Article(id=1322943163459043392, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942495801356913, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200575, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1596470400000, receivedDateStr=2020-08-04, revisedDate=1597766400000, revisedDateStr=2020-08-19, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343829263, onlineDateStr=2026-10-30, pubDate=1616169600000, pubDateStr=2021-03-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343829263, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343829263, creator=13701087609, updateTime=1793343829263, updator=13701087609, issue=Issue{id=1322942495801356913, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='3', pageStart='441', pageEnd='604', issueExtLink='null', onlineDate='null', pubDate='1616169600000', pubDateStr='2021-03-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343670081, creator='13701087609', updateTime=1793345495044, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322950150322258738, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942495801356913, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322950150322258739, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942495801356913, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=597, endPage=604, ext={EN=ArticleExt(id=1322943165132570690, articleId=1322943163459043392, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Microstructure and Thermoelectric Transport Behavior of ZrNiSn Material Synthesized by Non-Equilibrium Technology, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

ZrNiSn bulk thermoelectric materials were synthesized by a self-propagating high-temperature synthesis (SHS) process. Phases and microstructure of ZrNiSn were investigated. Its thermoelectric property was tested. The results show that there are a large number of nuclei and high concentration of dislocation groups and stress fluctuation area inside the dense material, greatly enhancing the phonon scattering and reducing the phonon mean free paths, thus leading to the decreased lattice thermal conductivity of the materials. The thermoelectric properties of the material were optimized, and the ZT value is 0.54 at 873 K.

, authors=Dongwang YANG1, Tingting LUO1, 2, Xianli SU1, Yonggao YAN1, Xinfeng TANG1, authorsList=Dongwang YANG, Tingting LUO, Xianli SU, Yonggao YAN, Xinfeng TANG, authorCompany=null, correspAuthors=Xinfeng TANG, authorNote=

YANG Dongwang (1989-), male, Ph.D. E-mail:

, correspAuthorsNote=
TANG Xinfeng (1962-), male, Ph.D., Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322943167183585347, articleId=1322943163459043392, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=快速非平衡技术制备ZrNiSn及其纳微结构与热电性能, columnId=0, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

利用外加引火剂的自蔓延高温合成(SHS)反应形成的“化学反应加热炉”引发ZrNiSn的SHS反应,在反应物坯体处于红热软化状态下快速加压制备得到致密的ZrNiSn块体。对材料物相及微结构进行表征,并对热电性能进行测试。结果表明:ZrNiSn内部存在大量纳米晶核和高浓度位错群及应力起伏区,极大地增强了声子散射,显著减小了声子平均自由程,进而降低了晶格热导率,并且热电性能得到优化,在873 K时,ZT值为0.54。

, authors=杨东旺1, 罗婷婷1, 2, 苏贤礼1, 鄢永高1, 唐新峰1, authorsList=杨东旺, 罗婷婷, 苏贤礼, 鄢永高, 唐新峰, authorCompany=null, correspAuthors=唐新峰, authorNote=

杨东旺(1989—),男,博士。

, correspAuthorsNote=
唐新峰(1962—),男,博士,教授。
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快速非平衡技术制备ZrNiSn及其纳微结构与热电性能
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杨东旺 1 , 罗婷婷 1, 2 , 苏贤礼 1 , 鄢永高 1 , 唐新峰 1
硅酸盐学报 | 2021,49(3): 597-604
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硅酸盐学报 | 2021 , 49 (3) : 597 -604
快速非平衡技术制备ZrNiSn及其纳微结构与热电性能
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杨东旺1 , 罗婷婷1, 2, 苏贤礼1, 鄢永高1, 唐新峰1
作者信息
  • 1.材料复合新技术国家重点实验室,武汉 430070
  • 2.武汉理工大学材料研究与测试中心,武汉 430070
通讯作者:
唐新峰(1962—),男,博士,教授。
作者简介:

杨东旺(1989—),男,博士。

Microstructure and Thermoelectric Transport Behavior of ZrNiSn Material Synthesized by Non-Equilibrium Technology
Dongwang YANG1 , Tingting LUO1, 2, Xianli SU1, Yonggao YAN1, Xinfeng TANG1
Affiliations
  • 1.State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan 430070, China
  • 2.Materials Research and Test Center of Wuhan University of Technology, Wuhan 430070, China
  • Corresponding Author:
    TANG Xinfeng (1962-), male, Ph.D., Professor. E-mail:

    YANG Dongwang (1989-), male, Ph.D. E-mail:

出版时间: 2021-03-20 doi: 10.14062/j.issn.0454-5648.20200575
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利用外加引火剂的自蔓延高温合成(SHS)反应形成的“化学反应加热炉”引发ZrNiSn的SHS反应,在反应物坯体处于红热软化状态下快速加压制备得到致密的ZrNiSn块体。对材料物相及微结构进行表征,并对热电性能进行测试。结果表明:ZrNiSn内部存在大量纳米晶核和高浓度位错群及应力起伏区,极大地增强了声子散射,显著减小了声子平均自由程,进而降低了晶格热导率,并且热电性能得到优化,在873 K时,ZT值为0.54。

化学炉  /  自蔓延高温合成  /  half-Heusler合金  /  缺陷  /  热电

ZrNiSn bulk thermoelectric materials were synthesized by a self-propagating high-temperature synthesis (SHS) process. Phases and microstructure of ZrNiSn were investigated. Its thermoelectric property was tested. The results show that there are a large number of nuclei and high concentration of dislocation groups and stress fluctuation area inside the dense material, greatly enhancing the phonon scattering and reducing the phonon mean free paths, thus leading to the decreased lattice thermal conductivity of the materials. The thermoelectric properties of the material were optimized, and the ZT value is 0.54 at 873 K.

chemical furnace  /  self-propagating high-temperature synthesis  /  half-Heusler alloy  /  defect  /  thermoelectric
杨东旺, 罗婷婷, 苏贤礼, 鄢永高, 唐新峰. 快速非平衡技术制备ZrNiSn及其纳微结构与热电性能. 硅酸盐学报, 2021 , 49 (3) : 597 -604 . DOI: 10.14062/j.issn.0454-5648.20200575
Dongwang YANG, Tingting LUO, Xianli SU, Yonggao YAN, Xinfeng TANG. Microstructure and Thermoelectric Transport Behavior of ZrNiSn Material Synthesized by Non-Equilibrium Technology[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (3) : 597 -604 . DOI: 10.14062/j.issn.0454-5648.20200575
  • 国家自然科学基金重点项目(复合热电材料的界面调控与电热输运)(51632006)
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2021年第49卷第3期
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doi: 10.14062/j.issn.0454-5648.20200575
  • 接收时间:2020-08-04
  • 首发时间:2026-10-30
  • 出版时间:2021-03-20
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  • 收稿日期:2020-08-04
  • 修回日期:2020-08-19
基金
国家自然科学基金重点项目(复合热电材料的界面调控与电热输运)(51632006)
作者信息
    1.材料复合新技术国家重点实验室,武汉 430070
    2.武汉理工大学材料研究与测试中心,武汉 430070

通讯作者:

唐新峰(1962—),男,博士,教授。
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20200575
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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