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Article(id=1322943158719488112, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942592224211277, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200578, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1596729600000, receivedDateStr=2020-08-07, revisedDate=1598716800000, revisedDateStr=2020-08-30, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343828134, onlineDateStr=2026-10-30, pubDate=1621440000000, pubDateStr=2021-05-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343828134, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343828134, creator=13701087609, updateTime=1793343828134, updator=13701087609, issue=Issue{id=1322942592224211277, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='5', pageStart='807', pageEnd='1032', issueExtLink='null', onlineDate='null', pubDate='1621440000000', pubDateStr='2021-05-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343693071, creator='13701087609', updateTime=1793345545174, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322950360561754466, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942592224211277, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322950360565948771, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942592224211277, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=939, endPage=947, ext={EN=ArticleExt(id=1322943158937591921, articleId=1322943158719488112, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Corrosion Inhibition Effect of Perimidine Derivatives Corrosion Inhibitor on Rebar in Simulated Concrete Pore Solutions, columnId=1319726165087077079, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Article, runingTitle=null, highlight=null, articleAbstract=

1H-perimidine (PED) and 2-hydroxy-1H-perimidine (HPED) were prepared as corrosion inhibitors for HRB400 reinforced steel in simulated concrete pore solution. The corrosion inhibition performance and adsorption mechanism were investigated via dry and wet cycle experiments, scanning electron microscopy, electrochemical impedance spectroscopy and related theoretical calculations. The results show that the inhibition efficiencies of these compounds are more than 80% for HRB400 reinforced steel in SCP at a concentration of less than 0.12 mmol/L. Moreover, HPED functions as a more effective inhibitor rather than PED due to the presence of 2-position hydroxyl-group. In addition, the inhibitor molecules spontaneously adsorb onto reinforced steel surfaces to form a protective film, and the adsorption process follows the Langmuir isothermal model.

, authors=Qi MA1, 2, Jingshun CAI1, 2, Song MU1, 2, Xiaocheng ZHOU1, 2, Jianzhong LIU1, 2, Jinxiang HONG1, 2, Jiaping LIU1, 2, 3, authorsList=Qi MA, Jingshun CAI, Song MU, Xiaocheng ZHOU, Jianzhong LIU, Jinxiang HONG, Jiaping LIU, authorCompany=null, correspAuthors=Song MU, authorNote=

MA Qi (1991-), male, Master, Assistant Engineer. E-mail:

, correspAuthorsNote=
MU Song (1982-), male, Ph.D., Senior Engineer. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322943159264747634, articleId=1322943158719488112, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=混凝土模拟孔隙液中呸啶衍生物对钢筋的阻锈性能与机制, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

制备了1H-呸啶（PED）和2-羟基-1H-呸啶（HPED），并研究了其在混凝土模拟孔隙液中对HRB400钢筋的阻锈作用。采用干湿循环试验、扫描电子显微镜、电化学阻抗谱以及量子化学方法研究其阻锈性能和在钢筋表面的吸附机理。结果表明：当呸啶衍生物浓度为0.12 mmol/L时，其在混凝土模拟孔隙液中对钢筋的阻锈效率均超过80%。此外，2-羟基-1H-呸啶结构中的2位含有羟基基团，所以HPED对钢筋的阻锈效果优于PED。而且，通过吸附等温线研究表明，呸啶衍生物能自发的吸附在金属表面，且吸附过程遵循Langmuir吸附。

, authors=马麒1, 2, 蔡景顺1, 2, 穆松1, 2, 周霄骋1, 2, 刘建忠1, 2, 洪锦祥1, 2, 刘加平1, 2, 3, authorsList=马麒, 蔡景顺, 穆松, 周霄骋, 刘建忠, 洪锦祥, 刘加平, authorCompany=null, correspAuthors=穆松, authorNote=

马麒（1991—），男，硕士，助理工程师。

, correspAuthorsNote=
穆松（1982—），男，博士，高级工程师。
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MA Qi (1991-), male, Master, Assistant Engineer. E-mail:

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混凝土模拟孔隙液中呸啶衍生物对钢筋的阻锈性能与机制
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马麒 1, 2 , 蔡景顺 1, 2 , 穆松 1, 2 , 周霄骋 1, 2 , 刘建忠 1, 2 , 洪锦祥 1, 2 , 刘加平 1, 2, 3
硅酸盐学报 | 研究论文 2021,49(5): 939-947
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硅酸盐学报 |研究论文 2021 , 49 (5) : 939 -947
混凝土模拟孔隙液中呸啶衍生物对钢筋的阻锈性能与机制
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马麒1, 2 , 蔡景顺1, 2, 穆松1, 2 , 周霄骋1, 2, 刘建忠1, 2, 洪锦祥1, 2, 刘加平1, 2, 3
作者信息
  • 1．高性能土木工程材料国家重点实验室，江苏省建筑科学研究院有限公司，南京，211103
  • 2．江苏苏博特新材料股份有限公司，南京 211103
  • 3．材料科学与工程学院，东南大学，南京 211189
通讯作者:
穆松（1982—），男，博士，高级工程师。
作者简介:

