior Engineer. E-mail:

, correspAuthorsNote=
LIU Baoshun(1977-), male, Ph.D., Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322943270699017186, articleId=1322943270153757664, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=热处理V膜制备VO2薄膜的结构和光电性能, columnId=0, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

先用磁控溅射法在石英玻璃基片上制备了金属V膜,然后经过真空退火处理被转变为VO2薄膜。研究了退火温度对VO2薄膜表面形貌、晶体结构、光学性能和电学性能的影响。结果表明:随着退火温度由300℃增加到450℃,VO2薄膜的结晶度明显增加。退火温度在400℃和450℃制备的样品是高纯M相单斜结构,晶粒发育较好,晶界清晰。不同温度退火的样品的表面V元素包含由4+和5+态,5+态的出现是由于表面V元素受环境中氧化导致。虽然退火温度的改变对VO2薄膜的可见光透过率无明显影响,但是可以改善对太阳光的调节效率。VO2薄膜半导体-金属相变温度和半导体相的电阻随热处理温度增加而增加,在400℃和450℃退火样品电阻相变前后的变化幅度可达2个数量级,450℃退火制备样品的滞后宽度和半导体金属相变临界温度分别为14.6℃和61.0℃。

, authors=袁文辉1, 刘保顺2, authorsList=袁文辉, 刘保顺, authorCompany=null, correspAuthors=刘保顺, authorNote=

袁文辉(1984—),男,硕士,高级工程师。

, correspAuthorsNote=
刘保顺(1977—),男,博士,研究员。
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=lYQaSON+cYwfp5fvKVLwew==, magXml=jtvOCXRE9Eq/A78JSyCTdQ==, pdfUrl=null, pdf=jm6OneX6SDXlls3P1WM6Ow==, pdfFileSize=2970563, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=Y5Jy2T5lfxmOjb+BCOS7ZA==, mapNumber=null, fund=null)}, authors=[Author(id=1322943271177167851, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=110yuanwenhui@163.com, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322943272804557805, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, authorId=1322943271177167851, language=EN, stringName=Wenhui YUAN, firstName=Wenhui, middleName=null, lastName=YUAN, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.Wuhan Global Sensor Technology Co. Ltd., Wuhan 430205, China, bio={"content":"

YUAN Wenhui(1984-), male, Master, Senior Engineer. E-mail:

"}, bioImg=null, bioContent=

YUAN Wenhui(1984-), male, Master, Senior Engineer. E-mail:

, aboutCorrespAuthor=null), CN=AuthorExt(id=1322943272947164143, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, authorId=1322943271177167851, language=CN, stringName=袁文辉, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.武汉高芯科技有限公司,武汉 430205, bio={"content":"

