Article(id=1322942423831294025, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942385474384734, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200427, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1592409600000, receivedDateStr=2020-06-18, revisedDate=1597075200000, revisedDateStr=2020-08-11, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343652923, onlineDateStr=2026-10-30, pubDate=1611072000000, pubDateStr=2021-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343652923, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343652923, creator=13701087609, updateTime=1793343652923, updator=13701087609, issue=Issue{id=1322942385474384734, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='1', pageStart='1', pageEnd='210', issueExtLink='null', onlineDate='null', pubDate='1611072000000', pubDateStr='2021-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343643777, creator='13701087609', updateTime=1793345438198, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322949911880282449, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942385474384734, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322949911880282450, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942385474384734, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=93, endPage=103, ext={EN=ArticleExt(id=1322942424061980746, articleId=1322942423831294025, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Electrolyte Corrosion in Liquid Metal Anode Solid Oxide Fuel Cell, columnId=1322942386086753121, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on SOFC, runingTitle=null, highlight=null, articleAbstract=

Liquid metal anode direct carbon solid oxide fuel cells have attracted recent attention due to the extremely high theoretical conversion efficiency. However, the corrosion of liquid metal electrodes to electrolytes is one of the key factors to degrade their performance and limit their life. This review represented the results on the chemical and electrochemical corrosion of liquid metal and oxides, i.e., mainly liquid antimony (Sb) and antimony oxide (Sb2O3), to the most frequently used ZrO2 and CeO2 based electrolytes in solid oxide fuel cells. The possible methods of reducing the degree of corrosion were discussed.

, authors=Jiyang MA1, 2, Yue HAN1, Lichao JIA1, Jian LI1, authorsList=Jiyang MA, Yue HAN, Lichao JIA, Jian LI, authorCompany=null, correspAuthors=Lichao JIA, authorNote=

MA Jiyang (1987-), male, Ph.D., Assistant Research Fellow. E-mail:

, correspAuthorsNote=
JIA Lichao (1985-), male, Ph.D., Associate Professor. E-mail:
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近年来,由于具有极高的理论转化效率,液态金属阳极直接碳固体氧化物燃料电池受到关注;然而,液态金属电极对电解质的腐蚀是降低其性能和限制其寿命的关键因素之一。本文综述了液态金属和氧化物,主要是液态锑(Sb)和氧化锑(Sb2O3),对固体氧化物燃料电池常用ZrO2和CeO2基电解质的化学和电化学腐蚀研究成果,并讨论了减缓腐蚀程度的途径与可能性。

, authors=马吉阳1, 2, 韩岳1, 贾礼超1, 李箭1, authorsList=马吉阳, 韩岳, 贾礼超, 李箭, authorCompany=null, correspAuthors=贾礼超, authorNote=

马吉阳(1987—),男,博士,助理研究员。

, correspAuthorsNote=
贾礼超(1985—),男,博士,副教授。
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液态金属阳极固体氧化物燃料电池中的电解质腐蚀
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马吉阳 1, 2 , 韩岳 1 , 贾礼超 1 , 李箭 1
硅酸盐学报 | SOFC专题 2021,49(1): 93-103
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硅酸盐学报 |SOFC专题 2021 , 49 (1) : 93 -103
液态金属阳极固体氧化物燃料电池中的电解质腐蚀
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马吉阳1, 2 , 韩岳1, 贾礼超1 , 李箭1
作者信息
  • 1.华中科技大学材料科学与工程学院,武汉 430074
  • 2.华南理工大学环境与能源学院,广州 510006
通讯作者:
贾礼超(1985—),男,博士,副教授。
作者简介:

马吉阳(1987—),男,博士,助理研究员。

Electrolyte Corrosion in Liquid Metal Anode Solid Oxide Fuel Cell
Jiyang MA1, 2 , Yue HAN1, Lichao JIA1 , Jian LI1
Affiliations
  • 1.Center for Fuel Cell Innovation, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
  • 2.School of Environment and Energy, South China University of Technology, Guangzhou 510006, China
  • Corresponding Author:
    JIA Lichao (1985-), male, Ph.D., Associate Professor. E-mail:

    MA Jiyang (1987-), male, Ph.D., Assistant Research Fellow. E-mail:

出版时间: 2021-01-20 doi: 10.14062/j.issn.0454-5648.20200427
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近年来,由于具有极高的理论转化效率,液态金属阳极直接碳固体氧化物燃料电池受到关注;然而,液态金属电极对电解质的腐蚀是降低其性能和限制其寿命的关键因素之一。本文综述了液态金属和氧化物,主要是液态锑(Sb)和氧化锑(Sb2O3),对固体氧化物燃料电池常用ZrO2和CeO2基电解质的化学和电化学腐蚀研究成果,并讨论了减缓腐蚀程度的途径与可能性。

直接碳固体氧化物燃料电池  /  液态锑阳极  /  电解质  /  腐蚀机理  /  耐蚀性

Liquid metal anode direct carbon solid oxide fuel cells have attracted recent attention due to the extremely high theoretical conversion efficiency. However, the corrosion of liquid metal electrodes to electrolytes is one of the key factors to degrade their performance and limit their life. This review represented the results on the chemical and electrochemical corrosion of liquid metal and oxides, i.e., mainly liquid antimony (Sb) and antimony oxide (Sb2O3), to the most frequently used ZrO2 and CeO2 based electrolytes in solid oxide fuel cells. The possible methods of reducing the degree of corrosion were discussed.

direct carbon solid oxide fuel cell  /  liquid antimony anode  /  electrolyte  /  corrosion mechanism  /  corrosion resistance
马吉阳, 韩岳, 贾礼超, 李箭. 液态金属阳极固体氧化物燃料电池中的电解质腐蚀. 硅酸盐学报, 2021 , 49 (1) : 93 -103 . DOI: 10.14062/j.issn.0454-5648.20200427
Jiyang MA, Yue HAN, Lichao JIA, Jian LI. Electrolyte Corrosion in Liquid Metal Anode Solid Oxide Fuel Cell[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (1) : 93 -103 . DOI: 10.14062/j.issn.0454-5648.20200427
  • 国家重点研发计划(2018YFE0124700)
  • 国家自然科学基金(U1601207)
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2021年第49卷第1期
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doi: 10.14062/j.issn.0454-5648.20200427
  • 接收时间:2020-06-18
  • 首发时间:2026-10-30
  • 出版时间:2021-01-20
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  • 收稿日期:2020-06-18
  • 修回日期:2020-08-11
基金
国家重点研发计划(2018YFE0124700)
国家自然科学基金(U1601207)
作者信息
    1.华中科技大学材料科学与工程学院,武汉 430074
    2.华南理工大学环境与能源学院,广州 510006

通讯作者:

贾礼超(1985—),男,博士,副教授。
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20200427
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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