马麒（1991—），男，硕士，助理工程师。

Corrosion Inhibition Effect of Perimidine Derivatives Corrosion Inhibitor on Rebar in Simulated Concrete Pore Solutions
Qi MA1, 2 , Jingshun CAI1, 2, Song MU1, 2 , Xiaocheng ZHOU1, 2, Jianzhong LIU1, 2, Jinxiang HONG1, 2, Jiaping LIU1, 2, 3
Affiliations
  • 1.State Key Laboratory of High Performance Civil Engineering Materials, Jiangsu Research Institute of Building Science Co., Ltd., Nanjing 211103, China
  • 2.Jiangsu Sobute New Materials Co., Ltd., Nanjing 211103, China
  • 3.School of Materials Science and Engineering, Southeast University, Nanjing 211189, China
    • Corresponding Author:
    MU Song (1982-), male, Ph.D., Senior Engineer. E-mail:

    MA Qi (1991-), male, Master, Assistant Engineer. E-mail:

出版时间: 2021-05-20 doi: 10.14062/j.issn.0454-5648.20200578
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制备了1H-呸啶（PED）和2-羟基-1H-呸啶（HPED），并研究了其在混凝土模拟孔隙液中对HRB400钢筋的阻锈作用。采用干湿循环试验、扫描电子显微镜、电化学阻抗谱以及量子化学方法研究其阻锈性能和在钢筋表面的吸附机理。结果表明：当呸啶衍生物浓度为0.12 mmol/L时，其在混凝土模拟孔隙液中对钢筋的阻锈效率均超过80%。此外，2-羟基-1H-呸啶结构中的2位含有羟基基团，所以HPED对钢筋的阻锈效果优于PED。而且，通过吸附等温线研究表明，呸啶衍生物能自发的吸附在金属表面，且吸附过程遵循Langmuir吸附。

呸啶衍生物  /  混凝土  /  模拟  /  孔隙液  /  钢筋  /  阻锈剂  /  耐久性

1H-perimidine (PED) and 2-hydroxy-1H-perimidine (HPED) were prepared as corrosion inhibitors for HRB400 reinforced steel in simulated concrete pore solution. The corrosion inhibition performance and adsorption mechanism were investigated via dry and wet cycle experiments, scanning electron microscopy, electrochemical impedance spectroscopy and related theoretical calculations. The results show that the inhibition efficiencies of these compounds are more than 80% for HRB400 reinforced steel in SCP at a concentration of less than 0.12 mmol/L. Moreover, HPED functions as a more effective inhibitor rather than PED due to the presence of 2-position hydroxyl-group. In addition, the inhibitor molecules spontaneously adsorb onto reinforced steel surfaces to form a protective film, and the adsorption process follows the Langmuir isothermal model.

perimidine derivatives  /  concrete  /  simulated  /  pore solution  /  reinforced steel  /  inhibitors  /  durability
马麒, 蔡景顺, 穆松, 周霄骋, 刘建忠, 洪锦祥, 刘加平. 混凝土模拟孔隙液中呸啶衍生物对钢筋的阻锈性能与机制. 硅酸盐学报, 2021 , 49 (5) : 939 -947 . DOI: 10.14062/j.issn.0454-5648.20200578
Qi MA, Jingshun CAI, Song MU, Xiaocheng ZHOU, Jianzhong LIU, Jinxiang HONG, Jiaping LIU. Corrosion Inhibition Effect of Perimidine Derivatives Corrosion Inhibitor on Rebar in Simulated Concrete Pore Solutions[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (5) : 939 -947 . DOI: 10.14062/j.issn.0454-5648.20200578
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  • 国家自然科学基金(52078240)
  • 广东省重点领域研发计划(2019B111106002)
  • 国家自然科学基金(51908254)
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doi: 10.14062/j.issn.0454-5648.20200578
  • 接收时间：2020-08-07
  • 首发时间：2026-10-30
  • 出版时间：2021-05-20
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  • 收稿日期：2020-08-07
  • 修回日期：2020-08-30
基金
国家自然科学基金(52078240)
广东省重点领域研发计划(2019B111106002)
国家自然科学基金(51908254)
作者信息
    1．高性能土木工程材料国家重点实验室，江苏省建筑科学研究院有限公司，南京，211103
    2．江苏苏博特新材料股份有限公司，南京 211103
    3．材料科学与工程学院，东南大学，南京 211189

通讯作者:

穆松（1982—），男，博士，高级工程师。
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2种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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