Article(id=1322943101056197233, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942495801356913, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200379, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1590508800000, receivedDateStr=2020-05-27, revisedDate=1594224000000, revisedDateStr=2020-07-09, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343814386, onlineDateStr=2026-10-30, pubDate=1616169600000, pubDateStr=2021-03-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343814386, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343814386, creator=13701087609, updateTime=1793343814386, updator=13701087609, issue=Issue{id=1322942495801356913, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='3', pageStart='441', pageEnd='604', issueExtLink='null', onlineDate='null', pubDate='1616169600000', pubDateStr='2021-03-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343670081, creator='13701087609', updateTime=1793345495044, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322950150322258738, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942495801356913, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322950150322258739, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942495801356913, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=519, endPage=527, ext={EN=ArticleExt(id=1322943101219775090, articleId=1322943101056197233, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Surface Functional Groups Regulation of 2D Ti3C2Tx-MXene by Microwave Plasma Strategy and Its Gas Sensing Property, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Two-dimensional titanium carbide (Ti3C2Tx) material with an organ-like morphology was prepared by a selective etching reaction strategy, and the surface-treated Ti3C2Tx samples were obtained by O2-Ar microwave plasma technology under different temperatures to regulate the terminal functional groups. The microstructure evolution and surface oxygen functional group changes of Ti3C2Tx were investigated at different plasma treatment temperatures. The effect of activated Ti3C2Tx on gaseous formaldehyde, benzene, toluene and xylene were analyzed. A possible gas-sensing mechanism was discussed based on the perspective of the variation of the surface oxygen functional groups. The results show that O2-Ar plasma treatment can increase the content of surface oxygen functional groups of activated Ti3C2Tx. The gas sensitive response of a sample treated by plasma at 500℃ can reach 169 for 0.01% formaldehyde at an optimal operating temperature, and this sample also exhibits a good selectivity to gaseous formaldehyde.

, authors=Wei MAO1, Jiyun GAO1, 2, Ming HOU2, Fang WANG1, Lijuan JIA1, Li YANG2, Shenghui GUO2, authorsList=Wei MAO, Jiyun GAO, Ming HOU, Fang WANG, Lijuan JIA, Li YANG, Shenghui GUO, authorCompany=null, correspAuthors=Jiyun GAO, authorNote=

MAO Wei (1999-), male, Bachelor candidate. E-mail:

, correspAuthorsNote=
GAO Jiyun (1989-), female, Lecturer. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322943101479821939, articleId=1322943101056197233, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=二维Ti3C2Tx官能团微波等离子体调控及其气敏性能, columnId=0, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

采用液相溶液选择性刻蚀法制备风琴状二维碳化钛(Ti3C2Tx),并采用O2-Ar微波等离子体在不同热处理温度下对Ti3C2Tx进行表面官能团调控。研究了不同等离子体处理温度下材料的微结构和表面官能团变化,探讨了Ti3C2Tx对甲醛和苯系物的气敏响应和选择性,从材料氧官能团变化角度探讨了可能的气体敏感机制。结果表明:O2-Ar等离子体处理可增加Ti3C2Tx材料中的表面氧官能团含量,经500℃热处理样品在最佳工作温度下对0.01%(体积分数)甲醛响应可达到169,同时在室温下对甲醛也表现出良好的气敏性能。

, authors=毛威1, 高冀芸1, 2, 侯明2, 王访1, 贾丽娟1, 杨黎2, 郭胜惠2, authorsList=毛威, 高冀芸, 侯明, 王访, 贾丽娟, 杨黎, 郭胜惠, authorCompany=null, correspAuthors=高冀芸, authorNote=

毛威(1999—),男,本科生。

, correspAuthorsNote=
高冀芸(1989—),女,讲师。
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二维Ti3C2Tx官能团微波等离子体调控及其气敏性能
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毛威 1 , 高冀芸 1, 2 , 侯明 2 , 王访 1 , 贾丽娟 1 , 杨黎 2 , 郭胜惠 2
硅酸盐学报 | 2021,49(3): 519-527
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硅酸盐学报 | 2021 , 49 (3) : 519 -527
二维Ti3C2Tx官能团微波等离子体调控及其气敏性能
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毛威(1999—),男,本科生。

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毛威1 , 高冀芸1, 2 , 侯明2, 王访1, 贾丽娟1, 杨黎2, 郭胜惠2
作者信息
  • 1.云南民族大学化学与环境学院,昆明 650503
  • 2.昆明理工大学冶金与能源工程学院,昆明 650093
通讯作者:
高冀芸(1989—),女,讲师。
作者简介:

毛威(1999—),男,本科生。

Surface Functional Groups Regulation of 2D Ti3C2Tx-MXene by Microwave Plasma Strategy and Its Gas Sensing Property
Wei MAO1 , Jiyun GAO1, 2 , Ming HOU2, Fang WANG1, Lijuan JIA1, Li YANG2, Shenghui GUO2
Affiliations
  • 1.College of Chemistry and Environment, Yunnan Minzu University, Kunming 650503, China
  • 2.Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
  • Corresponding Author:
    GAO Jiyun (1989-), female, Lecturer. E-mail:

    MAO Wei (1999-), male, Bachelor candidate. E-mail:

出版时间: 2021-03-20 doi: 10.14062/j.issn.0454-5648.20200379
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采用液相溶液选择性刻蚀法制备风琴状二维碳化钛(Ti3C2Tx),并采用O2-Ar微波等离子体在不同热处理温度下对Ti3C2Tx进行表面官能团调控。研究了不同等离子体处理温度下材料的微结构和表面官能团变化,探讨了Ti3C2Tx对甲醛和苯系物的气敏响应和选择性,从材料氧官能团变化角度探讨了可能的气体敏感机制。结果表明:O2-Ar等离子体处理可增加Ti3C2Tx材料中的表面氧官能团含量,经500℃热处理样品在最佳工作温度下对0.01%(体积分数)甲醛响应可达到169,同时在室温下对甲醛也表现出良好的气敏性能。

微波等离子体  /  二维碳化钛  /  表面官能团  /  气敏

Two-dimensional titanium carbide (Ti3C2Tx) material with an organ-like morphology was prepared by a selective etching reaction strategy, and the surface-treated Ti3C2Tx samples were obtained by O2-Ar microwave plasma technology under different temperatures to regulate the terminal functional groups. The microstructure evolution and surface oxygen functional group changes of Ti3C2Tx were investigated at different plasma treatment temperatures. The effect of activated Ti3C2Tx on gaseous formaldehyde, benzene, toluene and xylene were analyzed. A possible gas-sensing mechanism was discussed based on the perspective of the variation of the surface oxygen functional groups. The results show that O2-Ar plasma treatment can increase the content of surface oxygen functional groups of activated Ti3C2Tx. The gas sensitive response of a sample treated by plasma at 500℃ can reach 169 for 0.01% formaldehyde at an optimal operating temperature, and this sample also exhibits a good selectivity to gaseous formaldehyde.

microwave plasma  /  two-dimensional Titanium carbide  /  surface functional groups  /  gas sensing
毛威, 高冀芸, 侯明, 王访, 贾丽娟, 杨黎, 郭胜惠. 二维Ti3C2Tx官能团微波等离子体调控及其气敏性能. 硅酸盐学报, 2021 , 49 (3) : 519 -527 . DOI: 10.14062/j.issn.0454-5648.20200379
Wei MAO, Jiyun GAO, Ming HOU, Fang WANG, Lijuan JIA, Li YANG, Shenghui GUO. Surface Functional Groups Regulation of 2D Ti3C2Tx-MXene by Microwave Plasma Strategy and Its Gas Sensing Property[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (3) : 519 -527 . DOI: 10.14062/j.issn.0454-5648.20200379
  • 国家自然科学基金(51864028)
  • 云南省稀贵金属材料基因工程重大科技专项(202002AB080001)
  • 云南省杰出青年基金(2019FJ005)
  • 云南省应用基础研究计划项目(2018FD053; 2018FA029)
  • 云南省万人计划青年拔尖人才专项(YNWRQNBJ-2018-311)
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2021年第49卷第3期
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doi: 10.14062/j.issn.0454-5648.20200379
  • 接收时间:2020-05-27
  • 首发时间:2026-10-30
  • 出版时间:2021-03-20
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出版历史
  • 收稿日期:2020-05-27
  • 修回日期:2020-07-09
基金
国家自然科学基金(51864028)
云南省稀贵金属材料基因工程重大科技专项(202002AB080001)
云南省杰出青年基金(2019FJ005)
云南省应用基础研究计划项目(2018FD053; 2018FA029)
云南省万人计划青年拔尖人才专项(YNWRQNBJ-2018-311)
作者信息
    1.云南民族大学化学与环境学院,昆明 650503
    2.昆明理工大学冶金与能源工程学院,昆明 650093

通讯作者:

高冀芸(1989—),女,讲师。
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2种不同金属材料的力学参数
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属
Genus
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Number of
species
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Percentage of total
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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