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High-temperature electrolysis via a solid oxide electrolysis cell (SOEC) is considered as one of the most potential energy conversion and storage technologies due to its high energy conversion efficiency, modularization and easy assembly, and flexible application. Methane-assisted SOEC mode, which combines the state-of-the-art SOEC system with partial oxidation of methane (POM) reaction, was used to effectively reduce the energy consumption and produce a high-quality synthesized gas (i.e., a mixture of CO and H₂). This novel SOEC mode can utilize different energy networks including electricity, heat and gas, which can efficiently and flexibly transform different energies and realize the optimal utilization of energies and resources. This review represented recent developments on methane-assisted SOEC mode. The thermodynamic parameters, the Nernst potential, electrochemical performance, products compositions as well as energy structure and efficiency of methane-assisted SOEC mode were summarized. In addition, the research status of the electrode system for methane-assisted SOEC mode was also reviewed, and the future prospects of methane-assisted SOEC mode were discussed.

, authors=Yao WANG, Tong LIU, authorsList=Yao WANG, Tong LIU, authorCompany=null, correspAuthors=Tong LIU, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322942998564184941, articleId=1322942997914067819, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=甲烷辅助高温电解制氢气和合成气, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

基于固体氧化物电解池（SOEC）的高温电解技术具有能量转换效率高、模块化易组装、应用灵活等优点，是一种极具应用前景的能量转化和存储技术。新型甲烷辅助高温电解模式将SOEC系统与甲烷部分氧化（POM）反应耦合，在有效降低电解能耗的同时制备高品位合成气。这种新型SOEC模式打通了电、热、气等不同能源网络，能够高效、灵活地实现不同能量之间的转化，实现能量和资源的最优利用。本文简述了甲烷辅助SOEC模式的研究进展，详细分析和阐述了该种新型SOEC模式下电解池的热力学参数、Nernst电势、电化学性能、产物组成和能量结构及效率，同时，总结了适用于甲烷辅助SOEC模式的电极体系的研究现状，最后对甲烷辅助SOEC模式的应用前景进行了展望。

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WANG Yao (1987-), female, Ph. D., Associate Professor. E-mail: pmewy@whu.edu.cn

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WANG Yao (1987-), female, Ph. D., Associate Professor. E-mail: pmewy@whu.edu.cn

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王瑶（1987—），女，博士，副教授。

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王瑶（1987—），女，博士，副教授。

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