Article(id=1322917122581603140, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322917095268295267, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200317, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1588694400000, receivedDateStr=2020-05-06, revisedDate=1590249600000, revisedDateStr=2020-05-24, acceptedDate=null, acceptedDateStr=null, onlineDate=1793337620635, onlineDateStr=2026-10-30, pubDate=1608393600000, pubDateStr=2020-12-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793337620635, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793337620635, creator=13701087609, updateTime=1793337620635, updator=13701087609, issue=Issue{id=1322917095268295267, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='12', pageStart='1865', pageEnd='2010', issueExtLink='null', onlineDate='null', pubDate='1608393600000', pubDateStr='2020-12-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793337614123, creator='13701087609', updateTime=1793345927101, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951962475507806, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322917095268295267, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951962475507807, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322917095268295267, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1976, endPage=1981, ext={EN=ArticleExt(id=1322917122766152517, articleId=1322917122581603140, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Synthesis and Alkylation Properties of Mordenites with Different Morphologies, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=
Three mordenites with different morphologies (i.e., fiber bundle, regular fiber and flaky) were synthesized via the introduction of cyclohexylamine and hexamethyleneimmonium, respectively. The crystal form, morphology, pore structure and acidity of the samples were characterized by X-ray diffraction and N2 physical adsorption, scanning electron microscopy and NH3 temperature-programmed desorption, and the alkylation performance evaluation and regeneration experiments were carried out. The experimental results show that all three mordenites have a great catalytic activity, and the catalyst life of the flaky mordenite can reach 26 h, which is better than that of the fiber bundle mordenite for 5 h and the regular fibrous mordenite for 3 h. The fiber bundle and regular fibrous mordenites can have a selectivity to 2-substituted linear alkylbenzene of more than 75%, and the product selectivity of flaky mordenite can reach more than 50%, which is superior to the existing technology for linear alkylbenzene production. The catalyst regeneration rate is opposite to the catalyst deactivation rate. The three mordenites with fiber bundle regular fiber and flaky morphologies have the maximum catalytic activities of fresh catalysts after regeneration of 8, 11 h, and 5 h, respectively.
, authors=Sishuai REN
1, 2, Yan CUI
1, Fayong LI
1, Jian XU
2, Xinmei PANG
1, authorsList=Sishuai REN, Yan CUI, Fayong LI, Jian XU, Xinmei PANG, authorCompany=null, correspAuthors=Yan CUI, authorNote=
, correspAuthorsNote=
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通过向合成体系中引入环己胺和六亚甲基亚胺,合成出了纤维束状、针柱状、薄片状的丝光沸石,并采用X射线衍射谱、N2物理吸附、扫描电子显微镜、NH3程序升温脱附等方式对其晶型、形貌、孔道结构、酸性等进行了表征,并分别进行了烷基化性能评价及再生实验。结果表明:3种丝光沸石都具有较强的催化活性,薄片状丝光沸石的催化剂寿命可以达到26 h,明显优于纤维束状丝光沸石的5 h时和针柱状丝光沸石的3 h。纤维束状和规则纤维状丝光沸石对2位取代线性烷基苯的选择性可达到75%以上,薄片状丝光沸石的产品选择性可达50%以上,均优于现有线性烷基苯生产技术。催化剂再生速度与催化剂失活速度相反,3种丝光沸石分别经过8、11、5 h再生可完全恢复失活前最高催化活性。
, authors=任思帅
1, 2, 崔岩
1, 李发永
1, 徐建
2, 庞新梅
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崔岩(1988—),男,硕士,工程师。
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