袁文辉(1984—),男,硕士,高级工程师。

"}, bioImg=null, bioContent=

袁文辉(1984—),男,硕士,高级工程师。

, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322943270967452643, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, xref=1., ext=[AuthorCompanyExt(id=1322943270980035557, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, companyId=1322943270967452643, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.Wuhan Global Sensor Technology Co. Ltd., Wuhan 430205, China), AuthorCompanyExt(id=1322943270992618470, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, companyId=1322943270967452643, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.武汉高芯科技有限公司,武汉 430205)])]), Author(id=1322943273022661617, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, orderNo=1, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=bshliu@whut.edu.cn, emailSecond=null, emailThird=null, correspondingAuthor=1, authorType=1, ext={EN=AuthorExt(id=1322943273127519220, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, authorId=1322943273022661617, language=EN, stringName=Baoshun LIU, firstName=Baoshun, middleName=null, lastName=LIU, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2.State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322943273198822389, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, authorId=1322943273022661617, language=CN, stringName=刘保顺, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2.硅酸盐建筑材料国家重点实验室,武汉理工大学,武汉 430070, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322943271089087463, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, xref=2., ext=[AuthorCompanyExt(id=1322943271101670376, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, companyId=1322943271089087463, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China), AuthorCompanyExt(id=1322943271110058985, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, companyId=1322943271089087463, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.硅酸盐建筑材料国家重点实验室,武汉理工大学,武汉 430070)])])], keywords=[Keyword(id=1322943273316262902, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, language=EN, orderNo=1, keyword=vanadium dioxide films), Keyword(id=1322943273404343288, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, language=EN, orderNo=2, keyword=magnetron sputtering), Keyword(id=1322943273479840761, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, language=EN, orderNo=3, keyword=vacuum post-annealing), Keyword(id=1322943273546949626, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, language=EN, orderNo=4, keyword=semiconductor-metal transition), Keyword(id=1322943273622447099, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, language=CN, orderNo=1, keyword=二氧化钒薄膜), Keyword(id=1322943273693750268, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, language=CN, orderNo=2, keyword=磁控溅射), Keyword(id=1322943273781830654, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, language=CN, orderNo=3, keyword=真空退火), Keyword(id=1322943273853133823, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, language=CN, orderNo=4, keyword=半导体-金属相变)], refs=null, funds=[Fund(id=1322943273945408512, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, awardId=2017YFE0192600, language=CN, fundingSource=国家重点研发计划政府间国际科技创新合作重点专项(2017YFE0192600), fundOrder=null, country=null), Fund(id=1322943274020904960, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, awardId=51772230, language=CN, fundingSource=国家自然科学基金面上项目(51772230), fundOrder=null, country=null)], companyList=[AuthorCompany(id=1322943270967452643, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, xref=1., ext=[AuthorCompanyExt(id=1322943270980035557, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, companyId=1322943270967452643, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.Wuhan Global Sensor Technology Co. Ltd., Wuhan 430205, China), AuthorCompanyExt(id=1322943270992618470, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, companyId=1322943270967452643, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.武汉高芯科技有限公司,武汉 430205)]), AuthorCompany(id=1322943271089087463, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, xref=2., ext=[AuthorCompanyExt(id=1322943271101670376, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, companyId=1322943271089087463, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China), AuthorCompanyExt(id=1322943271110058985, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, companyId=1322943271089087463, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.硅酸盐建筑材料国家重点实验室,武汉理工大学,武汉 430070)])], figs=null, attaches=null, journal=Journal(id=1263186332462366751, delFlag=0, nameCn=硅酸盐学报, nameEn=Journal of the Chinese Ceramic Society, nameHistory1=null, nameHistory2=null, issn=0454-5648, eissn=null, cn=11-2310/TQ, coden=null, periodic=0, language=CN, oaType=null, ccby=null, superviseOffice=null, ownerOffice=null, pubOffice=null, editorOffice=null, officeType=null, aims=null, clcCode=null, officeProv=null, officeCity=null, officeAddr=null, officeZip=null, officeEmail=null, officePhone=null, editDirector=null, officeDirector=null, officeDirectorPhone=null, officeStaffNum=null, officeEmpNum=null, coverPicUrl=8Qg1+Is+LeRD1Lv6UJcXRg==, journalPrice=null, startedYear=null, abbrevIsoEn=Journal of the Chinese Ceramic Society, journalRemark=null, publicationField=null, createdTime=1779096690528, updatedTime=1788951192520, createdBy=18614031015, updatedBy=13041195026, firstLetterCn=G, firstLetterEn=G, subjectCode=Engineering, subjectName=null, subjectCodeEn=Engineering, subjectNameEn=null, picCn=8Qg1+Is+LeRD1Lv6UJcXRg==, picEn=AY9tl+TwuKtB81GF+w4WAg==, jcr=null, cjcr=null, exts=[JournalExt(id=1304519110767960749, language=CN, name=硅酸盐学报, nameHistory1=null, nameHistory2=null, managedBy=, sponsoredBy=, publishedBy=, editorOffice=, officeProv=null, officeCity=null, officeAddr=, officeZip=, editDirector=, officeDirector=null, officePhone=null, coverPicUrl=null, journalRemark=, submitArticleUrl=null, websiteUrl=, createdTime=1788951192800, updatedTime=1788951192800, createdBy=13041195026, updatedBy=13041195026, submissionGuidelinesUrl=, submissionAuthorUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=1, submissionEditorUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=3, submissionReviewUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=2, submissionCeEditorUrl=, submissionAeEditorUrl=, option={"copyright":""}), JournalExt(id=1304519110839263918, language=EN, name=Journal of the Chinese Ceramic Society, nameHistory1=null, nameHistory2=null, managedBy=, sponsoredBy=, publishedBy=, editorOffice=, officeProv=null, officeCity=null, officeAddr=, officeZip=, editDirector=, officeDirector=null, officePhone=null, coverPicUrl=null, journalRemark=, submitArticleUrl=null, websiteUrl=, createdTime=1788951192817, updatedTime=1788951192817, createdBy=13041195026, updatedBy=13041195026, submissionGuidelinesUrl=, submissionAuthorUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=1, submissionEditorUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=3, submissionReviewUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=2, submissionCeEditorUrl=, submissionAeEditorUrl=, option={"copyright":""})], databaseList=null, tenantJournalId=1263187385517883426, websiteList=[Website(id=1263188159895093557, webName=null, webTitle=null, webDomain=null, webCopyrigh=null, webIpcNo=null, seoTitle=null, seoKeywords=null, seoDescription=null, tenantJournalId=null, journalId=1263187385517883426, journalNameCn=null, journalNameEn=null, grayFlag=null, tenantId=1146029695717560320, platformId=null, journalGroupId=null, journalGroupNameCn=null, journalGroupNameEn=null, type=1, domain=https://castjournals.cast.org.cn/joweb/gsyxb/CN, language=CN, createTime=1779097126220, createBy=18614031015, updateTime=1779097837121, updateBy=18614031015, name=硅酸盐学报-中文, tplId=1146099689490845704, title=硅酸盐学报, delFlag=0, indexPage=/home, props=[WebsiteProps(id=1263191261578649862, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=articleTextType, value=kx, createTime=1779097865719, updateTime=1779097865719, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261545095427, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=banner, value=null, createTime=1779097865711, updateTime=1779097865711, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261599621385, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=grayFlag, value=0, createTime=1779097865724, updateTime=1779097865724, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261532512514, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=logo, value=https://castjournals.cast.org.cn/joweb/gsyxb/CN/file/pic?fileId=Oqq9gXZG0JiYeHvLNwX/eg==, createTime=1779097865708, updateTime=1779097865708, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261620592907, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=minRunFlag, value=0, createTime=1779097865729, updateTime=1779097865729, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261574455557, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=picServerUrl, value=https://castjournals.cast.org.cn/joweb/gsyxb/CN/file/pic, createTime=1779097865718, updateTime=1779097865718, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261616398602, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=silenceFlag, value=0, createTime=1779097865728, updateTime=1779097865728, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261566066948, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=staticResourcePath, value=https://castjournals.cast.org.cn/joweb/cast_kjdb_cn_619/, createTime=1779097865716, updateTime=1779097865716, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261587038471, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=themeColor, value=null, createTime=1779097865721, updateTime=1779097865721, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261591232776, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=themeStyle, value=null, createTime=1779097865722, updateTime=1779097865722, creator=18614031015, updator=18614031015)]), Website(id=1263188160188694841, webName=null, webTitle=null, webDomain=null, webCopyrigh=null, webIpcNo=null, seoTitle=null, seoKeywords=null, seoDescription=null, tenantJournalId=null, journalId=1263187385517883426, journalNameCn=null, journalNameEn=null, grayFlag=null, tenantId=1146029695717560320, platformId=null, journalGroupId=null, journalGroupNameCn=null, journalGroupNameEn=null, type=1, domain=https://castjournals.cast.org.cn/joweb/gsyxb/EN, language=EN, createTime=1779097126348, createBy=18614031015, updateTime=1779097825280, updateBy=18614031015, name=硅酸盐学报-英文, tplId=1146101810881728533, title=Journal of the Chinese Ceramic Society, delFlag=0, indexPage=/home, props=[WebsiteProps(id=1263191231102836987, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=articleTextType, value=kx, createTime=1779097858453, updateTime=1779097858453, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231052505336, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=banner, value=null, createTime=1779097858441, updateTime=1779097858441, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231186723070, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=grayFlag, value=0, createTime=1779097858473, updateTime=1779097858473, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231039922423, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=logo, value=https://castjournals.cast.org.cn/joweb/gsyxb/EN/file/pic?fileId=Oqq9gXZG0JiYeHvLNwX/eg==, createTime=1779097858438, updateTime=1779097858438, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231358689536, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=minRunFlag, value=0, createTime=1779097858514, updateTime=1779097858514, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231094448378, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=picServerUrl, value=https://castjournals.cast.org.cn/joweb/gsyxb/EN/file/pic, createTime=1779097858451, updateTime=1779097858451, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231195111679, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=silenceFlag, value=0, createTime=1779097858475, updateTime=1779097858475, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231086059769, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=staticResourcePath, value=https://castjournals.cast.org.cn/joweb/cast_kjdb_en_623/, createTime=1779097858449, updateTime=1779097858449, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231111225596, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=themeColor, value=null, createTime=1779097858455, updateTime=1779097858455, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231144780029, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=themeStyle, value=null, createTime=1779097858463, updateTime=1779097858463, creator=18614031015, updator=18614031015)])], journalTitle=硅酸盐学报, weixinUrl=null, journalUrl=https://jccsoc.cbpt.cnki.net/, iacademicId=null, status=1, seqNo=null, journalTitleEn=Journal of the Chinese Ceramic Society, journalPhotoCn=8Qg1+Is+LeRD1Lv6UJcXRg==, journalPhotoEn=AY9tl+TwuKtB81GF+w4WAg==, journalFirstLetter=G, journalRecommend=null, journalNew=null, journalCollection=null, jcrJf=null, cjcrJf=null, jcrJfStr=null, cjcrJfStr=null, submissionFirstDecision=null, sciSubjectClassification=null, casSubjectClassification=null, citeScore=null, totalCitationFrequency=null, icpCode=null, psCode=null, advertisingLicenseCode=null, copyrightInformation=null, country=null, option=, provinceCode=null, provinceName=null, collectFlag=false, interPubPlatform=, interPubPlatformUrl=null), detailUrlCn=https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20200608, detailUrlEn=https://castjournals.cast.org.cn/joweb/gsyxb/EN/10.14062/j.issn.0454-5648.20200608, pdfUrlCn=https://castjournals.cast.org.cn/joweb/gsyxb/CN/PDF/10.14062/j.issn.0454-5648.20200608, pdfUrlEn=https://castjournals.cast.org.cn/joweb/gsyxb/EN/PDF/10.14062/j.issn.0454-5648.20200608, aliStartDate=0, aliEndDate=0, collectionFlag=false, citedCount=null, citedUrl=null, previewStatus=0, delFlag=0, hasFullText=0, orderTime=1624118400000, fullTextJson=null, articleText=null, reference=null)
收藏切换
热处理V膜制备VO2薄膜的结构和光电性能
收藏切换
PDF下载
袁文辉 1 , 刘保顺 2
硅酸盐学报 | 2021,49(6): 1151-1156
收起
收藏切换
硅酸盐学报 | 2021 , 49 (6) : 1151 -1156
热处理V膜制备VO2薄膜的结构和光电性能
全屏
[Author(id=1322943271177167851, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=110yuanwenhui@163.com, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322943272804557805, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, authorId=1322943271177167851, language=EN, stringName=Wenhui YUAN, firstName=Wenhui, middleName=null, lastName=YUAN, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.Wuhan Global Sensor Technology Co. Ltd., Wuhan 430205, China, bio={"content":"

YUAN Wenhui(1984-), male, Master, Senior Engineer. E-mail:

"}, bioImg=null, bioContent=

YUAN Wenhui(1984-), male, Master, Senior Engineer. E-mail:

, aboutCorrespAuthor=null), CN=AuthorExt(id=1322943272947164143, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, authorId=1322943271177167851, language=CN, stringName=袁文辉, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.武汉高芯科技有限公司,武汉 430205, bio={"content":"

袁文辉(1984—),男,硕士,高级工程师。

"}, bioImg=null, bioContent=

袁文辉(1984—),男,硕士,高级工程师。

, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322943270967452643, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, xref=1., ext=[AuthorCompanyExt(id=1322943270980035557, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, companyId=1322943270967452643, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.Wuhan Global Sensor Technology Co. Ltd., Wuhan 430205, China), AuthorCompanyExt(id=1322943270992618470, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, companyId=1322943270967452643, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.武汉高芯科技有限公司,武汉 430205)])]), Author(id=1322943273022661617, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, orderNo=1, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=bshliu@whut.edu.cn, emailSecond=null, emailThird=null, correspondingAuthor=1, authorType=1, ext={EN=AuthorExt(id=1322943273127519220, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, authorId=1322943273022661617, language=EN, stringName=Baoshun LIU, firstName=Baoshun, middleName=null, lastName=LIU, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2.State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322943273198822389, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, authorId=1322943273022661617, language=CN, stringName=刘保顺, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2.硅酸盐建筑材料国家重点实验室,武汉理工大学,武汉 430070, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322943271089087463, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, xref=2., ext=[AuthorCompanyExt(id=1322943271101670376, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, companyId=1322943271089087463, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China), AuthorCompanyExt(id=1322943271110058985, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322943270153757664, companyId=1322943271089087463, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.硅酸盐建筑材料国家重点实验室,武汉理工大学,武汉 430070)])])]
袁文辉1 , 刘保顺2
作者信息
  • 1.武汉高芯科技有限公司,武汉 430205
  • 2.硅酸盐建筑材料国家重点实验室,武汉理工大学,武汉 430070
通讯作者:
刘保顺(1977—),男,博士,研究员。
作者简介:

袁文辉(1984—),男,硕士,高级工程师。

Structure and Optical-Electric Properties of VO2 Films Prepared by Annealing V Films
Wenhui YUAN1 , Baoshun LIU2
Affiliations
  • 1.Wuhan Global Sensor Technology Co. Ltd., Wuhan 430205, China
  • 2.State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China
  • Corresponding Author:
    LIU Baoshun(1977-), male, Ph.D., Professor. E-mail:

    YUAN Wenhui(1984-), male, Master, Senior Engineer. E-mail:

出版时间: 2021-06-20 doi: 10.14062/j.issn.0454-5648.20200608
文章导航
收藏切换

先用磁控溅射法在石英玻璃基片上制备了金属V膜,然后经过真空退火处理被转变为VO2薄膜。研究了退火温度对VO2薄膜表面形貌、晶体结构、光学性能和电学性能的影响。结果表明:随着退火温度由300℃增加到450℃,VO2薄膜的结晶度明显增加。退火温度在400℃和450℃制备的样品是高纯M相单斜结构,晶粒发育较好,晶界清晰。不同温度退火的样品的表面V元素包含由4+和5+态,5+态的出现是由于表面V元素受环境中氧化导致。虽然退火温度的改变对VO2薄膜的可见光透过率无明显影响,但是可以改善对太阳光的调节效率。VO2薄膜半导体-金属相变温度和半导体相的电阻随热处理温度增加而增加,在400℃和450℃退火样品电阻相变前后的变化幅度可达2个数量级,450℃退火制备样品的滞后宽度和半导体金属相变临界温度分别为14.6℃和61.0℃。

二氧化钒薄膜  /  磁控溅射  /  真空退火  /  半导体-金属相变

Metal V films were prepared on quartz substrates via magnetron sputtering, and then converted to VO2 films via vacuum annealing. The effect of annealing temperature on the surface morphologies, crystalline structures, optical properties and electric properties of VO2 films was investigated. The results show that the crystallinity of the films increases with the increase of annealing temperature from 300℃ to 450℃. The films annealed at 400℃ and 450℃ are a pure monoclinic phase. The grains grow better and the grain boundaries are clear. The valent states of V element for different samples include +4 and +5 states. The presence of V5+ in the films is due to the oxidation in atmosphere. The annealing temperature has little effect on the visible transmittance, but the solar modulation efficiency increases. The metal-insulator transition (MIT) temperature and the resistance of semiconductor phase increase with increasing the annealing temperature. The resistance change amplitude across the MIT for the films annealed at 400℃ and 450℃ is more than 2 orders of magnitude. The hysteresis width and the MIT temperature of the film annealed at 450℃ are 14.6℃ and 61.0℃, respectively.

vanadium dioxide films  /  magnetron sputtering  /  vacuum post-annealing  /  semiconductor-metal transition
袁文辉, 刘保顺. 热处理V膜制备VO2薄膜的结构和光电性能. 硅酸盐学报, 2021 , 49 (6) : 1151 -1156 . DOI: 10.14062/j.issn.0454-5648.20200608
Wenhui YUAN, Baoshun LIU. Structure and Optical-Electric Properties of VO2 Films Prepared by Annealing V Films[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (6) : 1151 -1156 . DOI: 10.14062/j.issn.0454-5648.20200608
  • 国家重点研发计划政府间国际科技创新合作重点专项(2017YFE0192600)
  • 国家自然科学基金面上项目(51772230)
参考文献 引证文献
排序方式:
2021年第49卷第6期
PDF下载
19
6
引用本文
BibTeX
文章信息
doi: 10.14062/j.issn.0454-5648.20200608
  • 接收时间:2020-08-16
  • 首发时间:2026-10-30
  • 出版时间:2021-06-20
补充材料
相关文章
文章信息
作者
出版历史
  • 收稿日期:2020-08-16
  • 修回日期:2020-09-15
基金
国家重点研发计划政府间国际科技创新合作重点专项(2017YFE0192600)
国家自然科学基金面上项目(51772230)
作者信息
    1.武汉高芯科技有限公司,武汉 430205
    2.硅酸盐建筑材料国家重点实验室,武汉理工大学,武汉 430070

通讯作者:

刘保顺(1977—),男,博士,研究员。
参考文献
分享链接
https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20200608
分享至
全文二维码

扫描看全文

引用本文
BibTeX
本文的引用情况
2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
关闭全屏